CAS 12012-95-2; 烯丙基氯化钯二聚体; Palladium chloride,allyl-(dimer)

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A799598

MACKLIN

氯化烯丙基钯(II)二聚物

99.95% metals basis

338元/100mg; 570元/250mg; 1534元/1g;

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储存：2-8°C, 避光, 惰性气体

A800122

MACKLIN

氯化烯丙基钯(II)二聚物

Pd 58.2%

320元/200mg; 1098元/1g; 5186元/5g;

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储存：2~8°C
状态：黄色到金色-绿色粉末或晶体

A1479

TCI

Allylpalladium(II) Chloride Dimer

>97.0%(T)

1290元/500MG; 2300元/1G;

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基本信息

纯度/分析方法	>97.0%(T)
分子式/分子量	C₆H₁₀Cl₂Pd₂ = 365.89
外观与形状(20℃)	固体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	光,湿气 (分解)
包装和容器	500MG-带有塑料内管的玻璃瓶 (查看图片)
PubChem物质ID	87562932
MDL编号	MFCD00044874

技术规格

Appearance	Light yellow to Amber to Dark green powder to crystal
Purity(Argentometric Titration)	min. 97.0 %
Purity(Chelometric Titration)	min. 97.0 %
Solubility in THF	almost transparency

物性(参考值)

水溶性	不溶
溶解性(可溶于)	甲醇,苯,丙酮,氯仿

安全信息

图形或危害标志
信号词	警告
危险性说明	H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。 P302 + P352 + P312 : 如皮肤沾染：用水充分清洗。如感觉不适，呼叫急救中心/医生。 P304 + P340 + P312 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。如感觉不适，呼叫急救中心/医生。

相关法规

RTECS#

RT3510000

982398

J&K

Allylpalladium(II) Chloride Dimer

98%

368元/250MG; 1193元/1G; 3784元/5G;

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基本信息

分子式	C₆H₁₀Cl₂Pd₂
分子量	365.89
熔点	160
MDL编码	MFCD00044874
Beilstein	4124623
EINECS 编号	234-579-8
存储条件	Store at 2-8℃

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
RTECS	RT3510000
TSCA	否

46-0100

Strem

Allylpalladium chloride dimer

min. 98%

1084元/500mg; 3510元/2g; 14040元/10g;

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Technical Notes:

1.Precatalyst for the enantioselective hydrosilylation of olefins.

2.Precatalyst for asymmetric allylic alkylation and amination.

3.Used as a palladium source for cross-coupling reactions .

4. Can be used with Trost ligands.

5. Catalyst for the carbostannylation of alkynes.

6. Used as a precatalyst for a-arylation of aldehydes.

References:

1.J. Am. Chem. Soc., 1991, 1 13, 9887.

2.Tetrahedron, 1994, 50, 335.

3.J. Am. Chem. Soc., 2007, 129, 7718.

4. Org. L ett., 2007, 9, 4295.

5. Org. L ett., 2008, 10, 501.

6. Org. L ett., 2005, 7, 945.

7.Synlett, 2005, 2057

8. Tetrahedron, 2007, 63, 9393.

9. J. Am. Chem. Soc., 2006, 128, 2540.

10.Org. L ett., 2006, 8, 2027.

11.Angew. Chem. Int. Ed., 2007, 46, 6123.

12.J. Am. Chem. Soc., 1998, 120, 2975.

13.Angew. Chem. Int. Ed., 2008, 47, 2127.

14.Chem. Rev., 1996, 96, 395. (review)

15.Science of Synthesis, 2002, 1, 1 13.

010005

Alfa Aesar

Allylpalladium(II) Chloride Dimer

Pd 56.0% min

836元/0.25g; 0元/1g; 0元/5g;

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应用
Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta³-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry.

备注
Air and moisture sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00044874

EINECS
234-579-8

分子式
C₆H₁₀Cl₂Pd₂

分子量
365.85

熔点
120° dec.

灵敏度
Moisture Sensitive. Air Sensitive. Keep Cold. Store under Nitrogen.

形态
Powder

溶解性
Very soluble in dichloromethane and dichloroethane. Slightly soluble in toluene, insoluble in waterSoluble in chloroform, benzene, acetone and dichloromethane, dichloroethane and methanol. Slightly soluble in toluene. Insoluble in water.

Beilstein
4124623

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

RTECS
RT3510000

TSCA
否

C20683

Alfa Aesar

Allylpalladium chloride dimer

98%

1411元/500mg; 13700元/5g;

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基本信息

Ref#
20683

MDL
44874

分子式
C6 H10 Cl2 Pd2

分子量
365.84

形态
Powder

222380

Sigma-Aldrich

Allylpalladium(II) Chloride Dimer

98%

992.55元/500 MG; 1331.94元/1 G; 5208.01元/5 G;

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产品说明

一般描述

我们致力于为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了催化效率。点击此处以获取更多信息。
氯化烯丙基钯二聚体被用作Heck反应的催化剂。它还作为催化剂参与炔醛与烯丙基氯和烯丙基丁基锡烷的串联亲核烯丙基化-烷氧基烯丙基化反应。

应用

钯催化交叉偶联反应应用指南
烯丙基钯(II)氯化物二聚体已用于以下研究：

微波辅助Heck芳基化用阳离子钯催化剂的合成。
N-杂环卡宾-钯-η³-烯丙基氯络合物的合成：它是芳基溴化物和活化芳基氯化物Suzuki-Miyaura交叉偶联的有效催化剂。
1，4-二烯丙基-1，2-二氢异喹啉的合成。
作为TPGS-750-M更绿色Buchwald-Hartwig耦合的催化剂

朝着通过E因子而量化的绿色过渡金属催化过程前进

包装

1, 5 g in glass bottle
500 mg in glass bottle

基本信息

经验(实验)分子式	C₆H₁₀Cl₂Pd₂
分子量	365.89
Beilstein	4124623
EC 号	234-579-8
MDL编号	MFCD00044874
PubChem化学物质编号	24853328

产品性质

质量水平	100
测定	98%
reaction suitability	core: palladium reagent type: catalyst reaction type: C-H Activation
环保替代产品特性	Catalysis Learn more about the Principles of Green Chemistry.
环保替代产品分类	Aligned
储存温度	2-8℃
SMILES string	Cl[Pd]CC=C.Cl[Pd]CC=C
InChI	1S/2C3H5.2ClH.2Pd/c21-3-2;;;;/h23H,1-2H2;21H;;/q;;;;2+1/p-2
InChI key	TWKVUTXHANJYGH-UHFFFAOYSA-L

安全信息

象形图
警示用语：	Warning
危险声明	H315
预防措施声明	P264 - P280 - P302 + P352 - P332 + P313 - P362 + P364
危险分类	Skin Irrit. 2
储存分类代码	11 - Combustible Solids
WGK	WGK 3
个人防护装备	dust mask type N95 (US), Eyeshields, Faceshields, Gloves

683396

Sigma-Aldrich

[Pd(allyl)Cl]₂

Umicore

788.8元/500 MG; 6234.61元/5 G;

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产品说明

应用

钯催化交叉偶联反应应用指南
[Pd(allyl)Cl]₂ can be used as a catalyst:

For the silylation of organobromides.
To synthesize α-aryl carbonyl compounds by coupling reaction between aldehydes and aryl halides.
To prepare various arylthiophene derivatives by cross-coupling reaction with aryl halides via C-H functionalization.

包装

5 g in glass bottle
500 mg in glass bottle

其他说明

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

法律信息

Umicore 产品

更多信息参见www.pmc.umicore.com

基本信息

经验(实验)分子式	C₆H₁₀Cl₂Pd₂
分子量	365.89
Beilstein	4124623
EC 号	234-579-8
MDL编号	MFCD00044874
PubChem化学物质编号	329760817
NACRES	NA.22

产品性质

质量水平	100
测定	≥98.0% (C, elemental analysis)
reaction suitability	core: palladium reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst
SMILES string	Cl[Pd]CC=C.Cl[Pd]CC=C
InChI	1S/2C3H5.2ClH.2Pd/c21-3-2;;;;/h23H,1-2H2;21H;;/q;;;;2+1/p-2
InChI key	TWKVUTXHANJYGH-UHFFFAOYSA-L

安全信息

象形图
警示用语：	Warning
危险声明	H315
预防措施声明	P264 - P280 - P302 + P352 - P332 + P313 - P362 + P364
危险分类	Skin Irrit. 2
储存分类代码	11 - Combustible Solids
WGK	WGK 3
个人防护装备	dust mask type N95 (US), Eyeshields, Faceshields, Gloves

705020

Sigma-Aldrich

Allylpalladium chloride dimer ChemDose^TM tablet

728.12元/10 TABLETS;

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产品说明

应用

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

ChemDose: Convenient Dosing of Catalysts and Reagents

包装

10, 100 tablets in glass bottle

法律信息

ChemDose is a trademark of Reaxa Ltd.

基本信息

经验(实验)分子式	C₆H₁₀Cl₂Pd₂
分子量	365.89
MDL编号	MFCD00044874
PubChem化学物质编号	329762500
NACRES	NA.22

产品性质

形式	tablet
组成	allylpalladium chloride dimer, <5% magnesium aluminometasilicate, >90% methylene chloride, <5%
SMILES string	Cl[Pd]CC=C.Cl[Pd]CC=C
InChI	1S/2C3H5.2ClH.2Pd/c21-3-2;;;;/h23H,1-2H2;21H;;/q;;;;2+1/p-2
InChI key	TWKVUTXHANJYGH-UHFFFAOYSA-L

046130

Fluorochem

Allylpalladium(II)chloride dimer

>98%

2090元/1g; 9350元/5g;

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基本信息

CAS Number	12012-95-2
MDL Number	MFCD00044874

安全信息

图形或危害标志
危险性说明	H302: Harmful if swallowed. H312: Harmful in contact with skin. H315: Causes skin irritation. H332: Harmful if inhaled.
防范说明	P261: Avoid breathing . P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P322: Specific measures (see . on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P362: Take off contaminated clothing and wash before reuse. P363: Wash contaminated clothing before reuse. P501: Dispose of contents/container to local regulations.