产品说明 应用 (S)-2-(Methoxydiphenylmethyl)pyrrolidine is a diphenylprolinol methyl ether, which can be used as a catalyst to synthesize:
- Enantioselective ketones via intermolecular asymmetric Michael addition of aldehydes to nonactivated enones.
- Stereoselective chiral bipyrazolidin-3-one derivatives by dipolar cycloaddition reaction of azomethine imines with α, β-unsaturated aldehydes.
- Enantioenriched spiro nitrogen heterocycles via asymmetric nucleophilic epoxidation of α-ylideneoxindole esters.
- Optically active secondary alcohols by asymmetric addition of Et2Zn to various aldehydes.
包装 100, 500 mg in glass bottle Bottomless glass bottle. Contents are inside inserted fused cone. 基本信息 | 经验(实验)分子式 | C18H21NO | | 分子量 | 267.37 | | MDL编号 | MFCD09750440 | | PubChem化学物质编号 | 24885069 | | NACRES | NA.22 |
产品性质 | 测定 | 95% (HPLC) | | 光学纯度 | ee: ≥99.5% (HPLC) | | 储存温度 | 2-8℃ | | SMILES string | COC([C@@H]1CCCN1)(c2ccccc2)c3ccccc3 | | InChI | 1S/C18H21NO/c1-20-18(17-13-8-14-19-17,15-9-4-2-5-10-15)16-11-6-3-7-12-16/h2-7,9-12,17,19H,8,13-14H2,1H3/t17-/m0/s1 | | InChI key | CGUGCZSRPDCLBT-KRWDZBQOSA-N |
安全信息 | 象形图 |  | | 警示用语: | Warning | | 危险声明 | H302 | | 危险分类 | Acute Tox. 4 Oral | | 储存分类代码 | 12 - Non Combustible Liquids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
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