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CAS: 118-90-1
分子式: C8H8O2
分子量: 136.15
沸点: 258-259℃
熔点: 103-105℃
中文名称: 
邻甲苯甲酸
邻甲酸
邻甲苯酸
邻甲基苯甲酸
2-甲基苯甲酸
英文名称: 
O-METHYL BENZOIC ACID
2-methyl-benzoic acid
2-Methyl benzoic acid
2-Toluic acid
2-methyl-Benzoic acid
o-toluic acid
2-methylbenzoic acid
2-methyl-benzoic aci
o-methylbenzoic acid
o-toluylic acid
orthotoluic acid
Benzoic acid,2-methyl-
o-toluic
o-toluicacid
toluic acid
展开更多英文名
性质描述: 白色易燃棱晶或针晶。低毒。熔点为103-105℃,沸点258-259℃(100.125kPa),相对密度1.062(115/4℃),折射率1.512(115℃),电离常数1.2×10-5。微溶于水,易溶于乙醇、乙醚及氯仿。能随水蒸气挥发。
生产方法: 由邻二甲苯经催化氧化而得。以邻二甲苯为原料、环烷酸钴为催化剂,在温度120℃,压力0.245MPa下,邻二甲苯连续进入氧化塔进行空气氧化,氧化液进入汽提塔进行浓缩、经结晶、离心,得成品。母液进行蒸馏,回收邻二甲苯及部分邻甲基苯甲酸后,排渣。收率为74%。每吨产品消耗邻二甲苯(95%)1300kg。
用途: 用作农药杀菌剂磷酰胺、香料、氯乙烯聚合引发剂MBPO、间甲酚、彩色胶片显影剂等有机合成中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T818886MACKLIN邻甲基苯甲酸98%30元/100g;   104元/500g;   399元/2.5kg;   1450元/10kg;   展开
储存:室温,干燥
状态:白色到黄色-棕褐色片状
折射率:1.512
T792789MACKLIN邻甲基苯甲酸10mM in DMSO185元/1ml;   展开
储存:-20°C
T0292TCIo-Toluic Acid>98.0%(T)150元/25G;   330元/100G;   450元/500G;   展开

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C8H8O2 = 136.15
外观与形状(20℃)固体
Reaxys-RN1072103
PubChem物质ID87576267
SDBS (AIST Spectral DB)2628
Merck Index (14)9535
MDL编号MFCD00002477

技术规格

AppearanceWhite to Orange to Green powder to crystal
Purity(Neutralization titration)min. 98.0 %
Melting point102.0 to 107.0 ℃

物性(参考值)

熔点104 ℃
沸点259 ℃
水溶性微溶
溶解性(易溶于)
溶解性(可溶于)氯仿

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。

相关法规

RTECS#XU1400000
285195J&Ko-Toluic Acid99%60元/1G;   72元/25G;   356元/500G;   展开

基本信息

分子式C8H8O2
分子量136.15
熔点103
沸点258-259
闪点148
密度1.062
MDL编码MFCD00002477
EINECS 编号204-284-9

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
RTECSXU1400000
TSCA
A13856Alfa Aesaro-Toluic Acid98+%391元/250g;   1215元/1000g;   3219元/5000g;   展开

应用
o-Toluic acid is used for producing of fluorescent whitening agent ER33%, bensulfuronmethyl,o-tolunitrile,o-cyano-benzaldehyde and 3,5-dinitro-o-toluylamide etc.

备注
Incompatible with strong oxidizing agents, strong bases.

基本信息

MDL
MFCD00002477

EINECS
204-284-9

分子式
C8H8O2

分子量
136.15

熔点
103-106°

沸点
258-259°

闪点
148°(298°F)

密度
1.060

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in alcohol and chloroform. Slightly soluble in water.

Beilstein
1072103

Merck
14,9535

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
XU1400000

TSCA

C13904Alfa Aesaro-Toluic Acid98+%401元/100g;   463元/5g;   2088元/1kg;   展开

基本信息

Ref#
13904

MDL
2477

分子式
C8 H8 O2

分子量
136.15

闪点
148

形态
White to pale cream cryst powder

T36404Sigma-Aldricho-Toluic acid99%603.06元/100 G;   1155.18元/500 G;   展开

基本信息

线性分子式CH3C6H4CO2H
分子量136.15
Beilstein1072103
EC 号204-284-9
MDL编号MFCD00002477
PubChem化学物质编号24900155
NACRESNA.22

产品性质

测定99%
bp258-259 ℃ (lit.)
mp102-104 ℃ (lit.)
密度1.062 g/mL at 25 ℃ (lit.)
SMILES stringCc1ccccc1C(O)=O
InChI1S/C8H8O2/c1-6-4-2-3-5-7(6)8(9)10/h2-5H,1H3,(H,9,10)
InChI keyZWLPBLYKEWSWPD-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)298.4 °F - closed cup
闪点(C)148 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
242818Fluorochem2-Methylbenzoic Acid97%220元/25g;   220元/5g;   330元/100g;   616元/500g;   展开

基本信息

CAS Number118-90-1
MDL NumberMFCD00002477
Boiling Point258-259℃
Melting Point102-104℃
Density1.062

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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