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CAS: 1169835-86-2
分子式: C45H49O4P
分子量: 684.8400  
中文名称: 
(3as,8as)-(+)-4,4,8,8四(3,5-二甲基苯基)四氢-2,2-二甲基-6-苯基-1,3-二氧杂环戊烯并[4,5-e]二噁磷杂庚英
英文名称: 
(3as,8as)-(+)-4,4,8,8-tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin
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货号品牌产品名称规格包装、参考价格
S951214MACKLIN(3aS,8aS)-(+)-4,4,8,8-四(3,5-二甲基苯基)四氢-2,2-二甲基-6-苯基-1,3-二氧杂环戊烯并[4,5-e]二氧杂磷杂环庚烷98%708元/100mg;   1136元/250mg;   3157元/1g;   咨询
储存:室温
15-1512Strem(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin1095元/100mg;   4440元/500mg;   咨询

Technical Notes:

1.Chiral ligand used in the nickel-catalyzed, enantios elective, conjugate allylation of activated enones.

2.Chiral ligand used in the platinum-catalyzed, asymmetric, 1 ,4-dihydroxylation of 1,3-dienes via catalytic enantios electivediboration.

3.Chiral ligand used in the platinum-catalyzed, asymmetric addition of Bz(pin)z to N-silyl imines for the synthesis of a- aminoboronates.

4. Asymmetric 1,4 dihydroxylation of 1,3 dienes by catalytic enantios elective diboration.

References: 1. J. Am. Chem. Soc., 2008, 130, 4978. 2.J. Am. Chem. Soc.,2009, 131, 9134. 3.J. Am. Chem. Soc., 2013, 135, 9252 . 4.Chem. Sci., 2015, 6, 51 64.
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