| CAS: | 1169835-86-2 | |
| 分子式: | C45H49O4P | |
| 分子量: | 684.8400 | |
| 中文名称: |
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| 英文名称: |
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| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |||
| S951214 | MACKLIN | (3aS,8aS)-(+)-4,4,8,8-四(3,5-二甲基苯基)四氢-2,2-二甲基-6-苯基-1,3-二氧杂环戊烯并[4,5-e]二氧杂磷杂环庚烷 | 98% | 708元/100mg; 1136元/250mg; 3157元/1g; | 咨询 | ||
储存:室温 | |||||||
| 15-1512 | Strem | (3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin | 1095元/100mg; 4440元/500mg; | 咨询 | |||
Technical Notes: 1.Chiral ligand used in the nickel-catalyzed, enantios elective, conjugate allylation of activated enones. 2.Chiral ligand used in the platinum-catalyzed, asymmetric, 1 ,4-dihydroxylation of 1,3-dienes via catalytic enantios electivediboration. 3.Chiral ligand used in the platinum-catalyzed, asymmetric addition of Bz(pin)z to N-silyl imines for the synthesis of a- aminoboronates. 4. Asymmetric 1,4 dihydroxylation of 1,3 dienes by catalytic enantios elective diboration. References: 1. J. Am. Chem. Soc., 2008, 130, 4978. 2.J. Am. Chem. Soc.,2009, 131, 9134. 3.J. Am. Chem. Soc., 2013, 135, 9252 . 4.Chem. Sci., 2015, 6, 51 64. | |||||||