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CAS: 116-63-2
分子式: C10H9NO4S
分子量: 239.25
沸点: 466℃
熔点: 295℃
中文名称: 
1,2,4-酸
4-氨基-3-羟基萘-1-磺酸
4-氨基-3-羟基-1-萘磺酸,ACS
4-氨基-3-羟基-1-萘磺酸
1-氨基-2-萘酚-4-磺酸
英文名称: 
4-amino-3-hydroxy-1-naphthalene sulfonic acid
1-Naphthalenesulfonic acid,4-amino-3-hydroxy-
4-Amino-3-hydroxynaphthalene-1-sulfonic acid
4-amino-3-hydroxy-1-Naphthalenesulfonic acid
1,2,4-acid
1-amino-2-naphthol-4-sulfonic acid
1-amino-4-sulfo-2-naphthol
4-amino-3-hydroxy-1-naphthalenesulfonic aci
2-hydroxy-4-sulfo-1-naphthylamine
4-amino-3-hydroxy-1-naphthalenesulfonic acid
1-Amino-2-naphthol-4-sulfonic
展开更多英文名
性质描述: 该品为白色或灰色针状结晶,常含半分子结晶水。能溶于热亚硫酸氢钠和碱溶液,不溶于冷的乙醇、乙醚、苯,微溶于水。在空气中变为粉红色,潮湿时更甚。碱溶液在空气中很快地氧化成棕色,中性溶液略显蓝色荧光。
生产方法: 以2-萘酚为原料,经碱熔、亚硝化、磺化而得。原料消耗定额:2-萘酚(99%)840kg/t、亚硫酸氢钠(98%)1500kg/t、硫酸(92.5%)1600kg/t。
用途: 酸性媒介染料及酸性络合染料中间体。用于制造酸性络合桃红B、酸性媒介黑R和酸性络合盐GGN、酸性媒介枣BN等。也用于比色法测定磷酸盐及钙盐。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
A909480MACKLIN1-氨基-2-萘酚-4-磺酸for spectrophotometric det. of Si, 95%80元/5g;   300元/25g;   750元/100g;   1700元/500g;   展开
储存:室温, 密封, 干燥, 避光, 惰性气体
状态:紫红色粉末
A800664MACKLIN1-氨基-2-萘酚-4-磺酸90%36元/5g;   96元/25g;   279元/100g;   918元/500g;   1499元/1kg;   2693元/2.5kg;   展开
储存:室温, 密封, 干燥, 避光, 惰性气体
状态:白色到红色和粉色到紫色粉末
A828267MACKLIN1-氨基-2-萘酚-4-磺酸95%28元/1g;   57元/5g;   103元/25g;   297元/100g;   924元/500g;   1526元/1kg;   2729元/2.5kg;   展开
储存:室温
状态:白色到红色和粉色到紫色粉末
A0367TCI1-Amino-2-naphthol-4-sulfonic Acid>95.0%(T)(HPLC)305元/25G;   展开

基本信息

纯度/分析方法>95.0%(T)(HPLC)
分子式/分子量C10H9NO4S = 239.25
外观与形状(20℃)固体
应避免的情况
Reaxys-RN2697469
PubChem物质ID87559365
SDBS (AIST Spectral DB)6644
Merck Index (14)454
MDL编号MFCD00004019

技术规格

AppearanceWhite to Brown to Dark purple powder to crystal
Purity(HPLC)min. 95.0 area%
Purity(Neutralization titration)min. 95.0 %

物性(参考值)

熔点295 ℃
水溶性实际上不溶
溶解性(不溶于)苯,乙醚,乙醇

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#QK1292000
419750J&K4-Amino-3-hydroxy-1-naphthalenesulfonic Acid97%247元/25G;   814元/100G;   展开

基本信息

分子式C10H9NO4S
分子量239.25
熔点290
MDL编码MFCD00004019
Beilstein2697469
Merck14,454
EINECS 编号204-147-3

安全信息

WGK3
RTECSQK1292000
TSCA
990923J&K4-Amino-3-hydroxy-1-naphthalenesulfonic Acid99%257元/25G;   845元/100G;   展开

基本信息

分子式C10H9NO4S
分子量239.25
熔点290
MDL编码MFCD00004019
Beilstein2697469
Merck14,454
EINECS 编号204-147-3

安全信息

WGK3
RTECSQK1292000
TSCA
036290Alfa Aesar4-Amino-3-hydroxy-1-naphthalenesulfonic AcidACS, 90+%194元/5g;   659元/25g;   1911元/100g;   展开

应用
4-Amino-3-hydroxy-1-naphthalenesulfonic acid is used as a key starting material for the preparation of naphthalenesulfonic acid derivatives by reacting with palmitoyl chloride, which shows the activity to inhibit DNA polymerase and ribonuclease H Activities of HIV-1 reverse transcriptase. It is also used to prepare a copolyner with melamine, which is associated with graphene to prepare molecularly imprinted sensor and utilized for the determination of melatonin in human biological fluids.

Grade Specifications
Maximum level of impurities: Solubilty in sodium carbonate P.T., Residue after ignition 0.1%, SO4 0.2%, Sensitivity to phosphate P.T.

备注
Incompatible with strong oxidizing agents, strong bases, acid chlorides and acid anhydrides.

基本信息

MDL
MFCD00004019

EINECS
204-147-3

分子式
C10H9NO4S

分子量
239.25

熔点
ca 295° dec.

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Soluble in hot water, hot hydrogen sulfite of sodium and alkali. Insoluble in water, ethanol, ethyl ether and benzene.

Beilstein
2697469

Merck
14,454

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

RTECS
QK1292000

TSCA

B24339Alfa Aesar4-Amino-3-hydroxy-1-naphthalenesulfonic Acid99%617元/25g;   2251元/100g;   展开

应用
4-Amino-3-hydroxy-1-naphthalenesulfonic acid is used as mordant dyes and acid dyes intermediate.

备注
Store away from strong oxidizers, strong bases, acid anhydrides, acid chlorides.

基本信息

MDL
MFCD00004019

EINECS
204-147-3

分子式
C10H9NO4S

分子量
239.25

熔点
ca 295° dec.

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Soluble in bases. Insoluble in water.

Beilstein
2697469

Merck
14,454

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

RTECS
QK1292000

TSCA

C40085Alfa Aesar4-Amino-3-hydroxy-1-naphthalenesulfonic Acid98+%, ACS reagent1638元/25g;   4661元/100g;   展开

基本信息

Ref#
40085

MDL
4019

分子式
C10 H9 N O4 S

分子量
239.25

形态
Powder

C14927Alfa Aesar4-Amino-3-hydroxy-1-naphthalenesulfonic Acid95%779元/25g;   2388元/100g;   展开

基本信息

Ref#
14927

MDL
4019

分子式
C10 H9 N O4 S

分子量
239.25

08751Supelco4-Amino-3-hydroxy-1-naphthalenesulfonic Acidfor spectrophotometric det. of Si, ≥90.0% (CHN)654.67元/25G;   2225.04元/100G;   展开

产品说明

一般描述

4-氨基-3-羟基-1-萘磺酸是一种芳族氨基磺酸。

应用

4-氨基-3-羟基-1-萘磺酸已被用于研究使用离子相互作用高效液相色谱和胶束电动毛细管色谱技术分离芳族磺化化合物。 它也被用作起始材料而与棕榈酰氯反应生成以下衍生物:

  • 2′-十五烷基萘[3,4-d]恶唑-1-磺酸
  • 4-氨基-3-(棕榈酰氧基)-1-萘磺酸
  • 4-(棕榈酰氨基)-3-羟基-1-萘磺酸
  • 4-(棕榈酰氨基)-3-(棕榈酰氧基)-1-萘磺酸

其他说明

分光光度法测定硅的试剂

基本信息

线性分子式H2NC10H5(OH)SO3H
分子量239.25
Beilstein2697469
EC 号204-147-3
MDL编号MFCD00004019
PubChem化学物质编号329748632
NACRESNA.21

产品性质

质量水平100
测定≥90.0% (CHN)
形式powder
质量for spectrophotometric det. of Si
technique(s)UV/Vis spectroscopy: suitable
mp290 ℃ (dec.) (lit.)
SMILES stringNc1c(O)cc(c2ccccc12)S(O)(=O)=O
InChI1S/C10H9NO4S/c11-10-7-4-2-1-3-6(7)9(5-8(10)12)16(13,14)15/h1-5,12H,11H2,(H,13,14,15)
InChI keyRXCMFQDTWCCLBL-UHFFFAOYSA-N

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
398969Sigma-Aldrich4-Amino-3-hydroxy-1-naphthalenesulfonic AcidACS reagent, ≥90%1078.79元/25 G;   展开

产品说明

一般描述

4-Amino-3-hydroxy-1-naphthalenesulfonic acid is a derivative of aniline consisting of a trifunctional monomer (bearing three functional groups –NH2, –OH and –SO3H). It also contains two fused benzene rings.

应用

4-Amino-3-hydroxy-1-naphthalenesulfonic acid has been used as a probe in a novel fluorescence assay for the determination of parathion-methyl.

包装

25 g in poly bottle

基本信息

线性分子式H2NC10H5(OH)SO3H
分子量239.25
Beilstein2697469
EC 号204-147-3
MDL编号MFCD00004019
PubChem化学物质编号24864776
NACRESNA.47

产品性质

质量水平200
等级ACS reagent
测定≥90%
形式powder
灼烧残渣≤0.1%
mp290 ℃ (dec.) (lit.)
痕量阴离子sulfate (SO42-): ≤0.2%
application(s)diagnostic assay manufacturing
hematology
histology
储存温度room temp
SMILES stringNc1c(O)cc(c2ccccc12)S(O)(=O)=O
InChI1S/C10H9NO4S/c11-10-7-4-2-1-3-6(7)9(5-8(10)12)16(13,14)15/h1-5,12H,11H2,(H,13,14,15)
InChI keyRXCMFQDTWCCLBL-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
448725Fluorochem4-Amino-3-hydroxynaphthalene-1-sulfonic acid99%220元/1g;   308元/25g;   990元/100g;   7414元/1kg;   展开

基本信息

CAS Number116-63-2
MDL NumberMFCD00004019

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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