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CAS: 116-17-6
分子式: C9H21O3P
分子量: 208.24
沸点: 63-64 °C/11 mm Hg(lit.)
中文名称: 
亚磷酸三异丙酯
英文名称: 
phosphorous acid triisopropyl ester
isopropyl phosphite ((c3h7o)3p)
tri-isopropyl phosphit
phosphorous acid, triisopropyl ester
phosphorous acid, tris(1-methylethyl) ester
tri-2-propylphosphite
triisopropoxyphosphine
triisopropyl phosphite
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折射率：n20/D 1.411(lit.)
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产品说明

一般描述

This product is provided as delivered and specified by the issuing Pharmacopoeia. All information provided in support of this product, including SDS and any product information leaflets have been developed and issued under the Authority of the issuing Pharmacopoeia.For further information and support please go to the website of the issuing Pharmacopoeia.

包装

Unit quantity: 60 uL. Subject to change. The product is delivered as supplied by the issuing Pharmacopoeia. For the current unit quantity, please visit the EDQM reference substance catalogue.

注意

Please find SDS provided by EDQM here..

其他说明

Sales restrictions may apply.

基本信息

线性分子式[(CH3)2CHO]3P
分子量208.24
Beilstein1701528
MDL编号MFCD00008874
PubChem化学物质编号329831268
NACRESNA.24

产品性质

等级pharmaceutical primary standard
蒸汽压<2 mmHg ( 20 ℃)
manufacturer/tradenameEDQM
折射率n20/D 1.411 (lit.)
bp63-64 ℃/11 mmHg (lit.)
密度0.844 g/mL at 25 ℃ (lit.)
application(s)pharmaceutical (small molecule)
格式neat
运输wet ice
储存温度−20℃
SMILES stringCC(C)OP(OC(C)C)OC(C)C
InChI1S/C9H21O3P/c1-7(2)10-13(11-8(3)4)12-9(5)6/h7-9H,1-6H3
InChI keySJHCUXCOGGKFAI-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语：Danger
危险声明H301 - H315
预防措施声明P264 - P270 - P280 - P301 + P310 - P302 + P352 - P332 + P313
危险分类Acute Tox. 3 Oral - Skin Irrit. 2
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)154.4 °F - closed cup
闪点(C)68 ℃ - closed cup
T67806Sigma-AldrichTriisopropyl phosphite95%1520.01元/500 ML;   展开

产品说明

应用

亚磷酸三异丙酯可作为反应剂：

  • 与钌亚茚基 (ruthenium indenylidene) 复合物形成复分解反应的第一代复合物。
  • 在Perkow反应中用于合成含极化碳碳双键的化合物。
  • 与芳香胺和亚硝酸异戊酯反应合成膦酰肼。

它还可在光延反应中替代三苯基膦，方便产物分离。

包装

100, 500 mL in glass bottle

基本信息

线性分子式[(CH3)2CHO]3P
分子量208.24
Beilstein1701528
EC 号204-130-0
MDL编号MFCD00008874
PubChem化学物质编号24900404
NACRESNA.22

产品性质

蒸汽压<2 mmHg ( 20 ℃)
质量水平200
测定95%
折射率n20/D 1.411 (lit.)
bp63-64 ℃/11 mmHg (lit.)
密度0.844 g/mL at 25 ℃ (lit.)
SMILES stringCC(C)OP(OC(C)C)OC(C)C
InChI1S/C9H21O3P/c1-7(2)10-13(11-8(3)4)12-9(5)6/h7-9H,1-6H3
InChI keySJHCUXCOGGKFAI-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语：Danger
危险声明H301 - H315
预防措施声明P301 + P310 + P330 - P302 + P352
危险分类Acute Tox. 3 Oral - Skin Irrit. 2
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)154.4 °F - closed cup
闪点(C)68 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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