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CAS: 116-09-6
分子式: C3H6O2
分子量: 74.08
沸点: 145℃
熔点: −17 °C(lit.)
中文名称: 
羟基丙酮
羟丙酮
英文名称: 
1-Hydroxy-2-propanone
1-hydroxy-2-Propanone
2-oxopropanol
1-hydroxy-2-propanon
acetone alcohol
acetylcarbinol
acetylmethanol
alpha-hydroxyacetone
hydroxyacetone
hydroxymethyl methyl ketone
hydroxypropanone
1-hydroxy-propan-2-one
2-Propanone,1-hydroxy-
展开更多英文名
性质描述: 无色液体。凝固点-17℃,沸点145-146℃,96-97℃(20kPa)。溶于水、乙醇、乙醚。存在于啤酒、烟草、蜂密中。该品不稳定,可加甲醇使基稳定。
生产方法: 取氢氧化钾、无水甲醇及甲酸乙酯一起回流2h,制成甲酸钾的甲醇溶液。将其与溴丙酮加热回流,反应16h,反应毕冷却至0℃,滤除溴化钾,取滤液蒸馏,收集40-43℃(1.6kPa)馏分,得羟基丙酮,收率54-58%。
用途: 有机合成中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
H811209MACKLIN丙酮醇95%46元/25g;   148元/100g;   663元/500g;   3118元/2.5kg;   展开
储存:2-8℃,干燥
状态:无色到淡黄色液体
折射率:n20/D 1.425(lit.)
H0388TCIHydroxyacetone (stabilized with Na2CO3)>90.0%(GC)135元/25ML;   320元/100ML;   750元/500ML;   展开

基本信息

纯度/分析方法>90.0%(GC)
分子式/分子量C3H6O2 = 74.08
外观与形状(20℃)液体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿),加热
Reaxys-RN605368
PubChem物质ID87570796
SDBS (AIST Spectral DB)13286
MDL编号MFCD00004669

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 90.0 %

物性(参考值)

闪点57 ℃
比重1.08
折射率1.42
水溶性完全混溶
溶解性(可与之混溶)

安全信息

图形或危害标志
信号词警告
危险性说明H303 : 吞咽可能有害。
H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P312 : 如感觉不适,呼叫急救中心/医生。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P403 + P235 : 存放在通风良好的地方。保持低温。

相关法规

RTECS#UC2800000

运输信息

UN编号UN1993
类别3
包装类别 III
监管条件代码(*)
325287J&KHydroxyacetone92%179元/100G;   654元/500G;   展开

基本信息

分子式C3H6O2
分子量74.08
熔点-17
沸点145-146
闪点56
密度1.082
折光率(n20D)1.4200-1.4280
MDL编码MFCD00004669
Beilstein605368
Merck14,65
EINECS 编号204-124-8
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H226
防范说明P210
P233
P240
P241+P242+P243
P280
P303+P361+P353
P312
P403+P235
P501
UN号码1224
危险分类3
包装等级III
WGK1
RTECSUC2800000
L15008Alfa AesarHydroxyacetone95%272元/100g;   1008元/500g;   展开

应用
Hydroxyacetone is used as a reagent in organic chemical reactions. It also serves as a component for Mannich reaction and aldol reactions. It is also used in the syntheses of 2-oxo-propionaldehyde, imidazoles, polyols, acrolein, dyes and skin tanning agents. It yields (R)-1,2-propanediol upon reduction of hydroxyacetone in the presence of a microbial cell catalyst.

备注
Store in cool place. Air sensitive and hygroscopic. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong acids.

基本信息

MDL
MFCD00004669

EINECS
204-124-8

分子式
C3H6O2

分子量
74.08

熔点
-17°

沸点
145-146°

闪点
56°(132°F)

密度
1.080

折射率
1.4250

灵敏度
Keep Cold. Hygroscopic.

溶解性
Miscible with water, alcohol and ether.

Beilstein
605368

Merck
14,65

GHS危害和防范说明

GHS符号

Hazard Statements
H226
Flammable liquid and vapour.

Precautionary Statements
P210-P280a-P240-P241-P303+P361+P353-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Wear protective gloves and eye/face protection.Ground/bond container and receiving equipment.Use explosion-proof electrical/ventilating/lighting/ equipment.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

RTECS
UC2800000

TSCA

C16034Alfa AesarHydroxyacetonetechnical566元/100g;   2118元/500g;   展开

基本信息

Ref#
16034

MDL
4669

分子式
C3 H6 O2

分子量
74.08

闪点
56

密度
1.08

安全信息

危险等级
3

包装组
III

097598FluorochemHydroxyacetone>80%374元/25ml;   638元/100ml;   1848元/500ml;   展开

基本信息

CAS Number116-09-6
MDL NumberMFCD00004669
Boiling Point135.89℃
Melting Point67.26℃
Density1.083

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H303: May be harmful if swallowed
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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