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CAS: 1155422-69-7
分子式: C46H67Cl2N2PRuS
分子量: 881.04
中文名称: 
三环己基膦[1,3-双(2,4,6-三甲基苯基)-4,5-二氢咪唑-2-亚基][(苯硫基)亚甲基]钌(ii)二氯
英文名称: 
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene][(phenylthio)methylene]ruthenium(ii) dichloride
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T959096MACKLIN三环己基膦[1,3-双(2,4,6-三甲基苯基)-4,5-二氢咪唑-2-亚基][(苯硫基)亚甲基]二氯化钌(II)≥95%839元/100mg;   咨询
储存：室温, 避光, 惰性气体
状态：紫褐色固体
44-7780StremTricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene][(phenylthio)methylene]ruthenium(II) dichloride1095元/100mg;   4440元/500mg;   咨询

Technical Notes:

1.Metathesis catalyst, stable in air and can be used in aqueous media .

2.Catalyst of choice for the ring-opening metathesis polymerization of cycloolefins .

3.Catalyst concentration 2-3 times lower than com parable phenyI and vinyI substituted rutheniumcarbenes.

4.Excellent initiator for solvent-free polymerization and control of initiation rates and gelation times.

5.Highly selective catalyst for the ring opening/cross-metathesis of norbornene derivatives.

References:

1.J. Org· Chem.. 2000, 606, 65.

2.“Ring Opening Metathesis Polymerization of Related Chemistry", NATO Science Series II, 2002, 23. 3. 3.Organometallics, 2003, 22, 586.

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