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CAS: 115-86-6
分子式: C18H15O4P
分子量: 326.28
沸点: 244℃(10
熔点: 47-49℃
中文名称: 
磷酸三苯基酯
磷酸三苯酯
三聚磷酸酯
磷酸三苯酯(TPP)
英文名称: 
phosphoric acid,triphenyl ester
Triphenyl phosphate
Phosphoric acid, triphenyl ester
Phosphoric triphenyl ester
celluflex tpp
disflamoll tp
phenyl phosphate ((pho)3po)
phosflex tpp
phosphate de triphenyle
phosphoric acid triphenyl ester
tp
trifenylfosfat
triphenoxyphosphine oxide
triphenylphosphate
展开更多英文名
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T819317MACKLIN磷酸三苯酯分析标准品,≥99.8%(GC)292元/1g;   展开
储存:室温
状态:白色到灰白色晶体或粉末或结晶粉末或熔融固体或片状或颗粒
折射率:1.563
T819319MACKLIN磷酸三苯酯98%29元/25g;   34元/100g;   76元/500g;   278元/2.5kg;   850元/10kg;   展开
储存:室温
状态:白色粉末,片状,或片状
折射率:1.563
P0272TCITriphenyl Phosphate>99.0%(GC)120元/25G;   240元/500G;   展开

基本信息

纯度/分析方法>99.0%(GC)
分子式/分子量C18H15O4P = 326.29
外观与形状(20℃)固体
Reaxys-RN1888236
PubChem物质ID87574511
SDBS (AIST Spectral DB)2915
Merck Index (14)9742
MDL编号MFCD00003031

技术规格

AppearanceWhite to Almost white powder to lump
Purity(GC)min. 99.0 %
Melting point49.0 to 52.0 ℃
Solubility in Toluenealmost transparency

物性(参考值)

熔点50 ℃
沸点220 ℃/11 mmHg
水溶性不溶
在水中的溶解度10 mg/l   20 ℃
溶解性(可溶于)甲苯,苯,醇,氯仿,乙醚,丙酮

安全信息

图形或危害标志
信号词警告
危险性说明H303 : 吞咽可能有害。
H320 : 造成眼刺激。
H410 : 对水生生物毒性极大并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P264 : 作业后彻底清洗皮肤。
P312 : 如感觉不适,呼叫急救中心/医生。
P391 : 收集溢出物。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。

相关法规

RTECS#TC8400000

运输信息

UN编号UN3077
类别9
包装类别 III
监管条件代码(*)
246559J&KTriphenylphosphate99%60元/50G;   102元/250G;   336元/1KG;   739元/2.5KG;   展开

基本信息

分子式C18H15O4P
分子量326.29
熔点48-50
沸点244
闪点220
MDL编码MFCD00003031
Beilstein1888236
Merck14,9742
EINECS 编号204-112-2

安全信息

图形或危害标志
提示语Warning
危险说明H410
防范说明P273
UN号码3077
危险分类9
包装等级III
WGK2
RTECSTC8400000
TSCA
93-1562StremTriphenylphosphate98%1224元/500g;   展开
L08130Alfa AesarTriphenyl Phosphate98%383元/250g;   1046元/1000g;   展开

应用
Triphenyl phosphate is used as an internal standard in the screening and quantification of agrochemical residues in vegetables and fruits. It is used in plastic processing and molding of plastic flow and performance.

备注
Incompatible with oxidizing agents and moisture. Store under dry inert gas. Protect from humidity and water.

基本信息

MDL
MFCD00003031

EINECS
204-112-2

分子式
C18H15O4P

分子量
326.29

熔点
48-52°

沸点
247-250°/11mm

闪点
223°(433°F)

灵敏度
Ambient temperatures.

溶解性
Reacts with water.

Beilstein
1888236

Merck
14,9742

GHS危害和防范说明

GHS符号

Hazard Statements
H400-H410
Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

安全信息

危险等级
9

包装组
III

危险类别
50/53
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
60-61
This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
TC8400000

TSCA

C14767Alfa AesarTriphenyl Phosphate99+%421元/250g;   868元/1kg;   1753元/2.5kg;   3167元/5kg;   展开

基本信息

Ref#
14767

MDL
3031

分子式
C18 H15 O4 P

分子量
326.28

闪点
220

形态
White flakes and chips

安全信息

危险等级
9

包装组
III

R10630Alfa AesarTriphenyl phosphate Standard solution100ppm335元/1ml;   展开

安全信息

危险等级
3

05498SupelcoTriphenyl PhosphateTraceCERT®, 31P-qNMR Standard, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland2588.77元/1G;   展开

产品说明

一般描述

该有证标准物质(CRM)是根据ISO/IEC 17025ISO 17034生产和认证的。该CRM可追溯来自NMI的原始材料,如NIST或NMIJ。
NMR 定量信息已包括在认证内容中。证书上已给出不确定性和失效日期。
在以下网址下载证书:http://www.sigma-aldrich.com

其他说明

Ion Mobility: TWCCSN2 value of 169.2 Å2 [M+H]+ and 180.3 Å2 [M+Na]+

The collision cross section (CCS) measurement was provided by Waters Corporation, using the SYNAPT XS mass spectrometer.
For a description and overview of how ion mobility enables the measurement of the CCS of an ion visit ims.waters.com.
Further information on the SYNAPT XS mass spectrometer can be found on the IMS microsite and product webpage.

TWCCS measurements are expected to be within 2% of this reference value.

P/N 05498 is part of the Waters Extractables & Leachables UNIFI scientific library which can be downloaded from Waters Marketplace.

法律信息

TraceCERT is a registered trademark of sigma-aldrich Co. LLC

基本信息

线性分子式(C6H5O)3PO
分子量326.28
Beilstein1888236
EC 号204-112-2
MDL编号MFCD00003031
PubChem化学物质编号329748075
NACRESNA.24

产品性质

质量水平300
蒸汽压1.3 mmHg ( 200 ℃)
产品线TraceCERT®
等级TraceCERT®
保质期limited shelf life, expiry date on the label
technique(s)qNMR: suitable
bp244 ℃/10 mmHg (lit.)
mp48-50 ℃ (lit.)
application(s)cleaning products
cosmetics
flavors and fragrances
food and beverages
personal care
SMILES stringO=P(Oc1ccccc1)(Oc2ccccc2)Oc3ccccc3
InChI1S/C18H15O4P/c19-23(20-16-10-4-1-5-11-16,21-17-12-6-2-7-13-17)22-18-14-8-3-9-15-18/h1-15H
InChI keyXZZNDPSIHUTMOC-UHFFFAOYSA-N

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)446.0 °F
闪点(C)> 230 ℃
241288Sigma-AldrichTriphenyl Phosphate≥99%413.68元/50 G;   展开

产品说明

一般描述

测定了母乳样品中有机磷阻燃剂磷酸三苯酯的含量。

应用

磷酸三苯酯被用作蔬菜和水果中农药残留的筛选和定量的内标。

包装

50 g in glass bottle

基本信息

线性分子式(C6H5O)3PO
分子量326.28
Beilstein1888236
EC 号204-112-2
MDL编号MFCD00003031
PubChem化学物质编号24854472
NACRESNA.22

产品性质

质量水平200
蒸汽压1.3 mmHg ( 200 ℃)
测定≥99%
bp244 ℃/10 mmHg (lit.)
mp48-50 ℃ (lit.)
溶解性acetone: soluble(lit.)
alcohol: moderately soluble(lit.)
benzene: soluble(lit.)
chloroform: soluble(lit.)
diethyl ether: soluble(lit.)
water: insoluble(lit.)
SMILES stringO=P(Oc1ccccc1)(Oc2ccccc2)Oc3ccccc3
InChI1S/C18H15O4P/c19-23(20-16-10-4-1-5-11-16,21-17-12-6-2-7-13-17)22-18-14-8-3-9-15-18/h1-15H
InChI keyXZZNDPSIHUTMOC-UHFFFAOYSA-N

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)446.0 °F
闪点(C)> 230 ℃
个人防护装备Eyeshields, Gloves
8.21197Sigma-AldrichTriphenyl Phosphatefor synthesis281.4元/100 G;   625.47元/1 KG;   展开

产品说明

分析说明

Assay (GC, area%): ≥ 99.0 % (a/a)
Melting range (lower value): ≥ 48 °C
Melting range (upper value): ≤ 50 °C
Identity (IR): passes test

基本信息

线性分子式(C6H5O)3PO
分子量326.28
MDL编号MFCD00003031
EC索引号204-112-2

产品性质

质量水平200
蒸汽压<0.01 hPa ( 20 ℃)
测定≥99.0% (GC)
自燃温度>500 ℃
效能3500 mg/kg LD50, oral (Rat)
>7900 mg/kg LD50, skin (Rabbit)
bp220 ℃/5 hPa
mp48-50 ℃
转变温度flash point >230 ℃
溶解性 0.0019 g/L
堆积密度650 kg/m3
储存温度2-30℃
InChI1S/C18H15O4P/c19-23(20-16-10-4-1-5-11-16,21-17-12-6-2-7-13-17)22-18-14-8-3-9-15-18/h1-15H
InChI keyXZZNDPSIHUTMOC-UHFFFAOYSA-N

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)446.0 °F
闪点(C)> 230 ℃
442829SupelcoTriphenyl Phosphateanalytical standard382.8元/1000 MG;   展开

产品说明

应用

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

基本信息

线性分子式(C6H5O)3PO
分子量326.28
Beilstein1888236
EC 号204-112-2
MDL编号MFCD00003031
PubChem化学物质编号24868016

产品性质

质量水平200
等级analytical standard
蒸汽压1.3 mmHg ( 200 ℃)
CofAcurrent certificate can be downloaded
包装ampule of 1000 mg
technique(s)HPLC: suitable
gas chromatography (GC): suitable
bp244 ℃/10 mmHg (lit.)
mp48-50 ℃ (lit.)
溶解性H2O: 0.0019 g/L at 20 ℃
application(s)environmental
格式neat
储存温度2-30℃
SMILES stringO=P(Oc1ccccc1)(Oc2ccccc2)Oc3ccccc3
InChI1S/C18H15O4P/c19-23(20-16-10-4-1-5-11-16,21-17-12-6-2-7-13-17)22-18-14-8-3-9-15-18/h1-15H
InChI keyXZZNDPSIHUTMOC-UHFFFAOYSA-N

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)446.0 °F
闪点(C)> 230 ℃
个人防护装备Eyeshields, Gloves
M-507-ISAccuStandardTriphenylphosphate ,0.5 mg/mL in MtBE0.5 mg/mL in MtBE154元/1mL;   展开
Triphenylphosphate三苯基膦115-86-6.5 mg/mL
M-507-IS-10XAccuStandardTriphenylphosphate ,5.0 mg/mL in MtBE5.0 mg/mL in MtBE309元/1mL;   展开
Triphenylphosphate三苯基膦115-86-6.5 mg/mL
M-507-IS-PAKAccuStandardTriphenylphosphate,0.5 mg/mL in MtBE0.5 mg/mL in MtBE760元/5×1mL;   展开
P-192NAccuStandardTriphenylphosphate185元/10mg;   展开
Triphenylphosphate三苯基膦115-86-6
P-192NB-250AccuStandardTriphenylphosphate386元/250mg;   展开
Triphenylphosphate三苯基膦115-86-6
P-192SAccuStandardTriphenylphosphate,100 μg/mL in MeOH100 μg/mL in MeOH185元/1mL;   展开
Triphenylphosphate三苯基膦115-86-6100 µg/mL
P-192S-10XAccuStandardTriphenylphosphate,1000 μg/mL in Methanol1000 μg/mL in Methanol386元/1mL;   展开
Triphenylphosphate三苯基膦115-86-6100 µg/mL
095390FluorochemTriphenyl Phosphate>99.0%(GC)374元/25g;   660元/500g;   展开

基本信息

CAS Number115-86-6
MDL NumberMFCD00003031
Boiling Point220℃
Melting Point50℃
Density1.19

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H400: Very toxic to aquatic life.
H410: Very toxic to aquatic life with long lasting effects.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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