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CAS: 115-27-5
分子式: C9H2Cl6O3
分子量: 370.85
熔点: 235-239°C (Lit.)
中文名称: 
4,5,6,7,8,8-六氯-3A,4,7,7A-四氢-4,7-亚甲基异苯并呋喃-1,3-二酮
氯桥酸酐
4,5,6,7,8,8-六氯-3A,4,7,7A-四氢-4,7-亚甲基异苯并呋喃-1,3
氯菌酸酐
六氯桥墩甲撑四氢苯二甲酸酐
六氯降冰片烯二酸酐
4,5,6,7,8,8-六氯-3α,4,7,7α-四氢-亚甲基异苯并呋喃-1,3-二酮
六氯内亚甲基四氢苯二甲酸酐
1,4,5,6,7,7-六氯-降冰片烯-2,3-二羧酸酐
六氯桥亚甲基四氢酞酸酐
1,4,5,6,7,7-六氯二环(2,2,1)-5-庚烯-2,3-二羧酸酐
展开更多中文名
英文名称: 
,7-methanoisobenzofuran-1,3-dione,4,5,6,7,8,8-hexachloro-3a,4,7,7a-
1,4,5,6,7,7-Hexachloro-5-norbornene-2,3-dicarbosylic anhydride
4,7-Methanoisobenzofuran-1,3-dione,4,5,6,7,8,8-hexachloro-3a,4,7,7a-t
4,7-Methanoisobenzofuran-1,3-dione,4,5,6,7,8,8-hexachloro-3a,4,7,7a-tetrahydro-
7-Methanoisobenzofuran-1,3-dione, 4,5,6,7,8,8-hexachloro-3a,4,7,7a-tetrahydro-4
1,4,5,6,7,7-Hexachlorobicyclo[2.2.1]-5-heptene-2,3-dicarboxylic acid anhydride
1,4,5,6,7,7-hexachloro-5-norbornene-3-dicarboxylic anhydride
1,4,5,6,7,7-hexachloro-endo-5-norbornene-2,3-dicarboxylic anhydride
1,4,5,6,7,7-hexachloro-endo-bicyclo(2.2.1)hept-5-ene-2,3-dicarboxylic anhydride
1,4,5,6,7,7-hexachlorobicyclo-(2,2,1)-5-heptene-2,3-dicarboxylic anhydride
4,7-methanoisobenzofuran-1,3-dione, 4,5,6,7,8,8-hexachloro-3a,4,7,7a-tetrahyd
chloran 542
chlorendic anhydride
het anhydride
hexachloro-5-norbornene-2,3-dicarboxylic anhydride
hexachloroendomethylene tetrahydrophthalic anhydride
1,4,5,6,7,7-hexachloro-5-norbornene-3-dicarboxylic anhydride
展开更多英文名
性质描述: 白色结晶。熔点231-235℃。溶解度(g/100g):苯为40.4,已烷4.5,丙酮127.0,四氯化碳6.7,微溶于水并水解成氯桥酸。
生产方法: 由六氯环戊二烯与顺酐反应而得。将六氯环戊二烯与顺酐按1:1.1的摩尔比混合在溶剂氯苯中,在140-145℃反应7-8h后,将反应产物加入水中水解,在70℃时水解得到的氯桥酸成为油状液体,加热到96-97℃时与水混溶,冷却后成为含一结晶水的氯桥酸(Het acid[115-28-6])。若反应产物用热水及稀乙酸进行结晶,一水合物经100-105℃干燥,即得氯桥酸酐。
用途: 氯桥酸酐和氯桥酸都是反应型阻燃剂,适用于不饱和聚酯、聚氨酯和环氧树脂,也用作环氧树脂固化剂。由该品固化的环氧树脂制品的热变形温度约180℃,耐药性好,氯桥酸也作为染料中间体和杀虫剂。也用作织物的阻燃剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
C832717MACKLIN氯菌酸酐95%32元/10g;   44元/50g;   90元/250g;   240元/1kg;   1199元/5kg;   展开
储存:室温,干燥,密封
状态:白色结晶
H0349TCIHet Anhydride>95.0%(T)160元/25G;   630元/500G;   展开

基本信息

纯度/分析方法>95.0%(T)
分子式/分子量C9H2Cl6O3 = 370.81
外观与形状(20℃)固体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解),加热
Reaxys-RN92693
PubChem物质ID87570765
SDBS (AIST Spectral DB)4558
Merck Index (14)2086
MDL编号MFCD00080438

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(Neutralization titration)min. 95.0 %
Melting point235.0 to 242.0 ℃
Solubility in Toluenevery faint turbidity

物性(参考值)

熔点238 ℃
水溶性微溶
溶解性(可溶于)丙酮,苯,甲苯

安全信息

图形或危害标志
信号词警告
危险性说明H303 : 吞咽可能有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H373 : 长期或反复接触可能损害器官。
H317 : 可能造成皮肤过敏反应。
H335 : 可能造成呼吸道刺激。
H412 : 对水生生物有害并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P272 : 受沾染的工作服不得带出工作场地。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P312 : 如感觉不适,呼叫急救中心/医生。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P333 + P313 : 如发生皮肤刺激或皮疹:求医/就诊。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P405 : 存放处须加锁。

相关法规

RTECS#RB9080000
313268J&KChlorendic Anhydride96%259元/50G;   549元/500G;   展开

基本信息

分子式C9H2Cl6O3
分子量370.83
熔点235-239
MDL编码MFCD00080438
Beilstein92693
Merck14,2086
EINECS 编号204-077-3

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
H351
H373
H412
防范说明P273
P305+P351+P338
WGK3
RTECSRB9080000
TSCA
L07349Alfa AesarChlorendic Anhydride95%, may cont. up to 3% chlorendic acid412元/50g;   600元/250g;   1628元/1000g;   展开

应用
Chlorendic anhydride is used in the synthesis of polymers, used in production of fiberglass-reinforced resins for chemical industry equipment. It can be used to make alkyd resins for use in special inks and paints. It is used as a hardening agent in epoxy resins used in manufacture of printed circuit boards

备注
Moisture Sensitive. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

基本信息

MDL
MFCD00080438

EINECS
204-077-3

分子式
C9H2Cl6O3

分子量
370.83

熔点
235-239°

密度
1.730

灵敏度
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Powder and/or Lumps

溶解性
Insoluble in water.

Beilstein
92693

Merck
14,2086

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H351-H335
Causes skin irritation.Causes serious eye irritation.Suspected of causing cancer.May cause respiratory irritation.

Precautionary Statements
P201-P261-P280-P305+P351+P338-P405-P501a
Obtain special instructions before use.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
40-36/37/38
Limited evidence of a carcinogenic effect.Irritating to eyes, respiratory system and skin.

安全等级
25-26-36/37-60
Avoid contact with eyes.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
RB9080000

TSCA

FRS-001NAccuStandardChlorendic Anhydride232元/10mg;   展开
Chlorendic anhydride氯菌酸酐115-27-5
237166Fluorochem4,5,6,7,8,8-Hexachloro-3a,4,7,7a-tetrahydro-4,7-methanoisobenzofuran-1,3-dione95%374元/25g;   1320元/500g;   展开

基本信息

CAS Number115-27-5
MDL NumberMFCD00080438
Melting Point238℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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