CAS 1148-79-4; 2,2':6',2''-三吡啶; 2,2':6',2"-Terpyridine

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T818516

MACKLIN

2,2':6',2''-三吡啶

98%

41元/250mg; 149元/1g; 650元/5g; 2635元/25g;

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储存：室温
状态：黄色到黄绿色到棕色粉末或晶体

T909427

MACKLIN

2,2':6',2"-三吡啶

for spectrophotometric det. of Ag, Fe, Ru, ≥98.5%

329元/250mg;

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储存：室温
状态：黄色到黄色-绿色到棕色粉末或晶体

T0024

TCI

2,2':6',2''-Terpyridine

>98.0%(GC)(T)

245元/100MG; 480元/200MG; 1310元/1G;

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基本信息

纯度/分析方法	>98.0%(GC)(T)
分子式/分子量	C₁₅H₁₁N₃ = 233.27
外观与形状(20℃)	固体
Reaxys-RN	11199
PubChem物质ID	87576048
SDBS (AIST Spectral DB)	10824
MDL编号	MFCD00006213

技术规格

Appearance	White to Light yellow to Green powder to crystal
Purity(GC)	min. 98.0 %
Purity(Nonaqueous Titration)	min. 98.0 %
Melting point	91.0 to 95.0 ℃

物性(参考值)

熔点	92 ℃
沸点	370 ℃

安全信息

图形或危害标志
信号词	危险
危险性说明	H300 + H310 : 吞咽或皮肤接触致命。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P270 : 使用本产品时不要进食、饮水或吸烟。 P262 : 严防进入眼中、接触皮肤或衣服。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P361 + P364 : 立即脱掉所有沾染的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P310 + P330 : 如误吞咽：立即呼叫急救中心/医生。漱口。 P302 + P352 + P310 : 如皮肤沾染：用水充分清洗。立即呼叫急救中心/医生。 P405 : 存放处须加锁。

运输信息

UN编号	UN2811
类别	6.1
包装类别	I
监管条件代码(*)

500947

J&K

2,2':6',2''-Terpyridine

98%

450元/250MG; 1055元/1G; 4512元/5G;

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基本信息

分子式	C₁₅H₁₁N₃
分子量	233.27
熔点	89-91
MDL编码	MFCD00006213
Beilstein	11199
EINECS 编号	214-559-5

安全信息

图形或危害标志
提示语	Danger
危险说明	EUH070 H300 H310 H315 H338 H335
防范说明	P261 P264 P280 P301+P310 P302+P350 P305+P351+P338
UN号码	2811
危险分类	6.1
包装等级	I
WGK	3
TSCA	是

07-1920

Strem

2,2':6',2''-Terpyridine

min. 98%

1501元/1g; 5449元/5g;

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A17750

Alfa Aesar

2,2':6',2''-Terpyridine

97%

1449元/0.25g; 2488元/1g; 11069元/5g;

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应用
2,2';6',2"-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture the racks, ladders and grids, helicates, catenanes and dendrimers. It plays an important role as a ligand in coordination chemistry. Its complexes are employed in the oxidation of alcohols, the carbonylation of aromatic compounds and as oxygen-binding molecules. Functionalized terpyridine ligands were used in semiconductors and solar panels. It forms chealate complexes with europium(III) and terbium(III), which is used in protein labelling.

备注
Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00006213

EINECS
214-559-5

分子式
C₁₅H₁₁N₃

分子量
233.28

熔点
89-92°

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Soluble in most organic solvents.

GHS危害和防范说明

GHS符号

Hazard Statements
H300-H310-H315-H319-H335
Fatal if swallowed.Fatal in contact with skin.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P262-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Do not get in eyes, on skin, or on clothing.Do not get in eyes, on skin, or on clothing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
I

危险类别
27/28-36/37/38
Very toxic in contact with skin and if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-27/28-36/37-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of ... (to be specified by the manufacturer).Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA
是

234672

Sigma-Aldrich

2,2′:6′,2′′-Terpyridine

98%

757元/250 MG; 1493.65元/1 G; 3308.8元/5 G;

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产品说明

一般描述

2,2′:6′,2′′′;-三联吡啶是一种三齿配体，可从 2-乙酰吡啶开始分两步制备。

应用

由于存在 3 个近共面的氮供体原子，2,2′:6′,2′′′;-三吡啶可作为金属结合域形成金属-超分子结构。

包装

250 mg in glass bottle
1, 5 g in glass bottle

基本信息

经验(实验)分子式	C₁₅H₁₁N₃
分子量	233.27
Beilstein	11199
EC 号	214-559-5
MDL编号	MFCD00006213
PubChem化学物质编号	57648035
NACRES	NA.21

产品性质

质量水平	200
测定	98%
mp	89-91 ℃ (lit.)
SMILES string	c1ccc(nc1)-c2cccc(n2)-c3ccccn3
InChI	1S/C15H11N3/c1-3-10-16-12(6-1)14-8-5-9-15(18-14)13-7-2-4-11-17-13/h1-11H
InChI key	DRGAZIDRYFYHIJ-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H300 + H310 - H315 - H318 - H335
预防措施声明	P261 - P262 - P280 - P301 + P310 - P302 + P352 + P310 - P305 + P351 + P338
危险分类	Acute Tox. 1 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

992134

Amethyst

2,2':6',2''-Terpyridine

98%, 用于合成

112元/250MG; 310元/1G; 1240元/5G; 4949元/25G;

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基本信息

分子式	C₁₅H₁₁N₃
分子量	233.27
熔点	89-91
MDL编码	MFCD00006213
Beilstein	11199
EINECS 编号	214-559-5

安全信息

图形或危害标志
提示语	Danger
危险说明	EUH070 H300 H310 H316 H335
防范说明	P280 P305+P351+P338 P308+P313 P314
UN号码	2811
危险分类	6.1
包装等级	I
WGK	3
TSCA	是

237056

Fluorochem

2,2':6',2''-Terpyridine

95%

1628元/1g; 4070元/5g; 11000元/25g;

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基本信息

CAS Number	1148-79-4
MDL Number	MFCD00006213

安全信息

图形或危害标志
危险性说明	H300: Fatal if swallowed. H310: Fatal in contact with skin. H315: Causes skin irritation. H318: Causes serious eye damage. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing P262: Do not get in eyes, on skin, or on clothing. P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302 + P350: IF ON SKIN: Gently wash with plenty of soap and water. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor/physician. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P322: Specific measures (see . on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P361: Remove/Take off immediately all contaminated clothing. P362: Take off contaminated clothing and wash before reuse. P363: Wash contaminated clothing before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to local regulations.