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CAS: 1116-76-3
分子式: C24H51N
分子量: 353.67
沸点: 365-367℃
熔点: 34 °C
中文名称: 
三正辛胺
N,N-二辛基-1-辛胺
三辛胺
英文名称: 
N,N-dioctyl-1-Octanamine
tri-n-Octylamine
n,n-dioctyl-1-octanamin
alamine 308
alamine 336
farmin 08
tri-n-caprylylamine
tricaprylamine
tricaprylylamine
trioctylamine
1-Octanamine,N,N-dioctyl-
TOA
N,N-Dioctyl-1-octanamine
Trioctylamin
展开更多英文名
性质描述: 无色油状液体。熔点-34℃,沸点365.812℃。相对密度(20/4℃)0.811,折光率(nD20)1.449。熔于醇和醚,微溶于甲醇,易溶于非极性溶剂,极微溶于水。有氨的气味,呈碱性。
生产方法: 以正辛醇为原料,在三氯化铝催化剂存在下进行氨化。反应在缩合釜中进行,将氨通入釜中,在400℃反应。然后赶除过剩的正辛醇,滤除催化剂,即得成品三辛胺。原料消耗(kg/t)正辛醇 1217三氧化铝 685
用途: 用作贵金属萃取剂。在冶金工业中,用来萃取分离钴、镍、锕系和镧系元素。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T818834MACKLIN三辛胺98%30元/5ml;   62元/25ml;   109元/100ml;   369元/500ml;   1278元/2.5L;   4562元/10L;   4339元/12X500ml;   展开
储存:室温
状态:无色液体
折射率:n20/D 1.449(lit.)
T818830MACKLIN三辛胺90%39元/25ml;   99元/100ml;   296元/500ml;   916元/2.5L;   展开
储存:室温
状态:无色液体
折射率:n20/D 1.449(lit.)
T820291MACKLIN三辛胺95%43元/25ml;   105元/100ml;   330元/500ml;   1199元/2.5L;   3920元/12X500ml;   展开
储存:室温
状态:无色液体
折射率:n20/D 1.449(lit.)
I0362TCITri-n-octylamine [Reagent for Ion-Pair Chromatography]>98.0%(GC)(T)450元/25ML;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C24H51N = 353.68
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气,湿气 (吸湿)
Reaxys-RN1210618
PubChem物质ID87571715
SDBS (AIST Spectral DB)2925
MDL编号MFCD00009560

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 98.0 %
Purity(Nonaqueous Titration)min. 98.0 %

物性(参考值)

沸点367 ℃
闪点184 ℃
比重0.81
水溶性不溶
在水中的溶解度0.05 mg/l   25 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H410 : 对水生生物毒性极大并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P391 : 收集溢出物。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#RG8225000

运输信息

UN编号UN3082
类别9
包装类别 III
监管条件代码(*)
T0502TCITri-n-octylamine>97.0%(GC)(T)235元/25ML;   460元/100ML;   910元/500ML;   展开

基本信息

纯度/分析方法>97.0%(GC)(T)
分子式/分子量C24H51N = 353.68
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN1210618
PubChem物质ID87576432
SDBS (AIST Spectral DB)2925
MDL编号MFCD00009560

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 97.0 %
Purity(Neutralization titration)min. 97.0 %

物性(参考值)

沸点367 ℃
闪点184 ℃
比重0.81
折射率1.45
水溶性不溶
在水中的溶解度0.05 mg/l   25 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H410 : 对水生生物毒性极大并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P391 : 收集溢出物。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#RG8225000
136152J&KTri-n-octylamine97%96元/25ML;   314元/100ML;   727元/500ML;   展开

基本信息

分子式C24H51N
分子量353.68
熔点-34
沸点365-367
闪点163
密度0.809
折光率(n20D)1.4480-1.4500
MDL编码MFCD00009560
Beilstein1210618
EINECS 编号214-242-1

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK2
RTECSRG8225000
A15067Alfa AesarTri-n-octylamine95%745元/100ml;   2969元/500ml;   11638元/2500ml;   展开

应用
Tri-n-octylamine is used as an extractant for organic acids like trichloroacetic acid, succinic acid, acetic acid and precious metals. It is also used as a solvent and an intermediate in the manufacture of pharmaceuticals. Further, it is employed in the preparation of quaternary ammonium compounds, agrochemicals, surfactants, lubricant additives, corrosion inhibitors, vulcanization accelerators and dyes.

备注
Air sensitive. Incompatible with strong oxidizing agents, carbon dioxide, acids, acid chlorides and acid anhydrides.

基本信息

MDL
MFCD00009560

EINECS
214-242-1

分子式
C24H51N

分子量
353.68

熔点
-39°

沸点
164-168°/0.7mm

闪点
158°(316°F)

密度
0.810

折射率
1.4485

灵敏度
Air Sensitive. Keep Cold.

形态
Liquid

溶解性
Miscible with chloroform. Immiscible with water.

Beilstein
1210618

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H401-H411
Causes skin irritation.Causes serious eye irritation.Toxic to aquatic life.Toxic to aquatic life with long lasting effects.

Precautionary Statements
P273-P280g-P305+P351+P338
Avoid release to the environment.Wear protective gloves.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

安全信息

危险等级
9

包装组
III

危险类别
36/38-51/53
Irritating to eyes and skin.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
26-37-61
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Avoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
RG8225000

TSCA

C14028Alfa AesarTri-n-octylamine97%670元/100ml;   3430元/500ml;   12811元/2.5L;   展开

基本信息

Ref#
14028

MDL
9560

分子式
C24 H51 N

分子量
353.66

闪点
163

密度
0.809

安全信息

危险等级
9

包装组
III

T81000Sigma-AldrichTrioctylamine98%469元/25 G;   718.89元/100 G;   2349.64元/500 G;   8615.46元/2.5 KG;   展开

产品说明

包装

25, 100, 500 g in glass bottle
2.5 kg in glass bottle

应用

三辛胺可作为有机酸(如 TCA、琥珀酸和乙酸)和贵金属的萃取剂。

基本信息

线性分子式[CH3(CH2)7]3N
分子量353.67
Beilstein1210618
EC 号214-242-1
MDL编号MFCD00009560
PubChem化学物质编号24900500
NACRESNA.22

产品性质

质量水平200
测定98%
折射率n20/D 1.449 (lit.)
bp164-168 ℃/0.7 mmHg (lit.)
365-367 ℃ (lit.)
密度0.809 g/mL at 25 ℃ (lit.)
web metadata keyword.defaultTri-n-octylamine, TOA, tri-octylamine, TOA supplier; extractant; surfactant nanowire, fatty acids, nanocyrstals, MnO, ZnO, alkylamine, tri-octylamine; N,N-dioctyl-1-octanamine,
SMILES stringCCCCCCCCN(CCCCCCCC)CCCCCCCC
InChI1S/C24H51N/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3
InChI keyXTAZYLNFDRKIHJ-UHFFFAOYSA-N

安全信息

象形图GHS07GHS09
警示用语:Warning
危险声明H315 - H319 - H411
预防措施声明P264 - P273 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313
危险分类Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 2
闪点(F)334.4 °F
闪点(C)168 ℃
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter
8.08649Sigma-AldrichTrioctylaminefor synthesis282.79元/10 ML;   302.86元/100 ML;   818.89元/500 ML;   展开

产品说明

分析说明

Assay (GC, area%): ≥ 92.5 % (a/a)
Density (d 20 °C/ 4 °C): 0.808 - 0.813
Identity (IR): passes test

基本信息

经验(实验)分子式C24H51N
分子量353.67
MDL编号MFCD00009560
EC索引号214-242-1

产品性质

质量水平200
蒸汽压<0.01 hPa ( 20 ℃)
测定≥92.5% (GC)
形式liquid
自燃温度315 ℃
mp-39 ℃
转变温度flash point 168 ℃
溶解性 <0.0001 g/L
密度0.81 g/cm3 at 20 ℃
储存温度2-30℃
InChI1S/C24H51N/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3
InChI keyXTAZYLNFDRKIHJ-UHFFFAOYSA-N

安全信息

象形图GHS07GHS09
警示用语:Warning
危险声明H315 - H319 - H411
预防措施声明P264 - P273 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313
危险分类Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)334.4 °F
闪点(C)168 ℃
464347FluorochemTrioctylamine95%286元/25g;   660元/100g;   展开

基本信息

CAS Number1116-76-3
MDL NumberMFCD00009560
Boiling Point367℃
Density0.81

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H400: Very toxic to aquatic life.
H410: Very toxic to aquatic life with long lasting effects.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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