基本信息

技术规格

物性(参考值)

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

基本信息

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
TSCA	是

基本信息

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
TSCA	是

Technical Notes：

1.Precursor for the preparation of boron oxide films deposited by MOCVD method

2.CVD precursor for the preparation of boron doped single- and multiwalled carbon nanotubes

3.CVD precursor for the preparation of boron doped titanium dioxide for photocatalytic water reduction and oxidation

4.Precursor for the preparation of B-doped ZnO transparent conductive oxides films deposited by AL D

References:

1.Thin Solid Films 2004, 464-465, 164

2.J. Mater. Chem.. 2008, 18, 5676

3.Phys. Status Solidi B, 2009, 246, 2518

4.Phys. Chem. Chem. Phys., 2013. 15, 16788

5.J. Mater. Chem. A, 2017, 5, 10836

6.J. Mater. Chem. c, 2015, 3, 3095

7. Sol. Energy Mater. Sol. Cells 2017 asap publication to be updated

应用
Tris(pentafluorophenyl)borane is used as an excellent activator component in homogeneous Ziegler-Natta chemistry. It is also used as a catalyst for reductions, alkylations, hydrometallation reactions and catalyzed aldol-type reactions. It is a useful Lewis acid and catalyzes hydrosilylation of aldehydes. Further, it is used in olefin polymerization catalysis. It serves as a reagent in the preparation of organometallic complexes. In addition to this, it is useful as polymerization catalysts and used to study the heterolytic cleavage of dihydrogen in associated with tri-tert-butylphosphine.

备注
Moisture sensitive. Incompatible with strong oxidizing agents and trimethylaluminum.

基本信息

MDL
MFCD00269813

分子式
C₁₈BF₁₅

分子量
511.99

熔点
126-130°

灵敏度
Moisture Sensitive. Store under Nitrogen. Store at -20°C.

形态
Powder

溶解性
Soluble in hexane, chloroform, dichloromethane, toluene, and polar solvents.

Beilstein
2931347

Merck
14,9755

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H315-H319-H335-H400-H410
Toxic if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P261-P280a-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
是

基本信息

Ref#
35313

MDL
269813

分子式
C18 B F15

分子量
511.99

形态
White to pale gray powder

产品说明

一般描述

B(C₆F₅)₃ 是一种路易斯酸，比无机母体分子BF₃更强。与主要的路易斯酸相反，第15族的较重元素的五氟化物，B(C₆F₅)₃ 没有氧化性。B(C₆F₅)₃能与中性和较弱的路易斯碱形成加合物。B(C₆F₅)₃ 具有容易接受与金属键合的阴离子配体的能力。
我们致力于为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了催化效率。 点击此处了解更多信息。

应用

广泛用于制备d⁰ 芳烃 和其他有机金属配合物的通用试剂 可用作聚合催化剂。
与-三叔丁基膦(570958)一起使用，可对在室温和一个大气压下二氢的异质裂解进行研究。

包装

1, 5 g in ampule

特点和优势

多功能试剂，广泛用于制备 d⁰ 芳烃和其他有机金属络合物，可用作聚合反应催化剂。

基本信息

产品性质

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

基本信息

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
TSCA	是

基本信息

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .