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CAS: 110-93-0
分子式: C8H14O
分子量: 126.20
沸点: 73℃(18 t
熔点: -67.1-58℃
中文名称: 
甲基庚烯酮
2-甲基-2-庚烯-6-酮
6-酮-2-甲基庚-2-烯
6-甲基-5-庚烯-2-酮
英文名称: 
6-methylhept-
6-methylhept-5-en
6-methylhept-5-en-2-one
methyl isohexenyl ketone
methylisohexenylketone
6-methyl-hept-5-en-2-one
6-Methyl-5-hepten-2-one,(2-2-6)
2-Methyl-6-oxo-2-heptene
2-Oxo-6-methylhept-5-ene
6-Methyl-Δ5-hepten-2-one
6-Methyl-hept-5-en-2-on
Methyl-(4-methyl-3-pentenyl)-keton
5-heptene-2-one,6-methyl-
2-Methyl-2-hepten-6-one
5-Hepten-2-one,6-methyl-
6-methyl-5-Hepten-2-one
6-methyl-5-hepten-2-on
6-methyl-5-hepten-2-one
methylheptenone
sulcatone
展开更多英文名
性质描述: 无色液体。熔点为-67.1℃,沸点172-174℃,73℃(2.4kPa),58.5℃(1.33kPa),相对密度0.860(20/4℃),折光率1.4445,闪点50℃。能与醇、醚混溶,不溶于水。
生产方法: 甲基庚烯酮广泛存在于各种精油中。工业合成可有多种方法,例如异丁烯、甲醛和丙酮在250℃、30MPa的条件下反应可得到该品。
用途: 该品具有水果香气和新鲜清香香气,我国 GB 2760-86规定为允许使用的食用香料,主要用以配制香蕉、梨、柑橘和浆果类香精。但很少直接作为香料,而用来作为合成香料的原料。例如用来合成假紫罗兰酮和柠檬醛。也用于其他有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M813940MACKLIN甲基庚烯酮98%35元/25ml;   45元/100ml;   190元/500ml;   805元/2.5L;   展开
储存:2~8°C,易燃物区域
状态:无色至淡黄色液体
折射率:n20/D 1.439(lit.)
M0252TCI6-Methyl-5-hepten-2-one>98.0%(GC)150元/25ML;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C8H14O = 126.20
外观与形状(20℃)液体
Reaxys-RN1741705
PubChem物质ID87572337
SDBS (AIST Spectral DB)3575
MDL编号MFCD00008905

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 98.0 %

物性(参考值)

沸点173 ℃
闪点50 ℃
比重0.86

安全信息

图形或危害标志
信号词警告
危险性说明H303 : 吞咽可能有害。
H315 : 造成皮肤刺激。
H402 : 对水生生物有害。
H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P312 : 如感觉不适,呼叫急救中心/医生。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P403 + P235 : 存放在通风良好的地方。保持低温。

相关法规

RTECS#MJ9700000

运输信息

UN编号UN1224
类别3
包装类别 III
监管条件代码(*)
384822J&K6-Methyl-5-hepten-2-one97.5%194元/100ML;   641元/500ML;   展开

基本信息

分子式C8H14O
分子量126.20
沸点73
闪点56
密度0.855
折光率(n20D)1.4390
MDL编码MFCD00008905
Beilstein1741705
EINECS 编号203-816-7

安全信息

图形或危害标志
提示语Warning
危险说明H226
防范说明P262
UN号码1224
危险分类3
包装等级III
WGK1
RTECSMJ9700000
A13335Alfa Aesar6-Methyl-5-hepten-2-one98%364元/25g;   513元/100g;   1612元/500g;   展开

应用
6-Methyl-hepten-2-one is used in the synthesis of thyrsiferyl 23-Acetate which acts as an anti-leukemic inducer of apoptosis.

备注
Store in cool, dry place in tightly closed container.

基本信息

MDL
MFCD00008905

EINECS
203-816-7

分子式
C8H14O

分子量
126.20

熔点
-67°

沸点
172-174°

闪点
56°(133°F)

密度
0.855

折射率
1.4390

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Soluble in methanol and chloroform.

Beilstein
1741705

GHS危害和防范说明

GHS符号

Hazard Statements
H226
Flammable liquid and vapour.

Precautionary Statements
P210-P280a-P240-P241-P303+P361+P353-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Wear protective gloves and eye/face protection.Ground/bond container and receiving equipment.Use explosion-proof electrical/ventilating/lighting/ equipment.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

RTECS
MJ9700000

TSCA

W270733Sigma-Aldrich6-Methyl-5-hepten-2-onenatural, ≥98%, FCC433.21元/;   814.79元/25 G;   2007.3元/100 G;   11980.4元/1 KG;   展开

产品说明

一般描述

6-甲基-5-庚二烯-2-酮是西红柿的主要挥发性香气之一。

包装

25 g in poly bottle
100 g in glass bottle
1 kg in glass bottle

基本信息

线性分子式(CH3)2C=CHCH2CH2COCH3
分子量126.20
FEMA编号2707
Beilstein1741705
EC 号203-816-7
欧洲委员会编号149c
MDL编号MFCD00008905
PubChem化学物质编号24901276
Flavis编号7.015
NACRESNA.21

产品性质

等级Kosher
natural
质量水平400
agencymeets purity specifications of JECFA
reg. complianceFCC
测定≥98%
折射率n20/D 1.439 (lit.)
bp73 ℃/18 mmHg (lit.)
密度0.858 g/mL at 20 ℃
0.855 g/mL at 25 ℃ (lit.)
文件see Safety & Documentation for available documents
性状检查apple; musty; fruity
application(s)flavors and fragrances
食品过敏原no known allergens
SMILES stringC\C(C)=C\CCC(C)=O
InChI1S/C8H14O/c1-7(2)5-4-6-8(3)9/h5H,4,6H2,1-3H3
InChI keyUHEPJGULSIKKTP-UHFFFAOYSA-N

安全信息

象形图GHS02
警示用语:Warning
危险声明H226
危险分类Flam. Liq. 3
储存分类代码3 - Flammable liquids
WGKWGK 1
闪点(F)132.8 °F - closed cup
闪点(C)56 ℃ - closed cup
个人防护装备Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
W270709Sigma-Aldrich6-Methyl-5-hepten-2-one≥98%, FCC, FG404.65元/;   894.89元/1 KG;   3314.9元/8 KG;   7781.54元/20 KG;   展开

产品说明

一般描述

6-Methyl-5-hepten-2-one is one of the main flavor volatile of tomatoes.

包装

20 kg in composite drum
8 kg in steel drum
1 kg in glass bottle

基本信息

线性分子式(CH3)2C=CHCH2CH2COCH3
分子量126.20
FEMA编号2707
Beilstein1741705
EC 号203-816-7
欧洲委员会编号149
MDL编号MFCD00008905
PubChem化学物质编号24901275
Flavis编号7.015
NACRESNA.21

产品性质

质量水平400
生物来源synthetic
等级FG
Halal
Kosher
agencyfollows IFRA guidelines
meets purity specifications of JECFA
reg. complianceEU Regulation 1223/2009
EU Regulation 1334/2008 & 872/2012
FCC
FDA 21 CFR 172.515
测定≥98%
折射率n20/D 1.439 (lit.)
bp73 ℃/18 mmHg (lit.)
密度0.858 g/mL at 20 ℃
0.855 g/mL at 25 ℃ (lit.)
文件see Safety & Documentation for available documents
性状检查apple; musty; fruity
application(s)flavors and fragrances
食品过敏原no known allergens
致敏芳香化合物no known allergens
SMILES stringC\C(C)=C\CCC(C)=O
InChI1S/C8H14O/c1-7(2)5-4-6-8(3)9/h5H,4,6H2,1-3H3
InChI keyUHEPJGULSIKKTP-UHFFFAOYSA-N

安全信息

象形图GHS02
警示用语:Warning
危险声明H226
预防措施声明P210 - P233 - P240 - P241 - P242 - P243
危险分类Flam. Liq. 3
储存分类代码3 - Flammable liquids
WGKWGK 1
闪点(F)132.8 °F - closed cup
闪点(C)56 ℃ - closed cup
个人防护装备Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
242741Fluorochem6-Methylhept-5-en-2-one95%418元/100g;   1034元/500g;   3058元/2kg;   展开

基本信息

CAS Number110-93-0
MDL NumberMFCD00008905
Boiling Point173℃
Density0.86

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H412: Harmful to aquatic life with long lasting effects.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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