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CAS: 110-87-2
分子式: C5H8O
分子量: 84.12
沸点: 89-86℃
熔点: -70-86℃
中文名称: 
2,3-二氢-4H-吡喃
3,4-二氢-2H-吡喃
3,4-二氢(2H)吡喃
3,4-二氢吡喃
英文名称: 
2,3-dihydro-pyran
pyran,dihydro-
δ2-dihydropyran
2,3-dihydro-γ-pyran
2,3-dihydro-4H-pyran
2H-3,4-dihydropyran
3,4-dihydro-2(H)-pyran
5,6-dihydro-4H-pyran
dihydro-2H-pyran
DHP,Dihydropyran,3,4-Dihydro-2H-Pyran
DHP
dihydropyran
2H-Pyran,3,4-dihydro-
3,4-Dihydropyran
3,4-dihydro-2H-Pyran
3,4-dihydro-2h-pyra
3,4-dihydro-2h-pyran
展开更多英文名
性质描述: 无色液体。凝固点-70℃,沸点86-87℃,相对密度0.9221(19/15℃),折光率1.4402(19℃),闪点-15℃。该品在100ml水中可溶解3g,可溶于多数有机溶剂。
生产方法: 由四氢糠醇脱水、扩环而得。
用途: 二氢吡喃化学性质活泼,通过聚合、加氢、氧化等反应可制得四氢吡喃、戊二醇、戊二酸、戊内酯、戊二烯以及树脂类产品。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D0555TCI3,4-Dihydro-2H-pyran>97.0%(GC)120元/25ML;   210元/100ML;   570元/500ML;   展开

基本信息

纯度/分析方法>97.0%(GC)
分子式/分子量C5H8O = 84.12
外观与形状(20℃)液体
Reaxys-RN103493
PubChem物质ID87567211
SDBS (AIST Spectral DB)2119
MDL编号MFCD00006558

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 97.0 %

物性(参考值)

沸点86 ℃
闪点-6 ℃
比重0.93
折射率1.44

安全信息

图形或危害标志
信号词危险
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H225 : 高度易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P403 + P235 : 存放在通风良好的地方。保持低温。

运输信息

UN编号UN2376
类别3
包装类别 II
监管条件代码(*)
391472J&K3,4-Dihydro-2H-pyran98%60元/5G;   140元/100G;   507元/500G;   展开

基本信息

分子式C5H8O
分子量84.12
熔点-70
沸点84-88
闪点-16
密度0.922
折光率(n20D)1.440
MDL编码MFCD00006558
Beilstein103493
EINECS 编号203-810-4

安全信息

图形或危害标志
提示语Danger
危险说明H225
H315
H319
H335
防范说明P210
P261
P305+P351+P338
UN号码2376
危险分类3
包装等级II
WGK3
TSCA
L02731Alfa Aesar3,4-Dihydro-2H-pyran99%276元/25ml;   336元/100ml;   1100元/500ml;   展开

应用
Widely used hydroxyl-protecting reagent3,4-Dihydro-2H-pyran is used as a hydroxyl-protecting reagent in organic synthesis. It acts as an intermediate in synthetic chemistry. It is used to protect various reactive functional groups. It is involved in the polymerization reaction either alone or with unsaturated compound and finds application in polymer industries. Further, it is employed in the preparation of bicyclic compounds of epoxide-fused, halo compounds and allenic alcohols.

备注
Incompatible with oxidizing agents, strong acids and alcohols.

基本信息

MDL
MFCD00006558

EINECS
203-810-4

分子式
C5H8O

分子量
84.12

熔点
-70°

沸点
85-86°

闪点
-15°(5°F)

密度
0.926

折射率
1.4420

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Miscible with water and chloroform.

Beilstein
103493

GHS危害和防范说明

GHS符号

Hazard Statements
H225-H315-H319-H335
Highly flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P210-P261-P280g-P305+P351+P338-P403+P233
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store in a well-ventilated place. Keep container tightly closed.

安全信息

危险等级
3

包装组
II

危险类别
11-36/37/38
Highly flammable.Irritating to eyes, respiratory system and skin.

安全等级
7/9-16-23-26-37
Keep container tightly closed and in a well-ventilated place.Keep away from sources of ignition - No smoking.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

欧盟危险品标志

TSCA

C11478Alfa Aesar3,4-Dihydro-2H-pyran99%515元/100g;   1915元/500g;   展开

基本信息

Ref#
11478

MDL
6558

分子式
C5 H8 O

分子量
84.12

闪点
-9

密度
0.92

形态
Liquid

安全信息

危险等级
3

包装组
II

8.02971Sigma-Aldrich3,4-Dihydro-2H-pyranfor synthesis361.2元/100 ML;   484.11元/250 ML;   展开

产品说明

分析说明

Assay (GC, area%): ≥ 98.0 % (a/a)
Density (d 20 °C/ 4 °C): 0.926 - 0.929
Water (GC): ≤ 0.50 % (a/a)
Identity (IR): passes test

基本信息

经验(实验)分子式C5H8O
分子量84.12
MDL编号MFCD00006558
EC索引号203-810-4

产品性质

质量水平200
蒸汽压77.8 hPa ( 20 ℃)
测定≥98.0% (GC)
自燃温度240 ℃
效能>4000 mg/kg LD50, oral (Rat)
expl. lim.1.1-13.8 % (v/v)
pH值(酸碱度)7 (20 ℃, 5 g/L in H2O)
bp85.5 ℃/1013 hPa
mp-70 ℃
转变温度flash point -9 ℃
溶解性 7.7 g/L
密度0.929 g/cm3 at 20 ℃
储存温度2-30℃
InChI1S/C5H8O/c1-2-4-6-5-3-1/h2,4H,1,3,5H2
InChI keyBUDQDWGNQVEFAC-UHFFFAOYSA-N

安全信息

象形图GHS02GHS07
警示用语:Danger
危险声明H225 - H315 - H317 - H319 - H412
预防措施声明P210 - P233 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338
危险分类Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1B
补充剂危害EUH019
储存分类代码3 - Flammable liquids
WGKWGK 3
闪点(F)5.0 °F - closed cup
闪点(C)-15 ℃ - closed cup
987876Amethyst3,4-Dihydro-2H-pyran98%, 用于合成48元/25ML;   83元/100ML;   310元/500ML;   1236元/2.5L;   展开

基本信息

分子式C5H8O
分子量84.12
熔点-70
沸点84-88
闪点-16
密度0.922
折光率(n20D)1.44 - 1.443
MDL编码MFCD00006558
Beilstein103493
EINECS 编号203-810-4

安全信息

图形或危害标志
提示语Danger
危险说明H225
H315
H319
H335
防范说明P210
P261
P305+P351+P338
UN号码2376
危险分类3
包装等级II
WGK3
TSCA
130700Fluorochem3,4-Dihydro-2H-pyran97%220元/25g;   770元/100g;   1100元/500g;   展开

基本信息

CAS Number110-87-2
MDL NumberMFCD00006558
Boiling Point86℃
Density0.92

安全信息

图形或危害标志
危险性说明 H225: Highly flammable liquid and vapour.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P235: Keep cool.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use CO2, powder or sand for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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