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CAS: 109998-76-7
分子式: C4H16I2N6O6Pt2
分子量: 888.17
熔点: 268 °C
英文名称: 
diiodobisethylenediaminediplatinumiinitr
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货号品牌产品名称规格包装、参考价格
E984939MACKLIN(乙二胺)碘铂(II)二聚硝酸盐96%2600元/250mg;   咨询
储存:室温, 密封, 干燥
状态:固体
78-0600StremDi-mu-iodobis(ethylenediamine)diplatinum(II) nitrate99%2385元/250mg;   7185元/1g;   咨询

Technical Note:

1. Widely used in complex multi-step organic syntheses. This mild hydration catalyst converts hindered and acid/base sensitive nitriles to amides. The amide is released from the metal coordination sphere preventing further hydrolysis to acid. Typically . turnover frequency (TOF) ranges from 16 to 380 h-1 depending on steric factors. For optimal results avoid the presence of coordinating anions especially cyanide and halide.

References:

1.J.Org.Chem.2004, 69, 2327.

2.Org. Lett, 2006. 8. 2643

3.J. Org Chem.. 2009. 74. 5405.

4.Tetrahedron Lett.,2010,51,6422

5. Appl. Sci. 2015, 5, 380. (catalyst review article)

700037Sigma-Aldrich(Ethylenediamine)iodoplatinum(II) dimer dinitrate96%1200.51元/250 MG;   咨询

基本信息

线性分子式C4H16I2N4Pt2 · 2NO3
分子量888.17
MDL编号MFCD00058712
PubChem化学物质编号329762175
NACRESNA.22

产品性质

质量水平100
测定96%
形式solid
reaction suitabilitycore: platinum
reagent type: catalyst
mp268 ℃
SMILES stringI[Pt+].I[Pt+].NCCN.NCCN.[O-][N+]([O-])=O.[O-][N+]([O-])=O
InChI1S/2C2H8N2.2HI.2NO3.2Pt/c2*3-1-2-4;;;2*2-1(3)4;;/h2*1-4H2;2*1H;;;;/q;;;;2*-1;2*+2/p-2
InChI keyNRXMBGQJNZDBOD-UHFFFAOYSA-L

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
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