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CAS: 1099-45-2
分子式: C22H21O2P
分子量: 348.38
熔点: 126-128℃
中文名称: 
乙基(三苯基膦)乙酸酯
(乙氧基羰基亚甲基)三苯基磷烷
英文名称: 
(triphenylphosphoranylidene)-acetic aci ethyl ester
(carbethoxymethylene)triphenylphosphorane,free of carbomethoxymethylene-analogue
(Carbethoxymethylene)triphenylphosphorane
(Ethoxycarbonylmethylene)triphenylphosphorane
Ethyl(triphenylphosphoranyliden)acetate
(Carboethoxymethylene)triphenylphosphorane
Ethyl(triphenylphosphoranylidene)acetate
(Triphenylphosphoranylidene)acetic Acid Ethyl Ester
推荐供应商
货号品牌产品名称规格包装、参考价格详情
E794194MACKLIN乙基(三苯基膦)乙酸酯10mM in DMSO185元/1ml;   展开
储存:-20°C
状态:白色至灰白色粉末、晶体或块状物
E808914MACKLIN乙基(三苯基膦)乙酸酯98%28元/5g;   35元/25g;   105元/100g;   468元/500g;   展开
储存:2~8 °C
状态:白色到灰白色粉末,晶体和/或块状
T1944TCIEthyl (Triphenylphosphoranylidene)acetate>98.0%(HPLC)490元/25G;   1390元/100G;   2490元/250G;   展开

基本信息

纯度/分析方法>98.0%(HPLC)
分子式/分子量C22H21O2P = 348.38
外观与形状(20℃)固体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况空气,加热
Reaxys-RN754639
PubChem物质ID87577647
MDL编号MFCD00009183

技术规格

AppearanceWhite to Light yellow to Light red powder to crystal
Purity(HPLC)min. 98.0 area%
Melting point126.0 to 130.0 ℃

物性(参考值)

熔点130 ℃
347745J&K(Carbethoxymethylene)triphenylphosphorane98%88元/5G;   358元/25G;   1178元/100G;   展开

基本信息

分子式C22H21O2P
分子量348.38
熔点128-130
MDL编码MFCD00009183
Beilstein754639
EINECS 编号214-151-7
存储条件Store at 2-8℃

安全信息

WGK3
TSCA
A12896Alfa Aesar(Ethoxycarbonylmethylene)triphenylphosphorane98+%529元/10g;   2139元/50g;   1496元/25g;   5396元/250g;   3229元/100g;   展开

应用
(Ethoxycarbonylmethylene)triphenylphosphoran is used as a Wittig reagent in organic synthesis. It is used in the preparation of indole from o-nitrobenzaldehydes, coumarins from o-hydroxy acetophenone. It acts as an inhibitor and inhibits the activity of cholinesterase.

备注
Air sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00009183

EINECS
214-151-7

分子式
CH3CH2O2CCH=P(C6H5)3

分子量
348.38

熔点
126-130°

灵敏度
Keep Cold. Air Sensitive. Store under Argon.

形态
Powder

溶解性
Soluble in organic solvents. Insoluble in water.

Beilstein
754639

安全信息

TSCA

C10829Alfa Aesar(Carbethoxymethylene)triphenylphosphorane98+%1324元/25g;   3738元/100g;   16806元/500g;   展开

基本信息

Ref#
10829

MDL
9183

分子式
C22 H21 O2 P

分子量
348.38

形态
White to pale cream/pale yellow powder

安全信息

危险等级
6.1

包装组
III

C5106Sigma-Aldrich(Carbethoxymethylene)triphenylphosphorane95%258.86元/5 G;   964.21元/25 G;   3195.02元/100 G;   展开

产品说明

应用

乙氧甲酰基亚甲基三苯基膦是一种Horner-Wittig试剂,常用于 Horner−Wadsworth−Emmons(HWE)反应。它可用作 (−)-奥司他韦、 (+)-nakadomarin A和(−)-dictyostatin等化合物全合成的反应试剂。

包装

5 g in glass bottle
25, 100 g in poly bottle

基本信息

线性分子式(C6H5)3P=CHCO2CH2CH3
分子量348.37
Beilstein754639
EC 号214-151-7
MDL编号MFCD00009183
PubChem化学物质编号24892754
NACRESNA.22

产品性质

质量水平200
测定95%
reaction suitabilityreaction type: C-C Bond Formation
mp128-130 ℃ (lit.)
储存温度2-8℃
SMILES stringCCOC(=O)C=P(c1ccccc1)(c2ccccc2)c3ccccc3
InChI1S/C22H21O2P/c1-2-24-22(23)18-25(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21/h3-18H,2H2,1H3
InChI keyIIHPVYJPDKJYOU-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
901631Amethyst(Carbethoxymethylene)triphenylphosphorane98%, 用于合成42元/5G;   103元/25G;   313元/100G;   1257元/500G;   展开

基本信息

分子式C22H21O2P
分子量348.38
熔点128-130
MDL编码MFCD00009183
Beilstein754639
EINECS 编号214-151-7
存储条件Store at 2-8℃

安全信息

WGK3
TSCA
003700Fluorochem(Carbethoxymethylene)triphenylphosphorane95%330元/10g;   748元/25g;   1320元/50g;   1980元/100g;   3410元/500g;   展开

基本信息

CAS Number1099-45-2
MDL NumberMFCD00009183

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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