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CAS: 109-57-9
分子式: C4H8N2S
分子量: 116.18
熔点: 69-72℃
中文名称: 
烯丙基硫脲
丙烯基硫脲
1-烯丙基-2-硫脲
N-烯丙基硫脲
硫代芥子胺
硫代芥子油
英文名称: 
N-2-propenylthiourea
Allylthioharnstoff
Allyl thiourea
2-propenyl-Thiourea
1-allyl-2-thio-ure
(2-propenyl)thiourea
1-allyl-2-thiourea
1-allylthiourea
allylthiocarbamide
allylthiomocovina
allylthiourea
aminosin
n-allylthiourea
rhodallin
rhodalline
thiocynamine
thiosinamin
thiosinamine
2-propenyl-thioure
u 19571
Thiourea,2-propenyl-
Allyl sulfocarbamide
Allyl sulfourea
Allyl thiocarbamide
2-Propenyl thiourea
展开更多英文名
性质描述: 白色结晶。熔点76-78.5℃,相对密度1.110。溶于水及乙醇,微溶于乙醚,不溶于苯。有蒜臭。
生产方法: 由氯丙烯与硫氰化钠反应,先将硫氰化钠加热溶解,冷却后加入少量碘化钾,再加入氯丙烯及乙醇,回流16h,冷却分出油层用水洗3-4次得异硫氰酸烯丙酯,用无水氯化钙干燥,蒸馏,收集沸点为140-155℃馏分而得“酯”。然后将其加入氨水中在搅拌下加热至80℃左右,发生猛烈反应,冷却析出结晶,过滤,干燥而得粗品,再经乙醇重结晶而得成品。
用途: 无氰镀铜添加剂、防腐剂、有机合成原料。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
A800459MACKLINN-烯丙基硫脲98%106元/25g;   319元/100g;   985元/500g;   3550元/2.5kg;   展开
储存:室温
状态:白色到灰白色粉末或晶体
A832154MACKLINN-烯丙基硫脲试剂级, 97%310元/100g;   950元/500g;   展开
储存:室温
状态:白色到灰白色粉末或晶体
N767037MACKLINN-烯丙基硫脲10mM in DMSO139元/1ml;   展开
储存:-20°C
A0220TCIN-Allylthiourea>98.0%(T)300元/25G;   680元/100G;   2990元/500G;   展开

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C4H8N2S = 116.18
外观与形状(20℃)固体
Reaxys-RN1071470
PubChem物质ID87561882
SDBS (AIST Spectral DB)3625
Merck Index (14)9362
MDL编号MFCD00004940

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(Volhard Method)min. 98.0 %
Melting point69.0 to 73.0 ℃

物性(参考值)

熔点71 ℃
水溶性可溶
溶解性(可溶于)乙醇,甲醇
溶解性(微溶于)乙醚
溶解性(不溶于)

安全信息

图形或危害标志
信号词危险
危险性说明H301 : 吞咽会中毒。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P405 : 存放处须加锁。

相关法规

RTECS#YR8050000

运输信息

UN编号UN2811
类别6.1
包装类别 III
监管条件代码(*)
158206J&KN-Allylthiourea98%138元/25G;   454元/100G;   1475元/500G;   展开

基本信息

分子式C4H8N2S
分子量116.19
熔点70-72
密度1.110
MDL编码MFCD00004940
Beilstein1071470
Merck14,9362
EINECS 编号203-683-5

安全信息

图形或危害标志
提示语Danger
危险说明H301
防范说明P301+P310
UN号码2811
危险分类6.1
包装等级III
WGK3
RTECSYR8050000
TSCA
L03377Alfa AesarN-Allylthiourea98%318元/25g;   979元/100g;   展开

应用
N-Allylthiourea is a nitrification inhibitor used in the study on the transformation of diclofenac, naproxen and bisoprolol under aerobic and anaerobic conditions. It is also used in medicine to minimize scar tissue in order to fight against a type of dermatitis. Further, it inhibits the growth of transplanted tumors in mice. It acts as a chelating agent. In addition, it is used in cosmetics, preservative and in organic synthesis.

备注
Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00004940

EINECS
203-683-5

分子式
C4H8N2S

分子量
116.19

熔点
70-78°

密度
1.220

灵敏度
Ambient temperatures.

形态
Crystals

溶解性
Soluble in water and alcohol. Slightly soluble in diethyl ether. Insoluble in benzene.

Beilstein
1071470

Merck
14,9362

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H317
Toxic if swallowed.May cause an allergic skin reaction.

Precautionary Statements
P262-P280h-P309-P310
Do not get in eyes, on skin, or on clothing.Wear protective gloves/clothing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.

安全信息

危险等级
6.1

包装组
III

危险类别
25-43
Toxic if swallowed.May cause sensitization by skin contact.

安全等级
20-24-37-45-60
When using do not eat or drink.Avoid contact with skin.Avoid contact with skin.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

RTECS
YR8050000

TSCA

C14880Alfa AesarAllylthiourea98%497元/25g;   1221元/100g;   4662元/500g;   展开

基本信息

Ref#
14880

MDL
4940

分子式
C4 H8 N2 S

分子量
116.18

形态
Powder

安全信息

危险等级
6.1

包装组
III

108804Sigma-AldrichN-Allylthiourea98%600.96元/50 G;   1758.1元/250 G;   展开

产品说明

应用

N-烯丙基硫脲作为硝化抑制剂,被用于研究双氯芬酸、萘普生和比索洛尔在有氧和厌氧条件下的转化。它已可用于医学中,以最大限度减小瘢痕组织并对抗一种皮炎。

包装

50, 250 g in poly bottle

生化/生理作用

N-烯丙基硫脲可抑制小鼠移植瘤的生长。

基本信息

线性分子式CH2=CHCH2NHCSNH2
分子量116.18
Beilstein1071470
EC 号203-683-5
MDL编号MFCD00004940
PubChem化学物质编号24846829

产品性质

质量水平100
测定98%
mp70-72 ℃ (lit.)
溶解性H2O: soluble 30 parts
alcohol: soluble
benzene: insoluble
diethyl ether: slightly soluble
密度1.11 g/mL at 25 ℃ (lit.)
SMILES stringNC(=S)NCC=C
InChI1S/C4H8N2S/c1-2-3-6-4(5)7/h2H,1,3H2,(H3,5,6,7)
InChI keyHTKFORQRBXIQHD-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语:Danger
危险声明H301
预防措施声明P264 - P270 - P301 + P310 - P405 - P501
危险分类Acute Tox. 3 Oral
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
8.08158Sigma-AldrichN-Allylthioureafor synthesis463.79元/25 G;   574.68元/50 G;   1565.59元/250 G;   展开

产品说明

分析说明

Assay (HPLC, area%): ≥ 98.0 % (a/a)
Identity (IR): passes test

基本信息

经验(实验)分子式C4H8N2S
分子量116.18
MDL编号MFCD00004940
EC索引号203-683-5

产品性质

质量水平200
测定≥98.0% (HPLC)
效能200 mg/kg LD50, oral (Rat)
mp70-73 ℃
溶解性 66 g/L
堆积密度550 kg/m3
储存温度2-30℃
InChI1S/C4H8N2S/c1-2-3-6-4(5)7/h2H,1,3H2,(H3,5,6,7)
InChI keyHTKFORQRBXIQHD-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语:Danger
危险声明H301
预防措施声明P264 - P270 - P301 + P310 - P405 - P501
危险分类Acute Tox. 3 Oral
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
018165Fluorochem1-Allyl-2-thiourea97%220元/1g;   902元/25g;   1650元/100g;   5060元/500g;   展开

基本信息

CAS Number109-57-9
MDL NumberMFCD00004940

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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