CAS 109-01-3; N-甲基哌嗪; N-Methyl piperazine

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产品名称

规格

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M813411

MACKLIN

1-甲基哌嗪

98%

29元/25ml; 62元/100ml; 188元/500ml; 748元/2.5L; 5235元/25L;

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储存：室温,易燃物区域,密封
状态：无色液体
折射率：n20/D 1.466(lit.)

M0553

TCI

1-Methylpiperazine

>98.0%(GC)

180元/25ML; 300元/100ML; 1025元/500ML;

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基本信息

纯度/分析方法	>98.0%(GC)
分子式/分子量	C₅H₁₂N₂ = 100.17
外观与形状(20℃)	液体
Reaxys-RN	102724
PubChem物质ID	87572586
SDBS (AIST Spectral DB)	4782
MDL编号	MFCD00005966

技术规格

Appearance	Colorless to Almost colorless clear liquid
Purity(GC)	min. 98.0 %
Purity(Nonaqueous Titration)	min. 97.0 %

物性(参考值)

熔点	-5 ℃
沸点	137 ℃
闪点	42 ℃
比重	0.91
折射率	1.47
水溶性	完全混溶

安全信息

图形或危害标志
信号词	危险
危险性说明	H312 + H332 : 皮肤接触或吸入有害。 H303 : 吞咽可能有害。 H314 : 造成严重皮肤灼伤和眼损伤。 H226 : 易燃液体和蒸气。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P240 : 容器和装载设备接地/等势联接。 P210 : 远离热源/火花/明火/热表面。禁止吸烟。 P233 : 保持容器密闭。 P243 : 采取防止静电放电的措施。 P241 : 使用防爆的电气/通风/照明设备。 P242 : 只能使用不产生火花的工具。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P312 : 如感觉不适，呼叫急救中心/医生。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。 P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。 P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。 P403 + P235 : 存放在通风良好的地方。保持低温。 P405 : 存放处须加锁。

相关法规

RTECS#

TM1225000

运输信息

UN编号	UN2924
类别	3 / 8
包装类别	III
监管条件代码(*)

227406

J&K

1-Methylpiperazine

99%

77元/5G; 174元/100G; 514元/500G;

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基本信息

分子式	C₅H₁₂N₂
分子量	100.16
沸点	135-138
闪点	39
密度	0.903
折光率(n20D)	1.4660
MDL编码	MFCD00005966
Beilstein	102724
EINECS 编号	203-639-5

安全信息

图形或危害标志
提示语	Danger
危险说明	H226 H312 H314 H331
防范说明	P261 P280 P305+P351+P338 P310
UN号码	2734
危险分类	8
次要危险性	3
包装等级	II
WGK	2
RTECS	TM1225000
TSCA	是

A10837

Alfa Aesar

1-Methylpiperazine

98+%

654元/100ml; 2817元/500ml; 10708元/2500ml;

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应用
1-Methylpiperazine is used in the preparation of 2-(4-methyl-1-piperazinylmethyl)acrylophenone. It is involved in the preparation of 1-(4-methoxy-phenyl)-4-methyl-piperazine by reacting with 1-chloro-4-methoxy-benzene. It acts as an intermediate in the synthesis of active pharmaceutical ingredients like ofloxacin, rifampicin, clozapine, sildenafil, trifluoperazine and zopiclone. Further, it is used as a mimic template in the preparation of molecularly imprinted microspheres. In addition to this, it is used in the generation of difunctional strong anion-exchange stationary phase from a 1,4-diazacyclohexane derivative.

备注
Hygroscopic. Moisture sensitive. Incompatible with acids, acid chlorides, acid anhydrides, strong oxidizing agents and carbon dioxide.

基本信息

MDL
MFCD00005966

EINECS
203-639-5

分子式
C₅H₁₂N₂

分子量
100.17

熔点
-6°

沸点
137-139°

闪点
34°(93°F)

密度
0.903

折射率
1.4655

灵敏度
Air Sensitive. Store under Argon. Ambient temperatures.

形态
Liquid

溶解性
Miscible with water and methanol.

Beilstein
102724

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H302-H312-H331-H314-H318
Flammable liquid and vapour.Harmful if swallowed.Harmful in contact with skin.Toxic if inhaled.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P210-P260h-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Keep away from heat/sparks/open flames/hot surfaces. - No smoking.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
10-21/22-34
Flammable.Harmful in contact with skin and if swallowed.Causes burns.

安全等级
20-23-26-36/37/39-45-60
When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
TM1225000

TSCA
是

C15691

Alfa Aesar

1-Methylpiperazine

99%

687元/5g; 810元/100g; 2451元/500g; 12081元/2.5kg;

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基本信息

Ref#
15691

MDL
5966

分子式
C5 H12 N2

分子量
100.16

闪点
42

密度
0.903

形态
Colorless liquid

安全信息

危险等级
8

包装组
II

8.05859

Sigma-Aldrich

1-Methylpiperazine

for synthesis

252.75元/5 ML; 469.06元/250 ML;

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产品说明

分析说明

Assay (GC, area%): ≥ 99.0 % (a/a)
Density (d 20 °C/ 4 °C): 0.901 - 0.903
Water (K. F.): ≤ 0.30 %
Identity (IR): passes test

基本信息

经验(实验)分子式	C₅H₁₂N₂
分子量	100.16
MDL编号	MFCD00005966
EC索引号	203-639-5

产品性质

质量水平	200
蒸汽压	12 hPa ( 20 ℃)
测定	≥99.0% (GC)
形式	liquid
自燃温度	320 ℃
效能	2547 mg/kg LD₅₀, oral (Rat) 1341 mg/kg LD₅₀, skin (Rabbit)
expl. lim.	1.2-9.9 % (v/v)
pH值(酸碱度)	11-12 (20 ℃, 50 g/L in H₂O)
bp	136-138 ℃/1013 hPa
mp	-6 ℃
转变温度	flash point 34 ℃
密度	0.90 g/cm³ at 20 ℃
储存温度	2-30℃
InChI	1S/C5H12N2/c1-7-4-2-6-3-5-7/h6H,2-5H2,1H3
InChI key	PVOAHINGSUIXLS-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H226 - H312 - H314 - H331
预防措施声明	P210 - P233 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类	Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Flam. Liq. 3 - Skin Corr. 1B
储存分类代码	3 - Flammable liquids
WGK	WGK 1
闪点(F)	102.2 °F - closed cup
闪点(C)	39 ℃ - closed cup

022134

Fluorochem

N-Methylpiperazine

99%

264元/25g; 440元/200g; 1540元/900g;

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基本信息

CAS Number	109-01-3
MDL Number	MFCD00005966
Boiling Point	136.66℃
Density	0.902

安全信息

图形或危害标志
危险性说明	H226: Flammable liquid and vapour. H314: Causes severe skin burns and eye damage. H317: May cause an allergic skin reaction. H332: Harmful if inhaled. H361: Suspected of damaging fertility or the unborn child .. H372: Causes damage to organs ..
防范说明	P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from – No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof ./ equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear . P281: Use personal protective equipment as required. P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313: IF exposed or concerned: Get medical advice/ attention. P310: Immediately call a POISON CENTER or doctor/physician. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P314: Get medical advice/attention if you feel unwell. P321: Specific treatment (see . on this label). P333 + P313: If skin irritation or rash occurs: Get medical advice/attention. P363: Wash contaminated clothing before reuse. P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction. P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up. P501: Dispose of contents/container to local regulations.