[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 108-93-0
关键词:       仅模糊查询
CAS: 108-93-0
分子式: C6H12O
分子量: 100.16
沸点: 161℃
熔点: 23-161℃
中文名称: 
环己醇
六氢苯酚
环己醇脱氢催化剂1101型
英文名称: 
Cyclohexanol
Hexahydrophenol
1-cyclohexanol
adronal
adronol
cicloesanolo
cicloesanolo (italian)
cyclohexyl alcohol
cykloheksanol
cykloheksanol (polish)
hexalin
hydralin
hydrophenol
hydroxycyclohexane
naxol
hexahydro-pheno
cyclohexanol dehydrogenation catalyst(1101)
展开更多英文名
性质描述: 无色油状可燃液体,低于凝固点时呈白色结晶。熔点24℃(凝固点25.15℃),沸点161.10℃,相对密度0.9493(20/4℃),折射率1.4648,闪点(开杯)67.2℃,粘度(30℃)41.067mPa·s。可与乙醇、醋酸乙酯、亚麻仁油、芳烃、乙醚、丙酮、氯仿等有机溶剂混溶,微溶于水。与空气混合爆炸极限1.52%-11.1%(体积)。有类似樟脑的气味,具有吸湿性。
生产方法: 工业生产方法主要为苯酚加氢法和环己烷氧化法。1.苯酚加氢法苯酚蒸气和氢气在镍催化剂存在下,在110-185℃、压力1.078-1.471MPa,在管式反应器中进行加氢反应制得环己醇蒸气产品,经换热、冷凝、分离除氢后再精馏得成品。2.环己烷氧化法苯蒸气在镍催化剂存在下,于120-180℃进行加氢反应得环己烷,环己烷氧化制造环己醇根据不同催化剂分为以下三种方法:(1)钴盐催化法 以环烷酸钴,硬脂酸钴或辛酸钴为催化剂。(2)硼酸催化法以硼酸或偏硼酸为催化剂,在空气氧化过程中,硼酸与环己基过氧化氢生成过硼酸环己醇酯,然后再变成硼酸环己醇酯,或者与生成的环己醇结合生成硼酸环己醇酯和偏硼酸环己醇酯。然后水解,油相经提纯即得成品。(3)无催化剂氧化法以环己烷为原料,在压力1.47-1.96MPa,温度170-200℃下,用氧含量为10%-15%的空气氧化得环己基过氧化氢,再经浓缩后,于70-160℃催化分解,即得环己醇和环己酮。
用途: 重要的化工原料,主要用于生产己二酸、己二胺、环己酮、己内酰胺,也可用作肥皂的稳定剂,制造消毒药皂和去垢乳剂,用作橡胶、树脂、硝基纤维、金属皂、油类、酯类、醚类的溶剂,涂料的掺合剂,皮革的脱脂剂、脱膜剂、干洗剂、擦亮剂。环己醇也是纤维整理剂、杀虫剂、增塑剂的原料,环己醇与光气反应得到氯甲酸环己酯,是引发剂过氧化二碳酸二环己酯的中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
C805170MACKLIN环己醇97%45元/500ml;   160元/2.5L;   450元/10L;   展开
储存:室温
折射率:n20/D 1.465(lit.)
C805171MACKLIN环己醇试剂级, ≥98.5 %(GC)56元/500ml;   224元/2.5L;   699元/10L;   670元/12X500ml;   展开
储存:室温
状态:无色到白色固体或蜡状固体或液体
折射率:n20/D 1.465(lit.)
C805169MACKLIN环己醇Standard for GC,>99.0%(GC)58元/5ml;   展开
储存:室温
折射率:n20/D 1.465(lit.)
A17576Alfa AesarCyclohexanol99%284元/100ml;   350元/500ml;   1102元/2500ml;   展开

应用
Cyclohexanol is used in making soaps, dry cleaning agents and plasticizers. It acts as a solvent for rubber, resins, nitrocellulose, metallic soaps, oils, esters and ethers. It is used in the preparation of adipic acid, hexamethylene diamine, cyclohexanone and caprolactam. It acts as a soap stabilizing agent, disinfection medicated soap and detergent emulsion. It is also useful for paint blending agent, leather degreasing agent and polishes.

备注
Hygroscopic. Incompatible with strong oxidizing agents, hydrogen peroxide and nitric acid.

基本信息

MDL
MFCD00003855

EINECS
203-630-6

分子式
C6H12O

分子量
100.16

熔点
23-24°

沸点
160-161°

闪点
67°(152°F)

密度
0.951

折射率
1.4650

灵敏度
Ambient temperatures.

形态
Low melting solid

溶解性
Miscible with ethanol, ethyl ether acetone, chloroform, ethyl acetate, linseed oil and benzene. Slightly miscible with cold water.

Beilstein
906744

Merck
14,2725

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H302-H332-H315-H335
Combustible liquid.Harmful if swallowed.Harmful if inhaled.Causes skin irritation.May cause respiratory irritation.

Precautionary Statements
P210e-P261-P280a-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
20/22-37/38
Harmful by inhalation and if swallowed.Irritating to respiratory system and skin.

安全等级
24/25
Avoid contact with skin and eyes.

欧盟危险品标志

RTECS
GV7875000

TSCA

C14768Alfa AesarCyclohexanol98%986元/1L;   1872元/2.5L;   6252元/10L;   展开

基本信息

Ref#
14768

MDL
3855

分子式
C6 H12 O

分子量
100.16

闪点
67

密度
0.96

形态
Colorless liquid/low-melting solid

T_702C9000PB08Alfa AesarCyclohexanolpure 500ML663元/500ml;   展开

基本信息

Ref#
F50909

MDL
MFCD00003855

分子式
C{6}H{1}{2}O

分子量
100.16

形态
Liquid

C558-500Alfa AesarCYCLOHEXANOL REAGENT 500ML398元/500ml;   展开

基本信息

Ref#
F51694

105899Sigma-AldrichCyclohexanolReagentPlus®, 99%516.42元/25 ML;   602.78元/1 L;   700.96元/2.5 L;   展开

产品说明

一般描述

环己醇是一种脂环醇。工业上,其可在存在Ni/Al2O3催化剂情况下由苯酚氢化而得。也可在存在Co3O4 纳米晶体(催化剂)的情况下,由分子氧氧化环己烷而得。环己酮(K)和环己醇(A)的混合物称为KA油。KA油可由环己烷液相氧化产生。

应用

环己醇可用于制备ε-己内酰胺和己二酸,后两者分别是工业合成尼龙-6和尼龙-6.6的重要前体。

包装

1, 2.5, 3 L in glass bottle
25 mL in glass bottle

法律信息

ReagentPlus is a registered trademark of sigma-aldrich Co. LLC

基本信息

线性分子式C6H11OH
分子量100.16
Beilstein906744
EC 号203-630-6
MDL编号MFCD00003855
eCl@ss39023102
PubChem化学物质编号24846712
NACRESNA.21

产品性质

质量水平200
蒸汽密度3.5 (vs air)
蒸汽压0.98 mmHg ( 25 ℃)
产品线ReagentPlus®
测定99%
自燃温度572 °F
expl. lim.12.25 %
折射率n20/D 1.465 (lit.)
bp160-161 ℃ (lit.)
mp20-22 ℃ (lit.)
密度0.948 g/mL at 25 ℃ (lit.)
SMILES stringOC1CCCCC1
InChI1S/C6H12O/c7-6-4-2-1-3-5-6/h6-7H,1-5H2
InChI keyHPXRVTGHNJAIIH-UHFFFAOYSA-N

安全信息

象形图GHS07GHS09
警示用语:Warning
危险声明H302 + H312 + H332 - H315 - H319 - H335 - H411
预防措施声明P273 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
危险分类Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)147.2 °F - closed cup - DIN 51794
闪点(C)64 ℃ - closed cup - DIN 51794
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
44113SupelcoCyclohexanolanalytical standard3928.38元/5 ML;   展开

产品说明

应用

有关合适的仪器技术的更多信息,请参阅产品的分析证书。想要获得更多支持,请联系技术服务部。

基本信息

线性分子式C6H11OH
分子量100.16
Beilstein906744
EC 号203-630-6
MDL编号MFCD00003855
PubChem化学物质编号329756453
NACRESNA.24

产品性质

质量水平100
等级analytical standard
蒸汽密度3.5 (vs air)
蒸汽压0.98 mmHg ( 25 ℃)
测定≥98.5% (GC)
自燃温度572 °F
保质期limited shelf life, expiry date on the label
expl. lim.12.25 %
technique(s)HPLC: suitable
gas chromatography (GC): suitable
杂质≤0.5% cyclohexanone (GC)
≤0.5% water
折射率n20/D 1.465 (lit.)
bp160-161 ℃ (lit.)
mp20-22 ℃ (lit.)
密度0.948 g/mL at 25 ℃ (lit.)
application(s)cleaning products
cosmetics
flavors and fragrances
food and beverages
personal care
格式neat
SMILES stringOC1CCCCC1
InChI1S/C6H12O/c7-6-4-2-1-3-5-6/h6-7H,1-5H2
InChI keyHPXRVTGHNJAIIH-UHFFFAOYSA-N

安全信息

象形图GHS07GHS09
警示用语:Warning
危险声明H302 + H312 + H332 - H315 - H319 - H335 - H411
预防措施声明P273 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
危险分类Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)147.2 °F - closed cup - DIN 51794
闪点(C)64 ℃ - closed cup - DIN 51794
8.22328Sigma-AldrichCyclohexanolfor synthesis207.78元/100 ML;   356.19元/1 L;   609.84元/2.5 L;   展开

产品说明

分析说明

Assay (GC, area%): ≥ 99.0 % (a/a)
Water (K. F.): ≤ 0.20 %
Identity (IR): passes test
Due to its specific melting range the product may be solid, liquid, a solidified melt or a supercooled melt.

基本信息

线性分子式C6H11OH
分子量100.16
Beilstein906744
MDL编号MFCD00003855
EC索引号203-630-6

产品性质

质量水平200
蒸汽密度3.5 (vs air)
蒸汽压0.98 mmHg ( 25 ℃)
测定≥99% (GC)
形式solid
自燃温度572 °F
效能1400 mg/kg LD50, oral (Rat)
expl. lim.12.25 %
折射率n20/D 1.465 (lit.)
pH值(酸碱度)6.5 (20 ℃, 40 g/L in H2O)
bp160-161 ℃ (lit.)
mp20-22 ℃ (lit.)
溶解性 40 g/L
密度0.948 g/mL at 25 ℃ (lit.)
储存温度2-30℃
SMILES stringOC1CCCCC1
InChI1S/C6H12O/c7-6-4-2-1-3-5-6/h6-7H,1-5H2
InChI keyHPXRVTGHNJAIIH-UHFFFAOYSA-N

安全信息

象形图GHS07GHS09
警示用语:Warning
危险声明H302 + H312 + H332 - H315 - H319 - H335 - H411
预防措施声明P273 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
危险分类Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)147.2 °F - closed cup - DIN 51794
闪点(C)64 ℃ - closed cup - DIN 51794
392462AmethystCyclohexanol98%, 用于合成85元/500ML;   271元/2.5L;   展开

基本信息

分子式C6H12O
分子量100.16
熔点20-23
沸点160-161
闪点68
密度0.948
折光率(n20D)1.4650
MDL编码MFCD00003855
Beilstein906744
Merck14,2725
EINECS 编号203-630-6

安全信息

图形或危害标志
提示语Warning
危险说明H302
H315
H332
H335
防范说明P261
WGK1
RTECSGV7875000
TSCA
094602FluorochemCyclohexanol99%352元/100g;   550元/500g;   792元/1l;   2112元/4L;   展开

基本信息

CAS Number108-93-0
MDL NumberMFCD00003855
Boiling Point160-161?
Melting Point22-24?
Density0.963

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H335: May cause respiratory irritation.
H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9