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CAS: 108-75-8
分子式: C8H11N
分子量: 121.18
沸点: 167-169℃
熔点: -46℃
中文名称: 
2,4,6-三甲基吡啶
三甲基吡啶
可力丁
英文名称: 
2,4,6-Trimethylpyridine
Trimethyl pyridine
2,4,6-trimethyl-Pyridine
2,4,6-trimethyl-pyridin
2,4,6-collidine
2,4,6-kollidin
alpha,gamma,alpha'-collidine
gamma-collidine
s-collidine
sym-collidine
Pyridine,2,4,6-trimethyl-
2,4,6-trimethyl-pyridine
展开更多英文名
用途: 用作色谱分析标准物质,也用作溶剂,有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T743007MACKLIN2,4,6-三甲基吡啶Standard for GC, ≥99.8%(GC)128元/5ml;   展开
储存:2-8°C
状态:液体
T819341MACKLIN2,4,6-三甲基吡啶99%45元/25ml;   130元/100ml;   419元/500ml;   2000元/2.5L;   展开
储存:2~8°C
状态:无色到浅黄色液体
折射率:n20/D 1.498(lit.)
T0716TCI2,4,6-Trimethylpyridine>98.0%(GC)(T)265元/25ML;   710元/100ML;   1750元/500ML;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C8H11N = 121.18
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN107283
PubChem物质ID87576580
SDBS (AIST Spectral DB)4589
Merck Index (14)9718
MDL编号MFCD00006338

技术规格

AppearanceColorless to Yellow clear liquid
Purity(GC)min. 98.0 %
Purity(Nonaqueous Titration)min. 98.0 %

物性(参考值)

熔点-43 ℃
沸点171 ℃
闪点58 ℃
比重0.92
折射率1.50
水溶性可溶
在水中的溶解度35 g/l   20 ℃
溶解性(可与之混溶)乙醚
溶解性(可溶于)氯仿,甲醇,乙醇,苯,丙酮

安全信息

图形或危害标志
信号词危险
危险性说明H311 : 皮肤接触会中毒。
H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P361 + P364 : 立即脱掉所有沾染的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P403 + P235 : 存放在通风良好的地方。保持低温。
P405 : 存放处须加锁。

相关法规

RTECS#UU0970000

运输信息

UN编号UN1992
类别3 / 6.1
包装类别 III
监管条件代码(*)
111237J&K2,4,6-Trimethylpyridine99%106元/25ML;   298元/100ML;   1070元/500ML;   展开

基本信息

分子式C8H11N
分子量121.18
熔点-43
沸点171-172
闪点54
密度0.916
折光率(n20D)1.4980
MDL编码MFCD00006338
Beilstein107283
Merck14,9718
EINECS 编号203-613-3
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H226
H302
H332
H311
H315
H319
H335
防范说明P261
P280
P305+P351+P338
P312
UN号码1992
危险分类3
次要危险性6.1
包装等级III
WGK3
RTECSUU0970000
A11058Alfa Aesar2,4,6-Collidine99%423元/25ml;   982元/100ml;   3642元/500ml;   展开

应用
2,4,6-Collidine is used as a tissue fixative for electron microscopy. It is useful in dehydrohalogenation reactions and acts as a solvent for the cleavage of hindered esters by anhydrous lithium iodide.

备注
Incompatible with oxidizing agents and strong acids.

基本信息

MDL
MFCD00006338

EINECS
203-613-3

分子式
C8H11N

分子量
121.18

熔点
-43°

沸点
171-172°

闪点
54°(129°F)

密度
0.916

折射率
1.4980

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Slightly miscible with water. Miscible with ether, methanol, acetone, chloroform, benzene, toluene and dilute acids.

Beilstein
107283

Merck
14,9718

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H302-H311-H315-H319-H335
Flammable liquid and vapour.Harmful if swallowed.Toxic in contact with skin.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

危险类别
10-21/22-36/37/38
Flammable.Harmful in contact with skin and if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
23-26-36/37-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
UU0970000

TSCA

C16195Alfa Aesar2,4,6-Collidine99%1245元/100ml;   2874元/500ml;   7293元/1L;   13543元/2.5L;   展开

基本信息

Ref#
16195

MDL
6338

分子式
C8 H11 N

分子量
121.18

闪点
57

密度
0.91

安全信息

危险等级
3

包装组
III

8.22267Sigma-Aldrich2,4,6-Trimethylpyridinefor synthesis358.91元/50 ML;   999.3元/250 ML;   2435.15元/1 L;   展开

产品说明

分析说明

Assay (GC, area%): ≥ 98.0 % (a/a)
Density (d 20 °C/ 4 °C): 0.913 - 0.915
Identity (IR): passes test

基本信息

线性分子式(CH3)3C5H2N
分子量121.18
MDL编号MFCD00006338
EC索引号203-613-3

产品性质

质量水平200
蒸汽压4 hPa ( 20 ℃)
测定≥98.0% (GC)
形式liquid
效能400 mg/kg LD50, oral (Rat)
bp170-172 ℃/1013 hPa
mp-43 ℃
转变温度flash point 55 ℃
溶解性 35 g/L
密度0.914 g/cm3 at 20 ℃
储存温度2-30℃
InChI1S/C8H11N/c1-6-4-7(2)9-8(3)5-6/h4-5H,1-3H3
InChI keyBWZVCCNYKMEVEX-UHFFFAOYSA-N

安全信息

象形图GHS02GHS06
警示用语:Danger
危险声明H226 - H302 + H332 - H311 - H315 - H319 - H335
预防措施声明P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338
危险分类Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码3 - Flammable liquids
WGKWGK 3
闪点(F)131.0 °F - closed cup
闪点(C)55 ℃ - closed cup
205168Amethyst2,4,6-Trimethylpyridine98.5%, 用于合成55元/25ML;   188元/100ML;   630元/500ML;   展开

基本信息

分子式C8H11N
分子量121.18
熔点-43
沸点171-172
闪点54
密度0.916
折光率(n20D)1.4980
MDL编码MFCD00006338
Beilstein107283
Merck14,9718
EINECS 编号203-613-3
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H226
H302
H332
H311
H315
H319
H335
防范说明P261
P280
P305+P351+P338
P312
UN号码1992
危险分类3
次要危险性6.1
包装等级III
WGK3
RTECSUU0970000
005102Fluorochem2,4,6-Collidine98%220元/1g;   330元/25g;   924元/100g;   2640元/500g;   5654元/1Kg;   展开

基本信息

CAS Number108-75-8
MDL NumberMFCD00006338
Boiling Point171-172℃
Density0.916

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H302: Harmful if swallowed.
H311: Toxic in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P361: Remove/Take off immediately all contaminated clothing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P370 + P378: In case of fire: Use CO2 for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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