| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | 详情 |
| C805066 | MACKLIN | 氯代二苯基膦 | 97% | 28元/5g; 35元/25g; 72元/100g; 275元/500g; 1352元/2.5kg; 4055元/10kg; | 展开 |
储存：室温, 充氩 状态：无色到黄色液体 折射率：n20/D 1.636(lit.) |
| C0597 | TCI | Chlorodiphenylphosphine | >97.0%(T) | 245元/25G; 700元/100G; 1035元/500G; | 展开 |
基本信息 | 纯度/分析方法 | >97.0%(T) | | 分子式/分子量 | C12H10ClP = 220.64 | | 外观与形状(20℃) | 液体 | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 空气,湿气 (分解) | | Reaxys-RN | 512032 | | PubChem物质ID | 87565694 | | SDBS (AIST Spectral DB) | 10853 | | MDL编号 | MFCD00000529 |
技术规格 | Appearance | Colorless to Light yellow to Light orange clear liquid | | Purity(Argentometric Titration) | min. 97.0 % |
物性(参考值) | 沸点 | 215 ℃/57 mmHg | | 闪点 | 138 ℃ | | 比重 | 1.20 | | 折射率 | 1.64 | | 水溶性 | 与水接触发生分解,不溶 |
安全信息 | 图形或危害标志 |  | | 信号词 | 危险 | | 危险性说明 | H314 : 造成严重皮肤灼伤和眼损伤。
| | 防范说明 | P501 : 将内装物/容器送到批准的废物处理厂处理。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。
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运输信息 | UN编号 | UN3265 | | 类别 | 8 | | 包装类别 | II | | 监管条件代码(*) | |
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| 297783 | J&K | Chlorodiphenylphosphine | 97% | 60元/5ML; 233元/25ml; 675元/100ml; | 展开 |
基本信息 | 分子式 | C12H10ClP | | 分子量 | 220.64 | | 沸点 | 320 | | 闪点 | 112 | | 密度 | 1.229 | | 折光率(n20D) | 1.6360 | | MDL编码 | MFCD00000529 | | Beilstein | 512032 | | EINECS 编号 | 214-093-2 |
安全信息 | 图形或危害标志 | | | 提示语 | Danger | | 危险说明 | H314 | | 防范说明 | P280
P305+P351+P338
P310 | | UN号码 | 3265 | | 危险分类 | 8 | | 包装等级 | II | | WGK | 2 | | TSCA | 是 |
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| 15-1551 | Strem | Diphenylchlorophosphine | min. 95% | 750元/50g; 2970元/250g; 8880元/1kg; | 展开 |
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| 15-1549 | Strem | Diphenylchlorophosphine | 98% | 598元/25g; 1459元/100g; 4449元/500g; | 展开 |
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| A14241 | Alfa Aesar | Chlorodiphenylphosphine | 97% | 379元/10g; 1061元/50g; 4089元/250g; | 展开 |
应用
Chlorodiphenylphosphine is used to introduce the diphenylphosphinyl moiety by aryl ortho-lithiation. It is also used as an intermediate to make antioxidants, flame retardants, stabilizers, catalysts, photoinitiators, and optical brighteners. Used as a halogenation reagent for the conversion of alcohols into halides, in the preparation of solid-phase reagent for the conversion of alcohols to alkyl halides. 备注
Air and moisture sensitive. Store in cool, dry place in tightly closed containers. Store way from water and air. 基本信息 MDL
MFCD00000529 EINECS
214-093-2 分子式
C12H10ClP 分子量
220.64 熔点
14-16° 沸点
318-321° 闪点
138°(280°F) 密度
1.204 折射率
1.6350 灵敏度
Moisture Sensitive. Air Sensitive. Store under Nitrogen. Ambient temperatures. 形态
Liquid 溶解性
Reacts with water. Beilstein
512032 GHS危害和防范说明 GHS符号
 Hazard Statements
H302-H314-H318
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage. Precautionary Statements
P280-P303+P361+P353-P305+P351+P338-P310-P402
Wear protective gloves/protective clothing/eye protection/face protection.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or doctor/physician.Store in a dry place. 安全信息 危险等级
8 包装组
II 危险类别
14-22-34
Reacts violently with water.Harmful if swallowed.Causes burns. 安全等级
8-20-23-26-30-36/37/39-45-60
Keep container dry.When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Never add water to this product.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste 欧盟危险品标志
  TSCA
是 |
| 041352 | Alfa Aesar | Chlorodiphenylphosphine | 98+% | 340元/10g; 1260元/50g; 4454元/250g; | 展开 |
应用
Chlorodiphenylphosphine is used in the synthesis of various phosphines and an useful reagent in for the introduction of Ph2P group. It is also useful as an intermediate to make antioxidants, flame retardants, stabilizers, catalysts, photoinitiators and optical brighteners. It is also used to produce diphenylphosphinous acid methyl esters. It is used as a precursor in the preparation of various phosphines. It is involved in the preparation of phosphines, which is used as stabilizers for plastics, flame retardants and UV-hardening paint systems. 备注
Moisture sensitive. Incompatible with strong oxidizing agents, water and strong bases. 基本信息 MDL
MFCD00000529 EINECS
214-093-2 分子式
C12H10ClP 分子量
220.64 熔点
14-16° 沸点
318-321° 闪点
138°(280°F) 密度
1.204 折射率
1.6360 灵敏度
Moisture Sensitive. Air Sensitive. Ambient temperatures. 形态
Liquid 溶解性
Miscible with alcohol. Slightly miscible with ammonia. Beilstein
512032 GHS危害和防范说明 GHS符号
Hazard Statements
H302-H314-H318
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage. Precautionary Statements
P280-P303+P361+P353-P305+P351+P338-P310-P402
Wear protective gloves/protective clothing/eye protection/face protection.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or doctor/physician.Store in a dry place. 安全信息 危险等级
8 包装组
II 危险类别
14-22-34
Reacts violently with water.Harmful if swallowed.Causes burns. 安全等级
8-20-23-26-30-36/37/39-45-60
Keep container dry.When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Never add water to this product.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste 欧盟危险品标志
TSCA
是 |
| C10913 | Alfa Aesar | Chlorodiphenylphosphine | 95%, tech. | 1149元/25ml; 2970元/100ml; 14499元/500ml; | 展开 |
基本信息 Ref#
10913 MDL
529 分子式
C12 H10 Cl P 分子量
220.64 闪点
138 密度
1229 安全信息 危险等级
8 包装组
II |
| C34730 | Alfa Aesar | Chlorodiphenylphosphine | 98% | 522元/5g; 1360元/25g; 3061元/100g; 13039元/500g; | 展开 |
基本信息 Ref#
34730 MDL
529 分子式
C12 H10 Cl P 分子量
220.64 闪点
138 密度
1229 形态
Liquid 安全信息 危险等级
8 包装组
II |
| C39601 | Sigma-Aldrich | Chlorodiphenylphosphine | 96% | 333.29元/25 G; 740.65元/100 G; 1154.18元/500 G; | 展开 |
产品说明 包装 25, 100, 500 g in glass bottle 应用 用于通过芳基邻锂化反应引入二苯基氧膦基部分。
用于合成各种膦的前体。 基本信息 | 线性分子式 | (C6H5)2PCl | | 分子量 | 220.63 | | Beilstein | 512032 | | EC 号 | 214-093-2 | | MDL编号 | MFCD00000529 | | PubChem化学物质编号 | 24892660 |
产品性质 | 质量水平 | 100 | | 蒸汽密度 | 7.8 (vs air) | | 测定 | 96% | | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings | | 折射率 | n20/D 1.636 (lit.) | | bp | 320 ℃ (lit.) | | 密度 | 1.194 g/mL at 25 ℃
1.229 g/mL at 25 ℃ (lit.) | | 官能团 | phosphine | | SMILES string | ClP(c1ccccc1)c2ccccc2 | | InChI | 1S/C12H10ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H | | InChI key | XGRJZXREYAXTGV-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Danger | | 危险声明 | H290 - H302 - H314 - H412 | | 预防措施声明 | P273 - P280 - P301 + P312 + P330 - P303 + P361 + P353 - P305 + P351 + P338 + P310 | | 危险分类 | Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B | | 补充剂危害 | EUH014 | | 储存分类代码 | 8A - Combustible, corrosive hazardous materials | | WGK | WGK 1 | | 闪点(F) | 280.4 °F | | 闪点(C) | 138 ℃ | | 个人防护装备 | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter |
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| 766054 | Sigma-Aldrich | P-Chlorodiphenylphosphine | 99% | 818.41元/25 G; | 展开 |
基本信息 | 线性分子式 | (C6H5)2PCl | | 分子量 | 220.63 | | Beilstein | 512032 | | EC 号 | 214-093-2 | | MDL编号 | MFCD00000529 | | PubChem化学物质编号 | 329767202 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | 蒸汽密度 | 7.8 (vs air) | | 测定 | 99% | | 形式 | liquid | | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand | | 折射率 | n20/D 1.636 (lit.) | | bp | 320 ℃ (lit.) | | 密度 | 1.194 g/mL at 25 ℃
1.229 g/mL at 25 ℃ (lit.) | | 官能团 | phosphine | | SMILES string | ClP(c1ccccc1)c2ccccc2 | | InChI | 1S/C12H10ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H | | InChI key | XGRJZXREYAXTGV-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Danger | | 危险声明 | H290 - H302 - H314 - H412 | | 预防措施声明 | P273 - P280 - P301 + P312 + P330 - P303 + P361 + P353 - P305 + P351 + P338 + P310 | | 危险分类 | Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B | | 补充剂危害 | EUH014 | | 储存分类代码 | 8A - Combustible, corrosive hazardous materials | | WGK | WGK 1 | | 闪点(F) | 280.4 °F | | 闪点(C) | 138 ℃ |
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| 050109 | Fluorochem | Diphenyl(chloro)phosphine | tech | 220元/1g; 264元/5g; 396元/25g; 1100元/100g; 2750元/250g; | 展开 |
基本信息 | CAS Number | 1079-66-9 | | MDL Number | MFCD00000529 | | Boiling Point | 100-102℃ | | Density | 1.19 |
安全信息 | 图形或危害标志 | | | 危险性说明 | EUH014: Reacts violently with water.
H314: Causes severe skin burns and eye damage.
| | 防范说明 | P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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