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CAS: 1071-93-8
分子式: C6H14N4O2
分子量: 174.20
熔点: 178-182℃
中文名称: 
己二酸二酰肼
己二酸二肼
英文名称: 
1,4-Butanedicarboxylic dihydrazide
Hexanedioic dihydrazide
Hexanedioic acid, dihydrazide
Adipyl Hydrazide
adipic dihydrazide
Adipic acid dihydrazide
Adipodihydrazide
Adipoyl Hydrazide
Hexanedioic acid,dihydrazide
Adipic dihy drazides
性质描述: 该品为白色结晶。熔点:180-182℃。无色透明,无可视不溶物。
用途: 中国药典 3118 己二酰肼含量测定法
推荐供应商
货号品牌产品名称规格包装、参考价格
A766470MACKLIN己二酸二酰肼对照品贮备液1mg/mL in H2O(CP)360元/100ml;   1638元/500ml;   咨询
储存:−20°C
A766469MACKLIN己二酸二酰肼对照品溶液20μg/mL in H2O(CP)280元/100ml;   1274元/500ml;   咨询
储存:−20°C
A766471MACKLIN己二酸二酰肼分析对照品, ≥99%(HPLC)750元/250mg;   咨询
储存:2-8℃
A800779MACKLIN己二酸二酰肼98%32元/25g;   75元/100g;   245元/500g;   735元/2.5kg;   2821元/10kg;   咨询
储存:2-8℃
状态:白色到几乎白色粉末到晶体
A0170TCIAdipic Dihydrazide>99.0%(HPLC)160元/25G;   630元/250G;   咨询

基本信息

纯度/分析方法>99.0%(HPLC)
分子式/分子量C6H14N4O2 = 174.20
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN973863
PubChem物质ID87561852
SDBS (AIST Spectral DB)1470
MDL编号MFCD00007614

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(HPLC)min. 99.0 area%
Purity(Bromination Method)min. 98.0 %
Melting point179.0 to 184.0 ℃
Solubility in hot Wateralmost transparency

物性(参考值)

熔点182 ℃
水溶性可溶

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#AV1400000
202233J&KAdipic acid dihydrazide98%60元/5G;   133元/25G;   561元/250g;   咨询

基本信息

分子式C6H14N4O2
分子量174.20
熔点180-182
闪点150
MDL编码MFCD00007614
Beilstein973863
EINECS 编号213-999-5
存储条件Freezer -20℃

安全信息

防范说明P260
P262
WGK3
RTECSAV1400000
TSCA
A15119Alfa AesarAdipic Dihydrazide97%524元/25g;   1747元/100g;   6952元/500g;   咨询

应用
Adipic dihydrazide is used as a formaldehyde scavenger and reacts with formaldehyde, thereby preventing the volatilizing of formaldehyde in the air. It is also employed as a paint additive and coating additive. It is also used as an intermediate. Further, it is used for cross-linking water-based emulsions and as a hardener for certain epoxy resins, which finds application in powder coating.

备注
Store in a cool place. Incompatible with strong oxidizing agents and strong bases.

基本信息

MDL
MFCD00007614

EINECS
213-999-5

分子式
H2NNHCO(CH2)4CONHNH2

分子量
174.20

熔点
180-182°

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in water, alcohol and acetone.

Beilstein
973863

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P280g-P305+P351+P338
Wear protective gloves.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

安全信息

危险等级
9

包装组
III

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA

C20331Alfa AesarAdipic Dihydrazide98%902元/25g;   3324元/100g;   13554元/500g;   咨询

基本信息

Ref#
20331

MDL
7614

分子式
C6 H14 N4 O2

分子量
174.2

形态
White to pale cream cryst powder

8.41689Sigma-AldrichAdipic Dihydrazidefor synthesis285.89元/10 G;   1393.72元/50 G;   咨询

产品说明

分析说明

Assay (HClO₄): ≥ 97,0 %(m)
Melting range (lower value): ≥ 178 °C
Melting range (upper value): ≤ 182 °C
Identity (IR): conforms

基本信息

经验(实验)分子式C6H14N4O2
分子量174.20
MDL编号MFCD00007614
EC索引号213-999-5

产品性质

质量水平200
自燃温度360 ℃
mp178-182 ℃
转变温度flash point >150 ℃
储存温度15-25℃
InChI1S/C6H14N4O2/c7-9-5(11)3-1-2-4-6(12)10-8/h1-4,7-8H2,(H,9,11)(H,10,12)
InChI keyIBVAQQYNSHJXBV-UHFFFAOYSA-N

安全信息

象形图GHS09
危险声明H411
预防措施声明P273 - P391 - P501
危险分类Aquatic Chronic 2
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)302.0 °F - closed cup
闪点(C)150 ℃ - closed cup
A0638Sigma-AldrichAdipic acid dihydrazide≥98% (titration)1036.11元/25 G;   4073.9元/100 G;   咨询

产品说明

应用

己二酸二肼是一种均二官能团交联试剂,对醛类具有特异性,从而形成相对稳定的肼键。己二酸二肼通常用于糖蛋白(如抗体)的连接,在高碘酸氧化后以特定的位点方式进行连接。在pH 5.0条件下,由于肼的pKa较低,避免了伯胺的竞争,所以氧化和偶联可以顺利地进行。

包装

25, 100 g in poly bottle

其他说明

请注意联氨键可以通过选择性还原来稳定,例如使用氰化钠。

基本信息

线性分子式NH2NHCO(CH2)4CONHNH2
分子量174.20
Beilstein973863
EC 号213-999-5
MDL编号MFCD00007614
PubChem化学物质编号24890442
NACRESNA.25

产品性质

质量水平300
测定≥98% (titration)
形式powder
reaction suitabilityreagent type: cross-linking reagent
mp180-182 ℃ (lit.)
溶解性H2O: 100 mg/mL
储存温度−20℃
SMILES stringNNC(=O)CCCCC(=O)NN
InChI1S/C6H14N4O2/c7-9-5(11)3-1-2-4-6(12)10-8/h1-4,7-8H2,(H,9,11)(H,10,12)
InChI keyIBVAQQYNSHJXBV-UHFFFAOYSA-N

安全信息

象形图GHS09
危险声明H411
预防措施声明P273 - P391 - P501
危险分类Aquatic Chronic 2
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)302.0 °F - closed cup
闪点(C)150 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type N95 (US)
018159FluorochemAdipic acid dihydrazide97%220元/25g;   550元/100g;   1012元/250g;   咨询

基本信息

CAS Number1071-93-8
MDL NumberMFCD00007614

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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