CAS 1069-08-5; Phosphoramidous dichloride,diethyl-

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D865493

MACKLIN

二氯(二乙氨基)膦

98%

42元/1g; 139元/5g; 431元/25g; 1599元/100g;

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储存：2-8°C
状态：无色到浅黄色液体

D3244

TCI

Dichloro(diethylamino)phosphine

>98.0%(GC)

745元/5G; 3155元/25G;

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基本信息

纯度/分析方法	>98.0%(GC)
分子式/分子量	C₄H₁₀Cl₂NP = 174.00
外观与形状(20℃)	液体
储存温度	0-10℃
储存在惰性气体下	存放于惰性气体之中
应避免的情况	空气,湿气 (分解),加热
Reaxys-RN	1736184
PubChem物质ID	87558612

技术规格

Appearance	Colorless to Almost colorless clear liquid
Purity(GC)	min. 98.0 %

物性(参考值)

沸点	189 ℃
闪点	83 ℃
比重	1.17
折射率	1.50

安全信息

图形或危害标志
信号词	危险
危险性说明	H314 : 造成严重皮肤灼伤和眼损伤。 H227 : 可燃液体。 H290 : 可能腐蚀金属。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P210 : 远离热源/火花/明火/热表面。禁止吸烟。 P234 : 只能在原容器中存放。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P390 : 吸收溢出物，防止材料损坏。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。 P363 : 沾染的衣服清洗后方可重新使用。 P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。 P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。 P403 + P235 : 存放在通风良好的地方。保持低温。 P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。 P405 : 存放处须加锁。

运输信息

UN编号	UN3265
类别	8
包装类别	II
监管条件代码(*)

H25934

Alfa Aesar

Dichloro(diethylamino)phosphine

97%

863元/5g; 3052元/25g; 8418元/100g;

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应用
Dichloro(diethylamino)phosphine is used as a reagent for the preparation of diethylaminophosphine-metal complexes and it is a critical starting material in the preparation of various phosphines, phosphoramidites & the phosphitylation of alcohols.

备注
Moisture sensitive. Store away from oxidizing agents, bases, active metals, water/ moisture.

基本信息

MDL
MFCD00013614

分子式
C₄H₁₀Cl₂NP

分子量
174.01

沸点
179°

闪点
83°(181°F)

密度
1.196

折射率
1.497

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Liquid

溶解性
Reacts violently in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H314-H318
Combustible liquid.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P210e-P260h-P303+P361+P353-P305+P351+P338-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
14-34
Reacts violently with water.Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA
否

362891

Sigma-Aldrich

Diethylphosphoramidous dichloride

97%

698.49元/5 G;

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产品说明

应用

二乙基膦胺金属络合物的制备和乙醇的亚磷酰化所需试剂。

包装

5 g in glass bottle

基本信息

线性分子式	(C₂H₅)₂NPCl₂
分子量	174.01
MDL编号	MFCD00013614
PubChem化学物质编号	24862338
NACRES	NA.22

产品性质

质量水平	100
测定	97%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand
折射率	n20/D 1.497 (lit.)
bp	179 ℃ (lit.)
密度	1.196 g/mL at 25 ℃ (lit.)
官能团	phosphine
储存温度	2-8℃
SMILES string	CCN(CC)P(Cl)Cl
InChI	1S/C4H10Cl2NP/c1-3-7(4-2)8(5)6/h3-4H2,1-2H3
InChI key	BPEMCEULJQTJMI-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H314
预防措施声明	P280 - P305 + P351 + P338 - P310
危险分类	Skin Corr. 1B
储存分类代码	8A - Combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	181.4 °F - closed cup
闪点(C)	83 ℃ - closed cup
个人防护装备	Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

101970

Fluorochem

Dichloro(diethylamino)phosphine

95%

220元/1g; 528元/5g; 1892元/25g; 6446元/100g; 12892元/250g;

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基本信息

CAS Number	1069-08-5
MDL Number	MFCD00013614
Boiling Point	179℃
Density	1.196

安全信息

图形或危害标志
危险性说明	H314: Causes severe skin burns and eye damage. H318: Causes serious eye damage.
防范说明	P260: Do not breathe . P264: Wash hands thoroughly after handling. P280: Wear . P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor/physician. P321: Specific treatment (see . on this label). P363: Wash contaminated clothing before reuse. P405: Store locked up. P501: Dispose of contents/container to local regulations.