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CAS: 1067-74-9
分子式: C7H15O5P
分子量: 210.16
沸点: 127-131℃
中文名称: 
甲基二乙基磷酸乙酯
英文名称: 
methyl diethylphosphonoacetate
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M830209MACKLIN膦酰基乙酸甲酯二乙酯98%30元/25g;   100元/100g;   480元/500g;   展开
储存:室温,密封
状态:无色到几乎无色澄清液体
D2873TCIMethyl Diethylphosphonoacetate>96.0%(GC)140元/5G;   490元/25G;   展开

基本信息

纯度/分析方法>96.0%(GC)
分子式/分子量C7H15O5P = 210.17
外观与形状(20℃)液体
Reaxys-RN1782397
PubChem物质ID87569251
MDL编号MFCD00009081

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 96.0 %

物性(参考值)

沸点129 ℃/9 mmHg
比重1.16
折射率1.43

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
581510J&KMethyl Diethylphosphonoacetate98%62元/5G;   250元/25G;   展开

基本信息

分子式C7H15O5P
分子量210.16
沸点127-131
闪点110
密度1.145
折光率(n20D)1.4330
MDL编码MFCD00009081
Beilstein1782397
EINECS 编号213-938-2

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
A10644Alfa AesarMethyl Diethylphosphonoacetate97%1559元/25g;   5575元/100g;   13382元/500g;   展开

应用
Methyl diethylphosphonoacetate is used as a reagent in the preparation of allylic fluorides compounds and in regioselective Diels-Alder reactions. It also serves as a reactant in the preparation of substituted thiophenes and furans, which finds application in type 2 diabetes treatment. Further, it acts as a precursor in the synthesis of pyridone alkaloids and immunosuppressive cyclopentanediol derivatives. In addition to this, it is utilized in the modification of botulinum neurotoxin serotype A protease inhibitors.

备注
Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00009081

EINECS
213-938-2

分子式
C7H15O5P

分子量
210.17

沸点
126-128°/8mm

闪点
>110°(230°F)

密度
1.145

折射率
1.4320

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Miscible with tetrahydrofuran.

Beilstein
1782397

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

C16998Alfa AesarMethyl Diethylphosphonoacetate97%917元/10g;   3698元/50g;   展开

基本信息

Ref#
16998

MDL
9081

分子式
C7 H15 O5 P

分子量
210.17

闪点
>110

密度
1.14

158763Sigma-AldrichMethyl Diethylphosphonoacetate97%541.74元/10 G;   1488.87元/50 G;   展开

产品说明

应用

Reactant or reagent for:

  • Synthesis of branches allylic fluorides
  • Regioselective Diels-Alder reactions to yield antibiotic building blocks
  • Substituted thiophenes and furans synthesis for treatment of type 2 diabetes
  • Stereoselective Diels-Alder cycloaddition reactions
  • Synthesis of pyridone alkaloids with neuritogenic activity
  • Modification of botulinum neurotoxin serotype A protease inhibitors
  • Synthesis of immunosuppressive cyclopentanediol derivatives

包装

10, 50 g in glass bottle

基本信息

线性分子式(C2H5O)2P(O)CH2CO2CH3
分子量210.16
Beilstein1782397
EC 号213-938-2
MDL编号MFCD00009081
PubChem化学物质编号24849773
NACRESNA.22

产品性质

质量水平100
测定97%
reaction suitabilityreaction type: C-C Bond Formation
折射率n20/D 1.433 (lit.)
bp127-131 ℃/9 mmHg (lit.)
密度1.145 g/mL at 25 ℃ (lit.)
SMILES stringCCOP(=O)(CC(=O)OC)OCC
InChI1S/C7H15O5P/c1-4-11-13(9,12-5-2)6-7(8)10-3/h4-6H2,1-3H3
InChI keyCTSAXXHOGZNKJR-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)230.0 °F - closed cup
闪点(C)110 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter
224636FluorochemMethyl 2-(diethoxyphosphoryl)acetate95%220元/10g;   440元/25g;   1078元/100g;   展开

基本信息

CAS Number1067-74-9
MDL NumberMFCD00009081
Boiling Point127-131℃
Density1.145

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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