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CAS: 106-91-2
分子式: C7H10O3
分子量: 142.15
沸点: 189 °C(lit.)
熔点: -42°C
中文名称: 
甲基丙烯酸甲酯缩水甘油
2-甲基-2-丙烯酸环氧乙烷基甲基酯
甲基丙烯酸缩水甘油酯
缩水甘油甲基丙烯酸酯
英文名称: 
Glycidyl methacrylete
2,3-Epoxypropylmethacrylate
GMA
2-Propenoic acid,2-methyl-,oxiranylmethyl ester
glycidyl methacrylate(gma)
glycidylmethacrylate
2-Propenoic acid, 2-methyl-, oxiranylmethyl ester
methacrylic acid, 2,3-epoxypropyl ester
2,3-epoxy-1-propano methacrylate
2,3-epoxy-1-propanol, methacrylate
2,3-epoxypropyl methacrylate
2-((methacryloxy)methyl)oxirane
2-methyl-2-propenoic acid, oxiranylmethyl ester
2-methyl-2-propenoic aci oxiranylmethyl ester
acriester g
blemmer g
blemmer gma
cp 105
glycidol methacrylate
glycidyl alpha-methyl acrylate
glycidyl methacrylate
light ester g
methacrylate de glycidyle
sr 379
sy-monomer g
展开更多英文名
性质描述: 无色液体。沸点189℃,相对密度1.073(25/4℃),折光率1.4494,闪点76℃。可溶于有机溶剂,不溶于水。
生产方法: 由甲基丙烯酸钠与环氧氯丙烷反应而得。原料消耗定额:甲基丙烯酸780kg/t、环氧氯丙烷690kg/t、氢氧化钠330kg/t。
用途: 主要用于粉末涂料,也用于热固性涂料、纤维处理剂、粘合剂、抗静电剂、氯乙烯稳定剂、橡胶和树脂改性剂、离子交换树脂和印刷油墨的粘合剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
G810426MACKLIN甲基丙烯酸缩水甘油酯97%,含100ppmMEHQ稳定剂44元/100g;   119元/500g;   590元/2.5kg;   1123元/5kg;   展开
储存:2~8°C
状态:无色液体
折射率:n20/D 1.449(lit.)
M0590TCIGlycidyl Methacrylate (stabilized with MEHQ)>95.0%(GC)120元/25G;   610元/500G;   展开

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C7H10O3 = 142.15
外观与形状(20℃)液体
储存温度0-10℃
应避免的情况加热
Reaxys-RN2506
PubChem物质ID87572617
SDBS (AIST Spectral DB)1438
MDL编号MFCD00005137

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 95.0 %

物性(参考值)

熔点-42 ℃
沸点189 ℃
闪点84 ℃
比重1.08
折射率1.45
水溶性可溶
在水中的溶解度50 g/l   25 ℃

安全信息

图形或危害标志
信号词危险
危险性说明H311 : 皮肤接触会中毒。
H302 + H332 : 吞咽或吸入有害。
H314 : 造成严重皮肤灼伤和眼损伤。
H360 : 可能对生育能力或胎儿造成伤害。
H370 : 会损害器官。
H372 : 长期或反复接触会对器官造成损害。
H317 : 可能造成皮肤过敏反应。
H341 : 怀疑可造成遗传性缺陷。
H350 : 可能致癌。
H401 : 对水生生物有毒。
H227 : 可燃液体。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P272 : 受沾染的工作服不得带出工作场地。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P201 : 使用前取得专用说明。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P308+P311 : 如接触到或有疑虑:呼叫急救中心/医生。
P361 + P364 : 立即脱掉所有沾染的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P333 + P313 : 如发生皮肤刺激或皮疹:求医/就诊。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。
P405 : 存放处须加锁。

相关法规

RTECS#OZ4375000

运输信息

UN编号UN2922
类别8 / 6.1
包装类别 II
监管条件代码(*)
304661J&KGlycidyl methacrylate96%, 含稳定剂MEHQ60元/25G;   65元/100G;   305元/500G;   展开

基本信息

分子式C7H10O3
分子量142.15
熔点-42
沸点85
闪点84
密度1.08
MDL编码MFCD00005137
EINECS 编号203-441-9
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H302
H332
H311
H314
H317
H341
H350
H360F
H370
防范说明P201
P280
P301+P330+P331
P303+P361+P353
P305+P351+P338+P310
P308+P311
UN号码2922
危险分类8
次要危险性6.1
包装等级II
WGK3
RTECSOZ4375000
916019J&KGlycidyl methacrylate99%, 含稳定剂MEHQ68元/100G;   339元/500G;   1049元/2.5KG;   展开

基本信息

分子式C7H10O3
分子量142.15
熔点-42
沸点189
闪点76
密度1.08
折光率(n20D)1.449 - 1.451
MDL编码MFCD00005137
Beilstein2506
EINECS 编号203-441-9
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H302
H332
H311
H315
H317
H319
H341
H350
H360F
H370
防范说明P201
P260
P280
P305+P351+P338
P308+P313
UN号码2922
危险分类8
次要危险性6.1
包装等级III
WGK1
RTECSOZ4375000
L11133Alfa AesarGlycidyl methacrylate97%, stab. with 100ppm 4-methoxyphenol294元/50g;   940元/250g;   展开

应用
Glycidyl methacrylate is commonly used as a monomer for the preparation of epoxy resins. It is also used to provide epoxy functionalization to polyolefins and other acrylate resins. Further, it is also useful as an epoxy resin additive for paint coating formulations and adhesive applications.

备注
Light sensitive. Store in a cool place. Incompatible with strong oxidizing agents, strong acids and strong bases and peroxides.

基本信息

MDL
MFCD00005137

EINECS
203-441-9

分子式
C7H10O3

分子量
142.16

熔点
-82°

沸点
189°

闪点
83°(181°F)

密度
1.078

折射率
1.4500

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Miscible with benzene, alcohol and ether. Slightly miscible with water.

Beilstein
2506

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H302-H311-H332-H315-H319-H317
Combustible liquid.Harmful if swallowed.Toxic in contact with skin.Harmful if inhaled.Causes skin irritation.Causes serious eye irritation.May cause an allergic skin reaction.

Precautionary Statements
P210e-P261-P280-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
20/21/22-36/38-43
Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes and skin.May cause sensitization by skin contact.

安全等级
26-28
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).

欧盟危险品标志

RTECS
OZ4375000

TSCA

151238Sigma-AldrichGlycidyl methacrylate97%, contains 100 ppm monomethyl ether hydroquinone as inhibitor653.43元/100 G;   2029.79元/500 G;   展开

产品说明

一般描述

甲基丙烯酸缩水甘油酯(GMA)是一种多功能的单体。它可作为一种粘附促进交联共聚单体用于丙烯酸乙烯树脂。它还是一种活性的无色稀释液。GMA可溶于乙醇、丙酮、乙醚、苯。

应用

甲基丙烯酸缩水甘油葡聚糖(GMA)已被报道可用作生物兼容性的水凝胶。还报道了GMA与三羟甲基丙烷三甲基丙烯酸酯的原位聚合以形成巨大孔吸附剂。GMA也可以被嫁接到聚丙烯上。

包装

100, 500 g in glass bottle
5 kg in poly drum

基本信息

经验(实验)分子式C7H10O3
分子量142.15
Beilstein2506
EC 号203-441-9
MDL编号MFCD00005137
PubChem化学物质编号24849103
NACRESNA.23

产品性质

质量水平200
测定97%
形式liquid
包含100 ppm monomethyl ether hydroquinone as inhibitor
杂质0.02% epichlorohydrin
折射率n20/D 1.449 (lit.)
bp189 ℃ (lit.)
密度1.042 g/mL at 25 ℃ (lit.)
储存温度2-8℃
SMILES stringCC(=C)C(=O)OCC1CO1
InChI1S/C7H10O3/c1-5(2)7(8)10-4-6-3-9-6/h6H,1,3-4H2,2H3
InChI keyVOZRXNHHFUQHIL-UHFFFAOYSA-N

安全信息

象形图GHS05GHS06GHS08
警示用语:Danger
危险声明H302 - H311 - H314 - H317 - H335 - H341 - H350 - H360F - H372
预防措施声明P201 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Carc. 1B - Eye Dam. 1 - Muta. 2 - Repr. 1B - Skin Corr. 1C - Skin Sens. 1 - STOT RE 1 - STOT SE 3
靶器官Respiratory system
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)168.8 °F - closed cup
闪点(C)76 ℃ - closed cup
779342Sigma-AldrichGlycidyl methacrylate≥97.0% (GC)554.55元/100 ML;   886.98元/500 ML;   展开

产品说明

应用

甲基丙烯酸缩水甘油酯(GMA)是一种通常用于衍生聚合物的环氧官能单体。它也可以通过聚合形成聚(甲基丙烯酸缩水甘油酯)。

基本信息

经验(实验)分子式C7H10O3
分子量142.15
Beilstein2506
EC 号203-441-9
MDL编号MFCD00005137
PubChem化学物质编号329768028
NACRESNA.22

产品性质

质量水平200
测定≥97.0% (GC)
形式liquid
包含~0.01% hydrochinone monomethylether as stabilizer
折射率n20/D 1.449 (lit.)
n20/D 1.450
bp189 ℃ (lit.)
密度1.075 g/mL at 20 ℃
1.042 g/mL at 25 ℃ (lit.)
SMILES stringCC(=C)C(=O)OCC1CO1
InChI1S/C7H10O3/c1-5(2)7(8)10-4-6-3-9-6/h6H,1,3-4H2,2H3
InChI keyVOZRXNHHFUQHIL-UHFFFAOYSA-N

安全信息

象形图GHS05GHS06GHS08
警示用语:Danger
危险声明H302 - H311 - H314 - H317 - H335 - H341 - H350 - H360F - H372
预防措施声明P201 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Carc. 1B - Eye Dam. 1 - Muta. 2 - Repr. 1B - Skin Corr. 1C - Skin Sens. 1 - STOT RE 1 - STOT SE 3
靶器官Respiratory system
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)168.8 °F - closed cup
闪点(C)76 ℃ - closed cup
948545AmethystGlycidyl methacrylate96%, 试剂级, 含稳定剂MEHQ53元/25G;   71元/100G;   195元/500G;   780元/2.5KG;   展开

基本信息

分子式C7H10O3
分子量142.15
熔点-42
沸点85
闪点84
密度1.08
MDL编码MFCD00005137
EINECS 编号203-441-9
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Warning
危险说明H302
H312
H315
H317
H319
H332
防范说明P280
P305+P351+P338
UN号码2922
危险分类8
次要危险性6.1
包装等级II
WGK3
RTECSOZ4375000
545996FluorochemOxiran-2-ylmethyl methacrylate96% (stabilized with MEHQ)374元/100g;   展开

基本信息

CAS Number106-91-2
MDL NumberMFCD00005137
Boiling Point189℃
Density1.07

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
H335: May cause respiratory irritation.
H341: Suspected of causing genetic defects ..
H350: May cause cancer ..
H360: May damage fertility or the unborn child ..
H372: Causes damage to organs ..
H317: May cause an allergic skin reaction
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P281: Use personal protective equipment as required.
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical advice/attention if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P361: Remove/Take off immediately all contaminated clothing.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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