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CAS: 105-55-5
分子式: C5H12N2S
分子量: 132.23
熔点: 76-78℃
中文名称: 
1,3-二乙基-2-硫脲
二乙基硫脲
N,N'-二乙基硫脲
促进剂DETU
英文名称: 
Thiourea,N,N'-diethyl-
N,N'-diethyl-Thiourea
1,3-diethyl-2-thio-ure
1,3-diethyl-2- thio uree
1,3-diethyl-2-thiourea
1,3-diethylthiourea
n,n'-diethylthiocarbamide
n,n'-diethylthiourea
n,n'-diethylthiouree
nci-c03816
pennzone e
thiate h
n,n'-diethyl-thioure
u 15030
usaf ek-1803
N,N'-diethyl-2-thiourea
2-thiourea,1,3-diethyl-
1,3-diethyl thiourea
展开更多英文名
性质描述: 白色或淡黄色粉末。熔点144℃。易溶于乙醇、丙酮,溶于水,难溶于汽油。有吸湿性。
生产方法: 由乙胺与二硫化碳反应而得。
用途: 该品为硫脲类促进剂,这类促进剂一般是由胺二硫化碳反应得到的,最常用的品种是乙撑硫脲(NA-22)和N,N'-二正丁基硫脲(DBTU)等。这类促进剂的促进效力低且抗焦烧性能差,故对二烯类橡胶来说现已绝少使用,但在某些特殊情况下,如用秋兰母硫化物等硫黄给予体硫化剂时,它具有活性剂的作用。硫脲类促进剂对于氯丁胶的硫化却具有独特的效能,可制得抗张强度、硬度、压缩永久变形等性能良好的氯丁硫化胶。二乙基硫脲与NA-22相比,焦烧及硫化均快,但硫化平坦性较好。该品易分散,不喷霜。用量较大时,可进行高温高速硫化,特别适用于压出制品的连续硫化。该品亦为丁基胶用促进剂,三元乙丙胶的硫化活性剂。在天然胶和丁苯胺中能活化噻唑类和次磺酰胺类促进剂,对天然胶、氯丁胶、丁腈胶和丁苯胶有抗氧化作用。二乙基硫脲还用于配制缓蚀剂Rodine 31A
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D0530TCIN,N'-Diethylthiourea>97.0%(T)125元/25G;   695元/500G;   展开

基本信息

纯度/分析方法>97.0%(T)
分子式/分子量C5H12N2S = 132.23
外观与形状(20℃)固体
Reaxys-RN773905
PubChem物质ID87567191
SDBS (AIST Spectral DB)1109
MDL编号MFCD00004925

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(Bromination Method)min. 97.0 %
Melting point77.0 to 80.0 ℃

物性(参考值)

熔点79 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H317 : 可能造成皮肤过敏反应。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P272 : 受沾染的工作服不得带出工作场地。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P333 + P313 : 如发生皮肤刺激或皮疹:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。

相关法规

RTECS#YS9800000
541966J&KN,N'-Diethylthiourea98%128元/100G;   展开

基本信息

分子式C5H12N2S
分子量132.23
熔点76-78
MDL编码MFCD00004925
Beilstein773905
EINECS 编号203-308-5

安全信息

图形或危害标志
提示语Danger
危险说明H302
H312
H317
H318
H372
H412
防范说明P260
P280
P301+P312
P331
P305+P351+P338
P310
WGK2
RTECSYS9800000
A17143Alfa AesarN,N'-Diethylthiourea98%666元/250g;   1961元/1000g;   展开

基本信息

MDL
MFCD00004925

EINECS
203-308-5

分子式
(CH3CH2NH)2C=S

分子量
132.23

熔点
75-79°

闪点
186°(367°F)

密度
1.120

形态
Crystalline powder

Beilstein
773905

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H318-H317-H351
Harmful if swallowed.Causes serious eye damage.May cause an allergic skin reaction.Suspected of causing cancer.

Precautionary Statements
P280-P305+P351+P338-P333+P313-P337+P313
Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.If skin irritation or rash occurs: Get medical advice/attention.If eye irritation persists: Get medical advice/attention.

安全信息

危险类别
22-40-41-43
Harmful if swallowed.Limited evidence of a carcinogenic effect.Risk of serious damage to eyes.May cause sensitization by skin contact.

安全等级
24-26-36/37/39
Avoid contact with skin.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.

欧盟危险品标志

RTECS
YS9800000

TSCA

D100900Sigma-AldrichN,N′-Diethylthiourea98%537.32元/250 G;   展开

产品说明

应用

N,N′-Diethylthiourea can be used as a reactant to prepare:

  • 3,5-Diethyltetrahydro-4-thioxo-1,3,5-triazine-1(2H)-propanoic acid by condensation reaction with formaldehyde and β-alanine.
  • Methyl 3-ethyl-2-(ethylimino)-3,4-dihydro-4-oxo-2H-1,3-thiazine-6-carboxylate by one-pot reaction with dimethyl acetylenedicarboxylate in the presence of triphenylphosphine catalyst.
  • 2-(Ethylimino)-3-ethyl-thiazolidin-4-one by cyclization reaction with 2-chloroacetic acid.
  • 3-Ethyl-2-(ethylimino)-4-oxo-5-thiazolidineacetamide by condensation reaction with maleimides via Michael-type reaction.

包装

250 g in glass bottle

基本信息

线性分子式(C2H5NH)2CS
分子量132.23
Beilstein773905
EC 号203-308-5
MDL编号MFCD00004925
PubChem化学物质编号24893318
NACRESNA.22

产品性质

质量水平200
测定98%
mp76-78 ℃ (lit.)
SMILES stringCCNC(=S)NCC
InChI1S/C5H12N2S/c1-3-6-5(8)7-4-2/h3-4H2,1-2H3,(H2,6,7,8)
InChI keyFLVIGYVXZHLUHP-UHFFFAOYSA-N
Gene Informationhuman ... EPHX2(2053)
mouse ... Ephx2(13850)

安全信息

象形图GHS05GHS07GHS08
警示用语:Danger
危险声明H302 + H312 - H317 - H318 - H351 - H412
预防措施声明P273 - P280 - P301 + P312 - P302 + P352 + P312 - P305 + P351 + P338 - P308 + P313
危险分类Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Skin Sens. 1B
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)366.8 °F
闪点(C)186 ℃
个人防护装备dust mask type N95 (US), Eyeshields, Faceshields, Gloves
8.03520Sigma-AldrichN,N′-Diethylthioureafor synthesis305.31元/250 G;   展开

产品说明

分析说明

Assay (HPLC, area%): ≥ 98.0 % (a/a)
Melting range (lower value): ≥ 75 °C
Melting range (upper value): ≤ 78 °C
Identity (IR): passes test

基本信息

线性分子式(C2H5NH)2CS
分子量132.23
MDL编号MFCD00004925
EC索引号203-308-5

产品性质

质量水平200
蒸汽压0.0000064 hPa ( 20 ℃)
测定≥98.0% (HPLC)
形式crystals
效能316 mg/kg LD50, oral (Rat)
pH值(酸碱度)7 (20 ℃, 38 g/L in H2O)
mp75-78 ℃
转变温度flash point 186 ℃
密度1.12 g/cm3 at 20 ℃
堆积密度735 kg/m3
储存温度2-30℃
InChI1S/C5H12N2S/c1-3-6-5(8)7-4-2/h3-4H2,1-2H3,(H2,6,7,8)
InChI keyFLVIGYVXZHLUHP-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07GHS08
警示用语:Danger
危险声明H302 + H312 - H317 - H318 - H372 - H412
预防措施声明P273 - P280 - P301 + P312 - P302 + P352 + P312 - P305 + P351 + P338 - P314
危险分类Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Sens. 1B - STOT RE 1 Oral
靶器官Thyroid
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 2
闪点(F)366.8 °F
闪点(C)186 ℃
PLAS-AX-103NAccuStandardN,N'-Diethylthiourea772元/50mg;   展开
N,N'-DiethylthioureaN,N'-二乙基硫脲105-55-5
098974Fluorochem1,3-Diethyl-2-thiourea97%220元/25g;   396元/100g;   展开

基本信息

CAS Number105-55-5
MDL NumberMFCD00004925

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H317: May cause an allergic skin reaction.
H318: Causes serious eye damage.
H351: Suspected of causing cancer ..
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P261: Avoid breathing .
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear .
P281: Use personal protective equipment as required.
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P333 + P313: If skin irritation or rash occurs: Get medical advice/attention.
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations..
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