CAS 10465-81-3; 1,1'-(Azodicarbonyl)dipiperidine

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A801530

MACKLIN

1,1'-(偶氮二羰基)二哌啶

>98.0%

28元/1g; 38元/5g; 86元/25g; 325元/100g;

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储存：室温
状态：黄色粉末或晶体

A1051

TCI

1,1'-(Azodicarbonyl)dipiperidine

>98.0%(N)

435元/5G; 1420元/25G;

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基本信息

纯度/分析方法	>98.0%(N)
分子式/分子量	C₁₂H₂₀N₄O₂ = 252.32
外观与形状(20℃)	固体
Reaxys-RN	261917
PubChem物质ID	87562542
MDL编号	MFCD00010111

技术规格

Appearance	Light yellow to Brown powder to crystal
Purity(with Total Nitrogen)	min. 98.0 %
Melting point	134.0 to 137.0 ℃

物性(参考值)

熔点	136 ℃
溶解性(可溶于)	甲苯

安全信息

图形或危害标志
信号词	警告
危险性说明	H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。 P302 + P352 + P312 : 如皮肤沾染：用水充分清洗。如感觉不适，呼叫急救中心/医生。 P304 + P340 + P312 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。如感觉不适，呼叫急救中心/医生。

428622

J&K

1,1'-(Azodicarbonyl)dipiperidine

98%

81元/1G; 202元/5G; 741元/25G;

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基本信息

分子式	C₁₂H₂₀N₄O₂
分子量	252.32
熔点	134-136
MDL编码	MFCD00010111
Beilstein	261917

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
UN号码	3234
危险分类	4.1
WGK	3
TSCA	否

H27719

Alfa Aesar

1,1'-(Azodicarbonyl)dipiperidine

97%

1771元/5g; 4967元/25g;

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应用
It is used in a study of the copper-catalyzed addition of aryboronic acids to azodicarboxyl derivatives providing aryl-substituted hydrazides. It is widely used reagent for the Mitsunobu reaction. It is reactant for preparation of polyfluoroalkylated tripyrazolylmethane ligands, (-)-Hygromycin A via Mitsunobu glycosylation, optically active α,α-disubstituted amino acids via Mitsunobu reaction, aza-β-lactams through [2+2] cycloaddition reactions, glycosyl disulfides, pyridine ether PPAR agonists, S-glycosyl amino acid, building blocks for combinatorial neoglycopeptide synthesis and is a histamine H3 receptor antagonists. It is a reactant for Mitsunobu inversion reactions.

备注
Store in cool dry conditions. Incompatible with oxidizing agents.

基本信息

MDL
MFCD00010111

分子式
C₁₂H₂₀N₄O₂

分子量
252.32

熔点
133-136°

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Slightly soluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否

255920

Sigma-Aldrich

1,1′-(Azodicarbonyl)dipiperidine

99%

622.77元/5 G; 1795.43元/25 G;

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产品说明

应用

制备用反应物：

多氟烷基化三吡唑甲烷配体

通过 Mitsunobu 糖基化的 (-)-潮霉素 A
通过 Mitsunobu 反应光学活性 α,α-二取代氨基酸
通过 [2 + 2] 环加成反应合成叠氮-β-内酰胺类
糖基二硫化物
吡啶醚类 PPAR 激动剂
组合新糖肽合成的 S-糖基氨基酸构件
组胺 H3 受体拮抗剂

反应物用于：

Mitsunobu 翻转反应

广泛用于 Mitsunobu 反应的试剂
用于研究芳基硼酸通过铜催化加成得到偶氮二甲酸衍生物，从而生成芳基取代酰肼的反应。

包装

5, 25 g in poly bottle

基本信息

经验(实验)分子式	C₁₂H₂₀N₄O₂
分子量	252.31
Beilstein	261917
MDL编号	MFCD00010111
PubChem化学物质编号	24855495
NACRES	NA.22

产品性质

质量水平	200
测定	99%
mp	134-136 ℃ (lit.)
SMILES string	O=C(\N=N\C(=O)N1CCCCC1)N2CCCCC2
InChI	1S/C12H20N4O2/c17-11(15-7-3-1-4-8-15)13-14-12(18)16-9-5-2-6-10-16/h1-10H2/b14-13+
InChI key	OQJBFFCUFALWQL-BUHFOSPRSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

221643

Fluorochem

1,1'-(Azodicarbonyl)dipiperidine

97%

264元/1g; 770元/5g; 1298元/10g; 2728元/25g; 7678元/100g;

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基本信息

CAS Number	10465-81-3
MDL Number	MFCD00010111
Melting Point	130-138℃

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .