CAS 104439-77-2; 1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)

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货号

品牌

产品名称

规格

包装、参考价格

H811492

MACKLIN

1-羟基四苯基环戊二烯基(四苯基-2,4-环戊二烯基-1-酮)-μ-羟基四羰基二钌(II)

98%

462元/100mg; 938元/500mg;

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储存：室温
状态：白色到棕褐色粉末晶体和/或块状

H1322

TCI

1-Hydroxytetraphenylcylclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)

920元/100MG;

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基本信息

分子式/分子量	C₆₂H₄₂O₆Ru₂ = 1085.15
外观与形状(20℃)	固体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	空气,湿气 (分解)
PubChem物质ID	125308084
Merck Index (14)	8483
MDL编号	MFCD03840556

技术规格

Appearance	Light yellow to Brown powder to crystal
Elemental analysis(Carbon)	67.0 to 71.0 %

物性(参考值)

熔点

227 ℃

44-0780

Strem

1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)

98%

735元/100mg; 1669元/500mg; 4963元/2g;

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Technical Notes:

1. In conjugation with lipase, ruthenium catalyst used in the asymmetric transformation of ketones and enol acetates intoacetates.

2.Dynamic kinetic resolution resulting from the ruthenium catalyzed racemization of enzymatically- resolved substrates.

3.Conversion of secondary amines to primary amines in the presence of ammonia.

4. Co-catalyt for aerobic lactonization of diols .

References: 1.Org. Lett.. 2000, 2, 2487. 2.Org. Lett.. 2001, 3, 1209. 3.Chem. Eur. J.2011.17, 4705. 4.Chem. Eur. J..2011. 17, 12596.

046884

Alfa Aesar

1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)

98%

1407元/0.5g; 4978元/2g;

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应用
1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydroteracarbonyldiruthenium(II) is widely used in various types of applications in organic synthesis. It is used for hydrogenation of carbonyls, alkenes and imines. It is also used in the alkylation of amines and amination of propargyl alcohols.

备注
Moisture sensitive. Keep container tightly sealed. Store in cool, dry condition. Protect from humidity and keep away from water. Incompatible with water and oxidizing agents.

基本信息

MDL
MFCD03840556

分子式
C₆₂H₄₂O₆Ru₂

分子量
1085.15

熔点
223-227°

灵敏度
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Crystalline

溶解性
Soluble in water and polar organic solvents.

Merck
14,8483

安全信息

TSCA
否

668281

Sigma-Aldrich

1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)

98%

578.94元/100 MG; 2162.26元/500 MG;

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产品说明

应用

Shvo′s Catalyst
已发现多种用途，如作为有机合成的多功能催化剂，有机合成反应包括醛和酮的还原反应生成醇，醛的双分子歧化反应生成酯，烯丙醇的异构化反应以及醇的氧化反应。

包装

100, 500 mg in glass bottle

基本信息

经验(实验)分子式	C₆₂H₄₂O₆Ru₂
分子量	1085.13
PubChem化学物质编号	24884974
NACRES	NA.22

产品性质

质量水平	100
测定	98%
reaction suitability	core: ruthenium reagent type: catalyst
mp	223-227 ℃
SMILES string	[Ru][RuH].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].O[C]1[C]([C]([C]([C]1c2ccccc2)c3ccccc3)c4ccccc4)c5ccccc5.O=C6C(c7ccccc7)=C(c8ccccc8)C(c9ccccc9)=C6c%10ccccc%10
InChI	1S/C29H21O.C29H20O.4CO.2Ru.H/c230-29-27(23-17-9-3-10-18-23)25(21-13-5-1-6-14-21)26(22-15-7-2-8-16-22)28(29)24-19-11-4-12-20-24;41-2;;;/h1-20,30H;1-20H;;;;;;;
InChI key	PISMVXYUJBWZFB-UHFFFAOYSA-N

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable