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CAS: 104-01-8
分子式: C9H10O3
分子量: 166.17
沸点: 140℃(3 t
熔点: 85-88℃
中文名称: 
4-甲氧基苯乙酸
对甲氧基苯乙酸
4-甲氧基苯基乙酸
对甲氧基甲苯(甲)酸
英文名称: 
Benzeneacetic acid,4-methoxy-
4-Methoxyphenylethanoic acid
p-Methioxy-toluic acid
(4-methoxyphenyl)ethanoic acid
ethanoic acid,(4-methoxyphenyl)-
4-methoxybenzeneethanoic acid
(4-Methoxy-phenyl)-acetic acid
4-methoxy-Benzeneacetic acid
p-methoxyphenyl-acetic aci
2-(p-anisyl)acetic acid
4-methoxybenzeneacetic acid
4-methoxyphenylacetic acid
4-methoxy-benzeneacetic aci
homoanisic acid
p-methoxyphenylacetic acid
展开更多英文名
性质描述: 白色片状结晶体。熔点为86-88.5℃,沸点140℃(0.4kPa)。溶于乙醇和乙醚。
生产方法: 由对甲氧基苯乙酮为原料制得。将乙醇、硫磺及六水哌嗪加入反应锅中回流4h,然后蒸出乙醇。将所得硫化哌嗪与对甲氧基苯乙酮在135-140℃反应20h,再加入氢氧化钠回流20h。反应结束后,冷至35℃以下,用盐酸调整pH值至8-9。用离心机分出硫磺后,再中和至pH值为3-4,冷却,离心脱水,将所得粗品精制即得对甲氧基苯乙酸。
用途: 用于有机合成,用作葛根素的中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M792824MACKLIN4-甲氧基苯乙酸10mM in DMSO185元/1ml;   展开
储存:-20°C
M818238MACKLIN4-甲氧基苯乙酸99%29元/5g;   42元/25g;   85元/100g;   315元/500g;   1380元/2.5kg;   展开
储存:室温
状态:白色到灰白色粉末或固体或块状
M0742TCI4-Methoxyphenylacetic Acid>98.0%(GC)(T)130元/25G;   270元/100G;   960元/500G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C9H10O3 = 166.18
外观与形状(20℃)固体
Reaxys-RN1101737
PubChem物质ID87572748
SDBS (AIST Spectral DB)6359
MDL编号MFCD00004345

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(GC)min. 98.0 %
Purity(Neutralization titration)min. 98.0 %
Melting point85.0 to 88.0 ℃

物性(参考值)

熔点86 ℃
沸点305 ℃

安全信息

图形或危害标志
信号词危险
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H318 : 造成严重眼损伤。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。

相关法规

RTECS#AI8960000
123469J&K4-Methoxyphenylacetic Acid99%60元/5G;   82元/25G;   177元/100G;   688元/500G;   展开

基本信息

分子式C9H10O3
分子量166.17
熔点84-86
沸点140
MDL编码MFCD00004345
Beilstein1101737
EINECS 编号203-166-4

安全信息

图形或危害标志
提示语Danger
危险说明H302
H315
H318
H335
防范说明P261
P280
P305+P351+P338
WGK3
RTECSAI8960000
TSCA
A14399Alfa Aesar4-Methoxyphenylacetic Acid98+%420元/5g;   609元/100g;   2235元/500g;   展开

基本信息

MDL
MFCD00004345

EINECS
203-166-4

分子式
C9H10O3

分子量
166.18

熔点
84-88°

沸点
138-140°/3mm

形态
Powder

Beilstein
1101737

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H315-H318-H335
Toxic if swallowed.Causes skin irritation.Causes serious eye damage.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-37/38-41
Harmful if swallowed.Irritating to respiratory system and skin.Risk of serious damage to eyes.

安全等级
26-36/37/39
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.

欧盟危险品标志

RTECS
AI8960000

TSCA

C12602Alfa Aesar4-Methoxyphenylacetic Acid99%442元/5g;   706元/100g;   1506元/250g;   5612元/1kg;   展开

基本信息

Ref#
12602

MDL
4345

分子式
C9 H10 O3

分子量
166.18

M19201Sigma-Aldrich4-Methoxyphenylacetic AcidReagentPlus®, 99%346.33元/5 G;   576.02元/100 G;   694.05元/250 G;   展开

产品说明

应用

4-甲氧基苯基乙酸已被用于:

  • 采用硫酸化介孔氧化锆催化剂与碳酸二甲酯进行酯化反应制备4-甲氧基苯乙酸甲酯。
  • 作为配体用于合成药理学上重要的双核镓(III)和苯基锡(IV)羧酸盐金属配合物。
  • 作为反应物用于通过与取代苯甲醛的Perkin反应合成羟基化(E)芪。

包装

5, 100 g in poly bottle

其他说明

斯克里普斯代谢组学和质谱技术中心独立生成的串联质谱数据可在 PDF M19201.pdf 中查看或下载。斯克里普斯代谢物组学和质谱技术中心的 METLIN 代谢物数据库中有测试代谢物。要了解更多信息,请访问sigma.com/metlin。

法律信息

ReagentPlus is a registered trademark of sigma-aldrich Co. LLC

基本信息

线性分子式CH3OC6H4CH2CO2H
分子量166.17
Beilstein1101737
EC 号203-166-4
MDL编号MFCD00004345
PubChem化学物质编号24896588
NACRESNA.22

产品性质

产品线ReagentPlus®
质量水平100
测定99%
bp140 ℃/3 mmHg (lit.)
mp84-86 ℃ (lit.)
SMILES stringCOc1ccc(CC(O)=O)cc1
InChI1S/C9H10O3/c1-12-8-4-2-7(3-5-8)6-9(10)11/h2-5H,6H2,1H3,(H,10,11)
InChI keyNRPFNQUDKRYCNX-UHFFFAOYSA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H318
预防措施声明P280 - P305 + P351 + P338
危险分类Eye Dam. 1
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)379.4 °F
闪点(C)193 ℃
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
078964Fluorochem4-Methoxyphenylacetic Acid95%220元/25g;   528元/100g;   展开

基本信息

CAS Number104-01-8
MDL NumberMFCD00004345
Boiling Point305℃
Melting Point86℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H318: Causes serious eye damage.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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