CAS 1034-39-5; 二溴三苯基正膦; dibromotriphenyl-phosphoran

推荐供应商

货号

品牌

产品名称

规格

包装、参考价格

T831129

MACKLIN

二溴三苯基膦

95%

25元/1g; 31元/5g; 78元/25g; 299元/100g; 1303元/500g;

咨询

储存：2~8℃
状态：白色到黄色固体

134566

J&K

Triphenylphosphine dibromide

95%

261元/5G; 1044元/25G; 1946元/50G; 4939元/250G;

咨询

基本信息

分子式	C₁₈H₁₅Br₂P
分子量	422.09
熔点	235
MDL编码	MFCD00000054
Beilstein	917652
EINECS 编号	213-855-1

安全信息

图形或危害标志
提示语	Danger
危险说明	H314
防范说明	P280 P305+P351+P338 P310
UN号码	3261
危险分类	8
包装等级	II
WGK	3

15-0990

Strem

Dibromotriphenylphosphorane

98%

825元/10g; 3240元/50g;

咨询

A11552

Alfa Aesar

Triphenylphosphine dibromide

96%

650元/10g; 2835元/50g; 7609元/250g;

咨询

应用
Triphenylphosphine dibromide is used as a reagent for conversion of aldoximes into nitriles. It acts as a reagent for cleavage of acetals. It reacts with amines to give iminophosphoranes. Further, it serves as a reagent in the preparation of alkyl and aryl bromides from alcohols and phenols without rearrangement.

备注
Moisture sensitive. Store in a cool place. Incompatible with strong bases, strong oxidizing agents, bases and active metals.

基本信息

MDL
MFCD00000054

EINECS
213-855-1

分子式
(C₆H₅)₃PBr₂

分子量
422.10

熔点
ca 260° dec.

灵敏度
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Powder

溶解性
Soluble in water, dichloromethane, acetonitrile, phenyl cyanide, dimethyl formamide, ether, chloroform, alcohol, carbon tetrachloride, acetic acid and carbon disulfide. Sparingly soluble in phenyl chloride, triphenylphosphine and phenyl hydride. Insoluble in aqueous bromine.

Beilstein
917652

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA
是

C29107

Alfa Aesar

Triphenylphosphine dibromide

ca. 33% bromine

7212元/100g; 658元/5g; 2154元/25g;

咨询

基本信息

Ref#
29107

MDL
54

分子式
C18 H15 Br2 P

分子量
422.09

形态
White to pale yellow powder

安全信息

危险等级
8

包装组
II

270946

Sigma-Aldrich

Triphenylphosphine dibromide

96%

402.86元/5 G; 1457.52元/25 G;

咨询

产品说明

应用

由醇和苯酚制备烷基溴和芳基溴的试剂，不发生重排反应。

包装

5, 25 g in glass bottle

基本信息

线性分子式	(C₆H₅)₃PBr₂
分子量	422.09
Beilstein	917652
EC 号	213-855-1
MDL编号	MFCD00000054
PubChem化学物质编号	24856415
NACRES	NA.22

产品性质

质量水平	200
测定	96%
mp	235 ℃ (dec.) (lit.)
SMILES string	BrP(Br)(c1ccccc1)(c2ccccc2)c3ccccc3
InChI	1S/C18H15Br2P/c19-21(20,16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
InChI key	OCXGTPDKNBIOTF-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H314
预防措施声明	P260 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338
危险分类	Skin Corr. 1B
储存分类代码	8A - Combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

940883

Amethyst

Triphenylphosphine dibromide

95%, 用于合成

75元/5G; 301元/25G; 992元/100G;

咨询

基本信息

分子式	C₁₈H₁₅Br₂P
分子量	422.09
熔点	235
MDL编码	MFCD00000054
Beilstein	917652
EINECS 编号	213-855-1

安全信息

图形或危害标志
提示语	Danger
危险说明	H314
防范说明	P280 P305+P351+P338 P310
UN号码	3261
危险分类	8
包装等级	II
WGK	3

043406

Fluorochem

Triphenylphosphine dibromide

95%

220元/1g; 418元/5g; 748元/25g; 2442元/100g; 9966元/500g;

咨询

基本信息

CAS Number	1034-39-5
MDL Number	MFCD00000054
Melting Point	235℃(dec.)

安全信息

图形或危害标志
危险性说明	H314: Causes severe skin burns and eye damage.
防范说明	P260: Do not breathe . P264: Wash hands thoroughly after handling. P280: Wear . P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor/physician. P321: Specific treatment (see . on this label). P363: Wash contaminated clothing before reuse. P405: Store locked up. P501: Dispose of contents/container to local regulations.