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CAS: 1031-93-2
分子式: (C6H5)2PC6H4CH3
分子量: 276.31
熔点: 66-68 ℃(lit.)
中文名称: 
对甲苯基二苯膦
对苯甲基二苯基磷
对苯甲基二苯基膦
英文名称: 
Diphenyl(p-tolyl)phosphine
p-Tolyldiphenylphosphine
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D807802MACKLIN二苯基对甲苯基膦96%36元/2g;   111元/10g;   479元/50g;   展开
储存:室温
状态:白色粉末或晶体
15-5600Stremp-Tolyldiphenylphosphinemin. 96%4995元/25g;   14970元/100g;   展开
155039Sigma-AldrichDiphenyl(p-tolyl)phosphine96%642.64元/10 G;   展开

产品说明

应用

Reactant for:

  • Three-component cyclization
  • Probing coordination ability via a palladium pincer complex
  • Chelation-assisted hydroacylation of olefins with primary alcohols

Reactant for synthesis of:
  • Trinuclear ruthenium carbonyl triarylphosphine cluster complexes
  • Leishmanicidal leads targeting mitochondria through inhibition of the respiratory complex
  • InP nanofibers / metal phosphide nanostructures
  • Peroxyl radical cations via pulse radiolysis one-electron oxidations

包装

10 g in glass bottle

基本信息

线性分子式(C6H5)2PC6H4CH3
分子量276.31
EC 号213-848-3
MDL编号MFCD00008543
PubChem化学物质编号24849330
NACRESNA.22

产品性质

质量水平100
测定96%
形式liquid
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
mp66-68 ℃ (lit.)
官能团phosphine
SMILES stringCc1ccc(cc1)P(c2ccccc2)c3ccccc3
InChI1S/C19H17P/c1-16-12-14-19(15-13-16)20(17-8-4-2-5-9-17)18-10-6-3-7-11-18/h2-15H,1H3
InChI keyQJIMTLTYXBDJFC-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
240272FluorochemDiphenyl(p-tolyl)phosphine95%2420元/10g;   8426元/50g;   展开

基本信息

CAS Number1031-93-2
MDL NumberMFCD00008543
Melting Point66-68℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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