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CAS: 1031-15-8
分子式: C19H18ClP
分子量: 312.77
熔点: 221℃
英文名称: 
Methyl-triphenyl-phosphonium chloride
methyltriphenylphosphonium chloride
推荐供应商
货号品牌产品名称规格包装、参考价格
M812928MACKLIN甲基三苯基氯化磷97%27元/1g;   29元/5g;   30元/25g;   85元/100g;   402元/500g;   咨询
储存:室温,密封
状态:白色粉末,晶体和/或块状
M2702TCIMethyltriphenylphosphonium Chloride>98.0%(T)(HPLC)290元/5G;   990元/25G;   咨询

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C19H18ClP = 312.78
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
Reaxys-RN4168881
PubChem物质ID354333154
MDL编号MFCD00797851

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Nonaqueous Titration)min. 98.0 %
Melting point221.0 to 225.0 ℃

物性(参考值)

熔点223 ℃
水溶性可溶

安全信息

图形或危害标志
信号词危险
危险性说明H302 + H312 : 吞咽或皮肤接触有害。
H315 : 造成皮肤刺激。
H318 : 造成严重眼损伤。
H411 : 对水生生物有毒并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P391 : 收集溢出物。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。

运输信息

UN编号UN3077
类别9
包装类别 III
监管条件代码(*)
H56851Alfa AesarMethyltriphenylphosphonium Chloride97%432元/1g;   1494元/5g;   5770元/25g;   咨询

应用
Methyltriphenylphosphonium chloride is used as a phase transfer catalyst in synthetic chemistry. It acts as a catalyst for regio-controlled ring-opening polymerization of substituted epoxides. It is utilized for controlling the corrosion iron. It acts as a reactant for intramolecular nitrone cycloaddition. In addition to this, it is used for neoplasm inhibition through antimitochondrial effect.

备注
Incompatible with oxidizing agents.

基本信息

MDL
MFCD00797851

EINECS
418-400-2

分子式
C19H18ClP

分子量
312.78

熔点
221° dec.

灵敏度
Hygroscopic. Ambient temperatures.

形态
Powder

溶解性
Soluble in methanol.

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H315-H318-H411
Harmful if swallowed.Harmful in contact with skin.Causes skin irritation.Causes serious eye damage.Toxic to aquatic life with long lasting effects.

Precautionary Statements
P280-P305+P351+P338-P310a-P301+P312a-P321-P501a
Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Specific treatment (see label).Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
9

包装组
III

危险类别
21/22-38-41-51/53
Harmful in contact with skin and if swallowed.Irritating to skin.Risk of serious damage to eyes.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
22-26-36/37/39-61
Do not breathe dust.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.Avoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

TSCA
否

468002Sigma-AldrichMethyltriphenylphosphonium Chloride97%1514.83元/5 G;   咨询

产品说明

应用

Catalyst for regio-controlled ring-opening polymerization of substituted epoxides
Used for:

  • Corrosion inhibition of iron
  • Neoplasm inhibition via antimitochondrial effect

Reactant for intramolecular nitrone cycloaddition

包装

5, 25 g in glass bottle

基本信息

线性分子式CH3P(C6H5)3Cl
分子量312.77
EC 号418-400-2
MDL编号MFCD00797851
PubChem化学物质编号24870456
NACRESNA.22

产品性质

质量水平100
测定97%
reaction suitabilityreaction type: C-C Bond Formation
mp221 ℃ (dec.) (lit.)
SMILES string[Cl-].C[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI1S/C19H18P.ClH/c1-20(17-11-5-2-6-12-17,18-13-7-3-8-14-18)19-15-9-4-10-16-19;/h2-16H,1H3;1H/q+1;/p-1
InChI keyQRPRIOOKPZSVFN-UHFFFAOYSA-M

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 + H312 - H315 - H318 - H411
预防措施声明P273 - P280 - P301 + P312 + P330 - P302 + P352 + P312 - P305 + P351 + P338 + P310
危险分类Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
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