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CAS: 103-64-0
分子式: C8H7Br
分子量: 183.04
沸点: 110-112℃
熔点: 7-112℃
中文名称: 
ω-溴代苯乙烯
β-溴苯乙烯
2-溴乙烯基苯
溴代苏合香烯
1-溴-2-苯乙烯
ω-溴苯乙烯
β-溴乙烯苯
ω-溴苏合香烯
1-溴-2-苯基乙烯
苯乙烯基溴
英文名称: 
(2-bromo-vinyl)-benzene
Benzene,(2-bromoethenyl)-
β-Bromostyrene
-Bromostyrene
-Bromovinylbenzene
-Bromostyrol
b-bromostyrene
á-Bromostyrene,cis +trans
.beta.-Bromostyrene
(2-bromoethenyl)-Benzene
2-Bromostyrol
1-Bromo-2-phenylethylene
beta-bromo-styren
(2-bromoethenyl)benzene
(2-bromovinyl)benzene
1-bromo-2-phenylethene
alpha-bromo-beta-phenylethylene
(2-bromoethenyl)-benzen
beta-bromostyrene
beta-bromstyrol
bromostyrol
bromostyrolene
bromstyrole
hyacinth base
omega-bromostyrene
styryl bromide
beta-bromostyrene, mixture of cis/trans isomers
展开更多英文名
性质描述: 淡黄色液体。熔点7℃,沸点219-220℃,108℃(2.67kPa),相对密度1.4269(16℃),折光率1.6066。能溶于4份90%醇,不溶于水,易聚合。闪点79℃。
生产方法: 由肉桂酸溴化而得。在肉桂酸中加入溴素,生成二溴代肉桂酸,再加入碳酸钠并经水蒸气蒸馏,同时进行脱CO2与脱HBr而生成溴代苏合香烯。产率约80%。
用途: 具强烈的素花馨。为卤代烃类香料的代表性产品,天然不存在,均由人工合成。该品的香调不属最上品,因此高级香精均未采用,但因其价格适中,故常用作皂用香精。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
B830808MACKLINbeta-溴苯乙烯97%(cis- and trans- mixture)48元/5g;   139元/25g;   428元/100g;   2136元/500g;   展开
储存:2~8℃
状态:无色到黄色到棕色液体
B0655TCIβ-Bromostyrene (cis- and trans- mixture)>95.0%(GC)305元/25G;   展开

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C8H7Br = 183.05
外观与形状(20℃)液体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况空气,加热
Reaxys-RN1903529
PubChem物质ID87563661
MDL编号MFCD00000185

技术规格

AppearanceLight yellow to Yellow clear liquid
Purity(GC)min. 95.0%(total of isomer)

物性(参考值)

闪点120 ℃
比重1.42
折射率1.61

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。

相关法规

RTECS#WL3850000
C16929Alfa Aesarbeta-Bromostyrene97%, mixture of cis/trans isomers1132元/5ml;   3966元/25ml;   11336元/100ml;   展开

基本信息

Ref#
16929

MDL
185

分子式
C8 H7 Br

分子量
183.05

闪点
79

密度
1.42

形态
Yellow/green liquid

157449Sigma-Aldrichβ-Bromostyrene97%603.97元/5 G;   展开

产品说明

一般描述

β-溴代苯乙烯是一种α ,β-不饱和芳族卤化物。它可以通过肉桂酸的催化Hunsdiecker反应(CHR)进行合成。 它通常用作制备取代的烯烃、相应的乙炔、以及天然化合物和抗生素全合成的前体。

应用

β-溴苯乙烯可用于一锅法制备肉桂腈。 它也可用于制备纯乙酯- Z-和 E-α ,α -二氟-4-苯基-3-丁烯酸乙酯 和1,3-二苯基-1-丁烯。 在二氯[1,1′-双(二苯基膦基)二茂铁]镍(II)催化剂存在下,它可用于与丁基氯化镁交叉偶联,合成β--丁基苯乙烯。 它也可用于在炔烃存在下与羰基镍反应制备γ -丁-2-烯内酯。

包装

5 g in glass bottle

基本信息

线性分子式C6H5CH=CHBr
分子量183.05
Beilstein2038495
EC 号203-131-3
MDL编号MFCD00000185
PubChem化学物质编号24849679
NACRESNA.22

产品性质

质量水平100
测定97%
形式liquid
折射率n20/D 1.607 (lit.)
bp110-112 ℃/20 mmHg (lit.)
mp7 ℃ (lit.)
密度1.427 g/mL at 25 ℃ (lit.)
储存温度2-8℃
SMILES stringBr\C=C\c1ccccc1
InChI1S/C8H7Br/c9-7-6-8-4-2-1-3-5-8/h1-7H/b7-6+
InChI keyYMOONIIMQBGTDU-VOTSOKGWSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302
危险分类Acute Tox. 4 Oral
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)215.6 °F - closed cup
闪点(C)102 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
049835Fluorochembeta-Bromostyrene95%220元/1g;   308元/10g;   506元/25g;   1518元/100g;   展开

基本信息

CAS Number103-64-0
MDL NumberMFCD00000185
Density1.427

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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