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CAS: 103-49-1
分子式: C14H15N
分子量: 197.28
沸点: 300℃
熔点: -26-163℃
中文名称: 
二苄胺
N,N-二苄基苯胺
N-(苯基甲基)苯甲胺
N-苯甲基苯甲胺
英文名称: 
Dibenzylamine
N-(phenylmethyl)-Benzenemethanamine
N,N-Dibenzyl aniline
n-(phenylmethyl)-benzenemethanamin
dibenzyl-amine
N-(Phenylmethyl)benzenemethanamine
Benzenemethanamine,N-(phenylmethyl)-
性质描述: 无色至淡黄色油状液体。熔点-26℃,沸点300℃(部分分解),270℃(33.3kPa),相对密度1.0256(22/4℃),折光率1.5743(22℃),闪点143℃。易溶于醇和醚,几乎不溶于水。有氨臭。
生产方法: 由氯苄与液氨在乙醇中反应而得。
用途: 二苄胺是重要的有机合成中间体,可用来合成青霉素和橡胶、塑料固化的熟化剂,主要用来生产高效无毒的硫化促进剂二硫化四苄基秋兰姆(TBZTD)和二苄基二硫代氨基甲酸锌(ZBEC)。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D766717MACKLIN二苄胺10mM in DMSO189元/1ml;   展开
储存:-20°C, 惰性气体
折射率:n20/D 1.574(lit.)
D807201MACKLIN二苄胺98%56元/100ml;   152元/500ml;   440元/2.5L;   1260元/10L;   展开
储存:室温
状态:无色液体
折射率:n20/D 1.574(lit.)
D0152TCIDibenzylamine>97.0%(GC)165元/25G;   685元/500G;   展开

基本信息

纯度/分析方法>97.0%(GC)
分子式/分子量C14H15N = 197.28
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN909664
PubChem物质ID87566880
SDBS (AIST Spectral DB)2064
Merck Index (14)3011
MDL编号MFCD00004770

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 97.0 %

物性(参考值)

熔点-26 ℃
沸点270 ℃/250 mmHg
闪点150 ℃
比重1.03
折射率1.57
水溶性不溶
溶解性(可溶于)醇,乙醚

安全信息

图形或危害标志
信号词危险
危险性说明H302 : 吞咽有害。
H314 : 造成严重皮肤灼伤和眼损伤。
H411 : 对水生生物有毒并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P391 : 收集溢出物。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。

运输信息

UN编号UN2735
类别8
包装类别 III
监管条件代码(*)
224836J&KDibenzylamine99%66元/25G;   107元/100G;   287元/500G;   展开

基本信息

分子式C14H15N
分子量197.28
熔点-26
沸点300
闪点143
密度1.026
折光率(n20D)1.5740
MDL编码MFCD00004770
Beilstein909664
Merck14,3011
EINECS 编号203-117-7

安全信息

图形或危害标志
提示语Danger
危险说明H302
H314
防范说明P280
P305+P351+P338
P310
UN号码2735
危险分类8
包装等级III
WGK3
TSCA
A11554Alfa AesarDibenzylamine98%916元/250g;   1862元/1000g;   7300元/5000g;   展开

应用
Dibenzylamine is used to prepare rubber accelerator for the vulcanization process and reaction-stoppers. Dibenzylamine type accelerators reduce nitrosamine production in the compounding process. It is also used to produce dibenzyl-nitroso-amine.

备注
Air Sensitive. Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

基本信息

MDL
MFCD00004770

EINECS
203-117-7

分子式
C14H15N

分子量
197.28

熔点
-26°

沸点
300°

闪点
143°(289°F)

密度
1.026

折射率
1.5745

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Soluble in water(0.4g/L).

Beilstein
909664

Merck
14,3011

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H314-H318-H410
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
22-34-50/53
Harmful if swallowed.Causes burns.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
20-23-26-36/37/39-45-57-60
When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Use appropriate container to avoid environmental contamination.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

C11261Alfa AesarDibenzylamine98%3517元/250ml;   16896元/1L;   展开

基本信息

Ref#
11261

MDL
4770

分子式
C14 H15 N

分子量
197.28

闪点
138

密度
1.02

形态
Liquid

安全信息

危险等级
8

包装组
III

D34108Sigma-AldrichDibenzylamine97%367.65元/5 G;   416.15元/100 G;   969.02元/500 G;   展开

基本信息

线性分子式(C6H5CH2)2NH
分子量197.28
Beilstein909664
EC 号203-117-7
MDL编号MFCD00004770
PubChem化学物质编号24893752
NACRESNA.22

产品性质

质量水平200
测定97%
折射率n20/D 1.574 (lit.)
bp300 ℃ (lit.)
mp−26 ℃ (lit.)
密度1.026 g/mL at 25 ℃ (lit.)
SMILES stringC(NCc1ccccc1)c2ccccc2
InChI1S/C14H15N/c1-3-7-13(8-4-1)11-15-12-14-9-5-2-6-10-14/h1-10,15H,11-12H2
InChI keyBWLUMTFWVZZZND-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H314 - H410
预防措施声明P270 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1C
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)289.4 °F - closed cup
闪点(C)143 ℃ - closed cup
个人防护装备Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
CRM95728SupelcoDibenzylaminecertified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland2245.39元/100 mg;   展开

产品说明

一般描述

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma aldrich.com

其他说明

Ion Mobility: TWCCSN2 value of 146.9 Å2 [M+H]+

The collision cross section (CCS) measurement was provided by Waters Corporation, using the SYNAPT XS mass spectrometer.
For a description and overview of how ion mobility enables the measurement of the CCS of an ion visit ims.waters.com.
Further information on the SYNAPT XS mass spectrometer can be found on the IMS microsite and product webpage.

TWCCS measurements are expected to be within 2% of this reference value.

P/N CRM95728 is part of the Waters Extractables & Leachables UNIFI scientific library which can be downloaded from Waters Marketplace.

法律信息

TraceCERT is a registered trademark of sigma-aldrich Co. LLC

基本信息

线性分子式(C6H5CH2)2NH
分子量197.28
Beilstein909664
MDL编号MFCD00004770

产品性质

质量水平300
等级certified reference material
TraceCERT®
产品线TraceCERT®
保质期limited shelf life, expiry date on the label
折射率n20/D 1.574 (lit.)
bp300 ℃ (lit.)
mp−26 ℃ (lit.)
密度1.026 g/mL at 25 ℃ (lit.)
储存温度2-8℃
SMILES stringC(NCc1ccccc1)c2ccccc2
InChI1S/C14H15N/c1-3-7-13(8-4-1)11-15-12-14-9-5-2-6-10-14/h1-10,15H,11-12H2
InChI keyBWLUMTFWVZZZND-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H314 - H410
预防措施声明P270 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1C
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)289.4 °F - closed cup
闪点(C)143 ℃ - closed cup
235564FluorochemDibenzylamine97%264元/25g;   440元/100g;   1100元/500g;   展开

基本信息

CAS Number103-49-1
MDL NumberMFCD00004770
Boiling Point300℃
Density1.026

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H410: Very toxic to aquatic life with long lasting effects.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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