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CAS: 103-33-3
分子式: C12H10N2
分子量: 182.22
沸点: 293℃
熔点: 68-69℃
中文名称: 
偶氮苯
二苯基二氮烯
英文名称: 
Benzene azobenzene
Diazene,diphenyl-
Azobenzene solution
AZOBENZENE,1GM,NEAT
Azobenzene
diphenyl-Diazene
1,2-diphenyldiazene
azobenzeen
azobenzeen (dutch)
azobenzide
azobenzol
azobisbenzene
azodibenzene
azodibenzeneazofume
trans-azobenzene
azofume
trans-diphenyl-diazene
azobis-benzen
benzeneazobenzene,trans-
benzene, azodi
trans-diphenyldiazene
benzeneazobenzene
Diphenyl-diazene
benzofume
Diazene,diphenyl-,(E)-
diphenyl-diazen
diazobenzene
diphenyldiazene
diphenyldiimide
ent 14,611
nci-c02926
usaf ek-704
展开更多英文名
性质描述: 该品为橙红色片状结晶体。熔点为68.5℃,沸点为293℃,相对密度为1.203(20/4℃),折光率1.6266。能溶于醇、醚、苯和冰醋酸,不溶于水。
生产方法: 由硝基苯按下面反应而得。将硝基苯、甲醇及氢氧化钠溶液加热保持76℃,在搅拌下慢慢加锌粉,保温搅拌16h;再加入锌粉,保温反应48h。趁热过滤,冷却,在粗品中加入20%盐酸在70℃下溶化后,冷却过滤,将结晶物在水浴中加热70-80℃,放冷过滤,最后经用乙醇重结晶、干燥而得。
用途: 用于联苯染料的制造,也用作橡胶促进剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
A796394MACKLIN偶氮苯溶液2000μg/mL in Methanol396元/1ml;   展开
储存:2-8°C
A796395MACKLIN偶氮苯溶液1000μg/mL in Methanol218元/1ml;   展开
储存:2-8°C
A741750MACKLIN偶氮苯分析对照品,99.5%78元/100mg;   490元/1g;   展开
储存:2~8°C
A741751MACKLIN偶氮苯99%140元/5g;   432元/25g;   1478元/100g;   5179元/500g;   展开
储存:2~8°C
A800377MACKLIN偶氮苯97%52元/1g;   118元/5g;   360元/25g;   1232元/100g;   5018元/500g;   展开
储存:2~8°C
状态:橙色到棕色或红色粉末或晶体
A0565TCIAzobenzene>98.0%(GC)365元/25G;   1150元/100G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C12H10N2 = 182.23
外观与形状(20℃)固体
Reaxys-RN742610
PubChem物质ID87562157
SDBS (AIST Spectral DB)858
Merck Index (14)917
MDL编号MFCD00003022

技术规格

AppearanceLight yellow to Yellow to Orange powder to crystal
Purity(GC)min. 98.0 %
Melting point66.0 to 70.0 ℃

物性(参考值)

熔点68 ℃
沸点293 ℃
水溶性不溶
在水中的溶解度6.4 mg/l   25 ℃
溶解性(可溶于)乙醚,苯,醇

安全信息

图形或危害标志
信号词危险
危险性说明H302 + H332 : 吞咽或吸入有害。
H373 : 长期或反复接触可能损害器官。
H341 : 怀疑可造成遗传性缺陷。
H350 : 可能致癌。
H410 : 对水生生物毒性极大并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P391 : 收集溢出物。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。
P405 : 存放处须加锁。

相关法规

RTECS#CN1400000

运输信息

UN编号UN3077
类别9
包装类别 III
监管条件代码(*)
469471J&KAzobenzene98%295元/25G;   870元/100G;   展开

基本信息

分子式C12H10N2
分子量182.23
熔点65-68
沸点293
闪点100
密度1.090
MDL编码MFCD00003022
Beilstein1819138
EINECS 编号203-102-5

安全信息

图形或危害标志
提示语Danger
危险说明H302
H332
H341
H350
H373
H410
防范说明P201
P273
P281
P308+P313
P501
UN号码3077
危险分类9
包装等级III
WGK3
RTECSCN1400000
TSCA
A10425Alfa AesarAzobenzene97+%15892元/25g;   4973元/100g;   13418元/500g;   展开

应用
Azobenzene is used to construct photoswitch tethered ligands to turn protein activity on and off. It is also used to increase the extracellular or intracellular concentration of active molecules to study the mechanism of action of sympathetic and parasympathetic neuromediators.

备注
Store at 4?°C. Incompatible with strong oxidizing agents. Air and light sensitive.

基本信息

MDL
MFCD00003022

EINECS
203-102-5

分子式
C12H10N2

分子量
182.23

熔点
65-69°

沸点
293°

密度
1.203

灵敏度
Ambient temperatures.

形态
Crystalline solid

溶解性
Soluble in alcohol, ether, benzene and glacial acetic acid. Insoluble in water.

Merck
14,917

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H332-H341-H350-H373-H400-H410
Harmful if swallowed.Harmful if inhaled.Suspected of causing genetic defects.May cause cancer.May cause damage to organs through prolonged or repeated exposure.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P260-P201-P280-P304+P340-P405-P501a
Do not breathe dust/fume/gas/mist/vapours/spray.Obtain special instructions before use.Wear protective gloves/protective clothing/eye protection/face protection.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
9

包装组
III

危险类别
45-20/22-48/22-68-50/53
May cause cancer.Harmful by inhalation and if swallowed.Harmful: danger of serious damage to health by prolonged exposure if swallowed.Possible risk of irreversible effects.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
53-45-60-61
Avoid exposure - obtain special instructions before use.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
CN1400000

TSCA

C40154Alfa AesarAzobenzene98%2869元/50g;   14742元/250g;   展开

基本信息

Ref#
40154

MDL
3022

分子式
C12 H10 N2

分子量
182.23

闪点
100

安全信息

危险等级
9

包装组
III

424633Sigma-AldrichAzobenzene98%667.56元/5 G;   2194.34元/25 G;   展开

产品说明

一般描述

Azobenzene is a chromogen and an azo compound that exhibits trans/cis isomerism yielding isomers that differ in color. It is a simple azoarene compound that shows cis-trans isomerization around the azo bond in response to light.

应用

Azobenzene and its derivatives have multiple applications in the field of mechanical and optical materials, in photopharmacology, and molecular photo-switches including in biological probes.
As human tissue is translucent to red and near-infrared light but opaque to blue and UV light, Azobenzene is important in medicine and photopharmacology for applications that involve shifting the absorptions of both trans and cis isomers of azobenzene to longer wavelengths.

包装

5, 25 g in glass bottle

基本信息

线性分子式C6H5N=NC6H5
分子量182.22
Beilstein1819138
EC 号203-102-5
MDL编号MFCD00003022
PubChem化学物质编号24866581
NACRESNA.47

产品性质

质量水平100
蒸汽压1 mmHg ( 104 ℃)
测定98%
形式powder or crystals
自燃温度890 °F
bp293 ℃ (lit.)
mp65-68 ℃ (lit.)
密度1.09 g/mL at 25 ℃ (lit.)
application(s)diagnostic assay manufacturing
hematology
histology
储存温度room temp
SMILES stringc1ccc(cc1)\N=N\c2ccccc2
InChI1S/C12H10N2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10H/b14-13+
InChI keyDMLAVOWQYNRWNQ-BUHFOSPRSA-N

安全信息

象形图GHS07GHS08GHS09
警示用语:Danger
危险声明H302 + H332 - H341 - H350 - H373 - H410
预防措施声明P202 - P260 - P273 - P301 + P312 - P304 + P340 + P312 - P308 + P313
危险分类Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Muta. 2 - STOT RE 2
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)212.0 °F - closed cup
闪点(C)100.0 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
930221AmethystAzobenzene98%, 用于合成143元/5G;   266元/25G;   783元/100G;   展开

基本信息

分子式C12H10N2
分子量182.23
熔点65-68
沸点293
闪点100
密度1.090
MDL编码MFCD00003022
Beilstein1819138
EINECS 编号203-102-5

安全信息

图形或危害标志
提示语Danger
危险说明H302
H332
H341
H350
H373
H410
防范说明P201
P273
P281
P308+P313
P501
UN号码3077
危险分类9
包装等级III
WGK3
RTECSCN1400000
TSCA
Z-014B-1AccuStandardAzobenzene ,2.0 mg/mL in CH2Cl22.0 mg/mL in CH2Cl2309元/1mL;   展开
Azobenzene偶氮苯103-33-32 mg/mL
358435Fluorochemdiphenyldiazene>98.0%(GC)264元/5g;   528元/10g;   836元/25g;   2530元/100g;   展开

基本信息

CAS Number103-33-3
MDL NumberMFCD00003022
Melting Point65-68℃
Density1.09

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H332: Harmful if inhaled.
H341: Suspected of causing genetic defects ..
H350: May cause cancer ..
H373: May cause damage to organs ..
H400: Very toxic to aquatic life.
H410: Very toxic to aquatic life with long lasting effects.
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P281: Use personal protective equipment as required.
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical advice/attention if you feel unwell.
P330: Rinse mouth.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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