CAS 10293-06-8; 3-溴-1,7,7-三甲基双环[2,2,1]庚-2-酮; (1R)-endo-(+)-3-bromocamphor

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规格

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B838165

MACKLIN

(+)-3-溴樟脑

≥97 % sum of enantiomers

35元/1g; 62元/5g; 150元/25g; 456元/100g;

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储存：室温，干燥
状态：白色到淡黄色固体

B0567

TCI

(+)-3-Bromocamphor

>98.0%(GC)

230元/25G; 1875元/500G;

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基本信息

纯度/分析方法	>98.0%(GC)
分子式/分子量	C₁₀H₁₅BrO = 231.13
外观与形状(20℃)	固体
Reaxys-RN	3197237
PubChem物质ID	87563585
Merck Index (14)	1414
MDL编号	MFCD00003744

技术规格

Appearance	White to Almost white powder to crystal
Purity(GC)	min. 98.0 %
Melting point	75.0 to 77.0 ℃
Specific rotation [a]20/D	+130.0 to +145.0 deg(C=2, EtOH)
Solubility in Methanol	almost transparency

物性(参考值)

熔点	76 ℃
沸点	274 ℃
比旋光度 [α]D	137.5° (C=2,EtOH)
溶解性(可溶于)	甲醇

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

相关法规

RTECS#

ED6750000

197852

J&K

(+)-3-Bromocamphor

98%

209元/25G; 689元/100G; 1681元/500G;

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基本信息

分子式	C₁₀H₁₅BrO
分子量	231.13
熔点	75-78
比旋光度([α]20D)	+128° to +132° (C=5, CH3OH)
MDL编码	MFCD00003744
Beilstein	3197237
EINECS 编号	233-652-1

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
RTECS	ED6750000

16571

Sigma-Aldrich

(+)-3-Bromocamphor

purum, ≥97.0% (sum of enantiomers, GC)

670.47元/50 G;

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产品说明

其他说明

作为手性结构单元；用于脱溴-硅烷化和-膦羧化反应

基本信息

经验(实验)分子式	C₁₀H₁₅BrO
分子量	231.13
Beilstein	3197237
EC 号	233-652-1
MDL编号	MFCD00003744
PubChem化学物质编号	57647579
NACRES	NA.22

产品性质

质量水平	200
等级	purum
测定	≥97.0% (sum of enantiomers, GC)
旋光性	[α]20/D +136±3°, c = 1% in ethanol
mp	75-77 ℃
SMILES string	[H][C@@]12CC[C@@](C)(C(=O)[C@H]1Br)C2(C)C
InChI	1S/C10H15BrO/c1-9(2)6-4-5-10(9,3)8(12)7(6)11/h6-7H,4-5H2,1-3H3/t6-,7+,10+/m1/s1
InChI key	NJQADTYRAYFBJN-FWWHASMVSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

094159

Fluorochem

endo-3-Bromo-D-camphor

220元/5g; 572元/25g; 1650元/100g;

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基本信息

CAS Number	10293-06-8
MDL Number	MFCD00003744
Boiling Point	274℃
Melting Point	76℃

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .