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CAS: 102-51-2
分子式: C7H10N2O
分子量: 138.17
沸点: 253.57℃
熔点: 46-48℃
中文名称: 
4-甲氧基-1,2-苯二胺
3,4-二氨基苯甲醚
4-甲氧基邻基苯二胺
英文名称: 
4-Methoxy-1,2-phenylenediamine
3,4-Diaminoanisidine
4-methoxy-o-phenylenediamin
4-methoxy-2-benzenediamine
3,4-diaminoanisole
4-methoxy-1,2-benzenediamine
4-methoxy-o-phenylenediamine
性质描述: 绿色片状结晶。熔点为50-52℃,沸点167-170℃(1.47kPa),溶于乙醚。
生产方法: 由3-硝基对氨基苯甲醚用铁粉还原而得。将60%的乙酸和3-硝基对氨基苯甲醚加入还原锅内,搅拌半小时,加入铁粉。加热至60%,保温反应直至料液渗圈无色即为终点,还原生成4-甲氧基-1,2-苯二胺。
用途: 该品可作染料中间体。用于制取分散荧光黄Ⅱ。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M828055MACKLIN4-甲氧基邻苯二胺≥95%116元/5g;   409元/25g;   1525元/100g;   展开
储存:2-8℃,避光,惰性气体
状态:灰色或棕色或紫色晶体或熔融固体或液体
物化性质:Soluble in dimethyl sulfoxide and methanol.
折射率:1.5200
M2882TCI4-Methoxybenzene-1,2-diamine>98.0%(GC)(T)590元/1G;   2350元/5G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C7H10N2O = 138.17
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况光,空气
Reaxys-RN878789
MDL编号MFCD00047837

技术规格

AppearanceWhite to Amber powder to crystal
Purity(GC)min. 98.0 %
Purity(Nonaqueous Titration)min. 98.0 %
Melting point48.0 to 52.0 ℃
NMRconfirm to structure

物性(参考值)

熔点50 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#ST2690000
A15557Alfa Aesar4-Methoxy-o-phenylenediamine98%600元/1g;   2766元/5g;   9360元/25g;   展开

应用
4-Methoxy-o-phenylenediamine is widely used as an intermediate in organic synthesis and pharmaceuticals. It is an important precursor for the synthesis of other heterocyclic compounds. It is used in the determination of glyoxal, methylglyoxal, and diacetyl in urine using 4-methoxy-o-phenylenediamine as a derivatizing reagent by High-performance liquid chromatography (HPLC).

备注
Air sensitive and Hygroscopic. Incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents.

基本信息

MDL
MFCD00047837

分子式
C7H10N2O

分子量
138.17

熔点
46-50°

灵敏度
Keep Cold. Air Sensitive. Store under Argon. Light Sensitive.

形态
Powder

溶解性
Soluble in dimethyl sulfoxide and methanol.

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H332-H315-H319-H335
Harmful if swallowed.Harmful in contact with skin.Harmful if inhaled.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P280h-P305+P351+P338
Wear protective gloves/clothing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

安全信息

危险等级
6.1

包装组
III

危险类别
20/21/22-36/37/38
Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
9-26-36/37-60
Keep container in a well-ventilated place.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
ST2690000

TSCA

092184Fluorochem3,4-Diaminoanisole97%352元/1g;   924元/5g;   1584元/10g;   2244元/25g;   展开

基本信息

CAS Number102-51-2
MDL NumberMFCD00047837
Melting Point46-50℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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