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CAS: 10191-60-3
分子式: C4H6N2S2
分子量: 146.23
熔点: 50-51℃
中文名称: 
氰氨基荒酸二甲酯
氰氨基二硫化碳酸二甲酯
氰亚胺二硫代碳酸二甲酯
二甲基氰基亚氨基二硫代碳酸酯
氰亚氨基二硫代碳酸二甲酯
氰基亚氨基二硫代碳酸二甲酯
N-氰亚胺基-S,S-二硫代碳酸二甲酯
英文名称: 
Dimethyl cyanodithioiminocarbonate
S,S'-Dimethyl N-Cyanodithioiminocarbonate
Dimethyl N-Cyanodithiocarbonimidate
Dimethyl carbodithiocyanamate
Dimethyl N-cyanodithioiminocarbonate
Dimethyl cyanoimidothiocarbonate
Carbonimidodithioic acid,cyano-,dimethyl ester
Dimethyl cyanimino dithiocarbonate
Cyanoimino dithiocarbonic dimethyl ester
Carbonimidodithioic acid, cyano-, dimethyl ester
cyano-carbonimidodithioic aci dimethyl ester
dimethyl cyanocarbonimidodithioate
n-cyanoimido-s,s-dimethyl-dithiocarbonate,remainder water
展开更多英文名
性质描述: 黄色或黄绿色晶体。有恶臭气味,有毒。熔点49-54℃。
生产方法: 石灰氮与二硫化碳反应得到二硫代钙盐。经离心分离残渣后,二硫代钙盐溶液与硫酸二甲酯进行甲酯化反应,得氰亚胺二硫代碳酸二甲酯。再经分离去除硫酸钙及蒸出低沸物,得到成品。工业品含量≥90%原料消耗定额:石灰氮(含N20%)1550kg/t、二硫化碳950kg/t、硫酸二甲酯(98%)2200kg/t。
用途: 医药中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D807148MACKLINN-氰基二硫代亚胺碳酸二甲酯90%68元/25g;   189元/100g;   404元/500g;   1615元/2.5kg;   展开
储存:室温,密封
状态:灰白色到黄色或棕褐色固体
D1798TCIS,S'-Dimethyl N-Cyanodithioiminocarbonate>98.0%(N)370元/25G;   1310元/250G;   展开

基本信息

纯度/分析方法>98.0%(N)
分子式/分子量C4H6N2S2 = 146.23
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN635998
PubChem物质ID87568267
MDL编号MFCD00009825

技术规格

Purity(with Total Nitrogen)min. 98.0 %
Melting point53.0 to 58.0 ℃

物性(参考值)

熔点54 ℃
溶解性(微溶于)甲醇

安全信息

图形或危害标志
信号词危险
危险性说明H302 : 吞咽有害。
H314 : 造成严重皮肤灼伤和眼损伤。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘或烟雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。

运输信息

UN编号UN1759
类别8
包装类别 III
监管条件代码(*)
273799J&KDimethyl cyanodithioiminocarbonate98%231元/25G;   540元/100G;   2155元/500G;   展开

基本信息

分子式C4H6N2S2
分子量146.24
熔点45-50
闪点>113
MDL编码MFCD00009825
Beilstein635998
EINECS 编号233-467-6

安全信息

图形或危害标志
提示语Danger
危险说明H302
H314
防范说明P280
P305+P351+P338
P310
UN号码1759
危险分类8
包装等级II
WGK3
TSCA
A11043Alfa AesarDimethyl cyanodithioiminocarbonate95%479元/25g;   1337元/100g;   4395元/500g;   展开

应用
Dimethyl cyanodithioiminocarbonate has been used in the synthesis of 4-methylthiopyrazolo[1,5-a]-1,3,5-triazines, methylsulfanylpyrimidines, cyanoguanidines and N-aryl-6-methylsulfanyl-4-oxopyrimidine-5-carbonitriles. It has been also used in the synthesis of methylsulfanyl derivatives of azoloazines and azoloazoles.

备注
Stable under recommended storage conditions. Incompatible with oxidizing agents.

基本信息

MDL
MFCD00009825

EINECS
233-467-6

分子式
C4H6N2S2

分子量
146.23

熔点
50-56°

闪点
>110°(230°F)

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Slightly soluble in methanol.

Beilstein
635998

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H332-H314-H318
Harmful if swallowed.Harmful in contact with skin.Harmful if inhaled.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
20/21/22-34
Harmful by inhalation, in contact with skin and if swallowed.Causes burns.

安全等级
9-20-26-36/37/39-45-60
Keep container in a well-ventilated place.When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

249637Sigma-AldrichDimethyl N-cyanodithioiminocarbonate90%1636.77元/50 G;   展开

产品说明

应用

Dimethyl N-cyanodithioiminocarbonate has been used in the synthesis of:

  • 4-methylthiopyrazolo[1,5-a]-1,3,5-triazines
  • methylsulfanyl derivatives of azoloazines and azoloazoles
  • methylsulfanylpyrimidines
  • N-aryl-6-methylsulfanyl-4-oxopyrimidine-5-carbonitriles
  • cyanoguanidines

包装

50, 250 g in glass bottle

其他说明

残留物为水

基本信息

线性分子式(CH3S)2C=NCN
分子量146.23
Beilstein635998
EC 号233-467-6
MDL编号MFCD00009825
PubChem化学物质编号24855008
NACRESNA.22

产品性质

质量水平100
测定90%
mp45-50 ℃ (lit.)
SMILES stringCS\C(SC)=N\C#N
InChI1S/C4H6N2S2/c1-7-4(8-2)6-3-5/h1-2H3
InChI keyIULFXBLVJIPESI-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H302 - H314
预防措施声明P260 - P270 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
450488FluorochemDimethyl cyanocarbonimidodithioate95%220元/1g;   396元/25g;   1430元/100g;   3058元/250g;   6006元/500g;   展开

基本信息

CAS Number10191-60-3
MDL NumberMFCD00009825
Melting Point54℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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