CAS 1019-71-2; 二(对甲苯基)氯化膦; chlorodi(p-tolyl)phosphine

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货号

品牌

产品名称

规格

包装、参考价格

详情

B835872

MACKLIN

双(4-甲基苯基)氯膦

95%

90元/50mg; 239元/250mg; 901元/1g; 2050元/5g;

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储存：室温，干燥，惰性气体氛围
状态：无色-黄色液体
折射率：n20/D 1.501

H25889

Alfa Aesar

Chlorodi(p-tolyl)phosphine

95%

1628元/1g; 5325元/5g;

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应用
Chlorodi(p-tolyl)phosphine is used as a reactant for synthesis of palladium catalysts for C-C bond forming cross-coupling reactions, ligands for nickel(0)-catalyzed isomerization reactions, phosphinosulfonamide nickel complexes for oligomerization reactions. It is a reactant for phosphinylation reactions.

备注
Air and moisture sensitive. Incompatible with oxidizing agents, water/ moisture.

基本信息

MDL
MFCD01630844

EINECS
000-000-0

分子式
C₁₄H₁₄ClP

分子量
248.69

沸点
180-184°/10mm

密度
1.159

灵敏度
Moisture Sensitive. Air Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Liquid

溶解性
Reacts with water.

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
20-26-36/37/39-45
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA
否

695815

Sigma-Aldrich

Bis(4-methylphenyl)chlorophosphine

96%

835.07元/1 G;

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产品说明

应用

Reactant for synthesis of:

Palladium catalysts for C-C bond forming cross-coupling reactions
Ligands for nickel(0)-catalyzed isomerization reactions
Phosphinosulfonamide nickel complexes for oligomerization reactions

Reactant for:

Pd-catalyzed intramolecular asymmetric allylic amination and ring-closing metathesis
Phosphinylation reactions

包装

1 g in glass bottle
250 mg in glass bottle

基本信息

经验(实验)分子式	C₁₄H₁₄ClP
分子量	248.69
MDL编号	MFCD01630844
PubChem化学物质编号	329761777
NACRES	NA.22

产品性质

质量水平	100
测定	96%
形式	liquid
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand
折射率	n20/D 1.501
密度	1.1 g/mL at 25 ℃
官能团	phosphine
SMILES string	Cc1ccc(cc1)P(Cl)c2ccc(C)cc2
InChI	1S/C14H14ClP/c1-11-3-7-13(8-4-11)16(15)14-9-5-12(2)6-10-14/h3-10H,1-2H3
InChI key	BJBXRRHIBSXGLF-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H314
预防措施声明	P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405
危险分类	Skin Corr. 1B
补充剂危害	EUH014
储存分类代码	8A - Combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

532551

Fluorochem

Chlorodi(p-tolyl)phosphine

95%

4576元/1g; 13662元/5g;

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基本信息

CAS Number	1019-71-2
MDL Number	MFCD01630844