[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 1013-88-3
关键词:       仅模糊查询
CAS: 1013-88-3
分子式: C13H11N
分子量: 181.23
沸点: 151℃(10
中文名称: 
二苯酮亚胺二苯甲酮亚胺
二苯甲酮亚胺
二苯基酮亚胺
英文名称: 
benzophenone imine
benzophenoneimine
benzhydrylideneamine
Diphenylmethanimine
Benzenemethanimine,-phenyl-
性质描述: 无色液体。沸点151-153℃(1.33kPa),相对密度1.080,折光率1.6169。
生产方法: 将二苯甲酮肟加热,分解生成二苯甲酮和二苯甲酮亚胺,向反应混合物通入干燥的氯化氢气体,使二苯甲酮亚胺成盐析出,滤出亚胺盐,再用碱中和,即得游离的二苯甲酮亚胺。
用途: 用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
B831084MACKLIN二苯甲酮亚胺97%28元/5g;   51元/25g;   158元/100g;   653元/500g;   3060元/2.5kg;   展开
储存:室温,密封
状态:无色到浅黄色液体
B1912TCIBenzophenone Imine>95.0%(GC)390元/5G;   1100元/25G;   展开

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C13H11N = 181.24
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN1100371
PubChem物质ID87564798
SDBS (AIST Spectral DB)39460
MDL编号MFCD00001760

技术规格

AppearanceColorless to Light orange to Yellow clear liquid
Purity(GC)min. 95.0 %

物性(参考值)

沸点108 ℃/1 mmHg
比重1.08
折射率1.62

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
139939J&KBenzophenone Imine98%443元/5G;   1309元/25G;   3710元/100g;   展开

基本信息

分子式C13H11N
分子量181.24
沸点151-153
闪点109
密度1.08
折光率(n20D)1.6180
MDL编码MFCD00001760
Beilstein1100371
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
H30110Alfa AesarBenzophenone Imine95%, Stab.906元/5g;   3040元/25g;   展开

应用
Useful in the preparation of nitrile ylide dimers.Benzophenone imine as ammonia surrogate. As intermediate material for synthesis of organic chemicals. Catalytic enantioselective alkylation of the benzophenone imine of glycine t-butyl ester using phosphazene (Schwesinger) bases and chiral quaternary ammonium salts yields either enantiomer of amino acid derivatives in excellent yield.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

基本信息

MDL
MFCD00001760

分子式
C13H11N

分子量
181.23

沸点
151-153°/10mm

密度
1.08

折射率
1.6180

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Insoluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA

C36859Alfa AesarBenzophenone Imine97%, stabilized921元/5g;   4057元/25g;   11815元/100g;   展开

基本信息

Ref#
36859

MDL
1760

分子式
C13 H11 N

分子量
181.23

闪点
145

密度
1.08

安全信息

危险等级
9

包装组
III

293733Sigma-AldrichBenzophenone Imine95%865.59元/5 G;   2648.88元/25 G;   展开

产品说明

包装

5, 25 g in glass bottle

应用

用于腈产量二聚体的制备。

基本信息

线性分子式(C6H5)2C=NH
分子量181.23
Beilstein1100371
MDL编号MFCD00001760
PubChem化学物质编号24857673
NACRESNA.47

产品性质

质量水平100
测定95%
形式liquid
折射率n20/D 1.618 (lit.)
bp151-153 ℃/10 mmHg (lit.)
密度1.08 g/mL at 25 ℃ (lit.)
web metadata keyword.defaultbenzophenone derivatives, imine reduction, sodium benzophenone, benzophenone reduction, imine chemistry, phase-transfer catalysis, imine formation, schiff bases,
application(s)diagnostic assay manufacturing
hematology
histology
储存温度room temp
SMILES stringN=C(c1ccccc1)c2ccccc2
InChI1S/C13H11N/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,14H
InChI keySXZIXHOMFPUIRK-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)228.2 °F - closed cup
闪点(C)109 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter
953595AmethystBenzophenone Imine97%, 用于合成40元/5G;   112元/25G;   310元/100G;   1341元/500G;   展开

基本信息

分子式C13H11N
分子量181.24
沸点151-153
闪点109
密度1.08
折光率(n20D)1.6150 - 1.6190
MDL编码MFCD00001760
Beilstein1100371
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
092251FluorochemBenzophenoneimine98%220元/5g;   352元/25g;   748元/100g;   2728元/500g;   展开

基本信息

CAS Number1013-88-3
MDL NumberMFCD00001760
Boiling Point151 - 153
Density1.08

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H412: Harmful to aquatic life with long lasting effects.
H320: Causes eye irritation
防范说明 P264: Wash hands thoroughly after handling.
P273: Avoid release to the environment.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P362: Take off contaminated clothing and wash before reuse.
P501: Dispose of contents/container to local regulations.
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9