CAS 100516-54-9; (2R,3S)-N-苄氧羰基-2,3-二苯基吗啉-6-酮; Benzyl(2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

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货号

品牌

产品名称

规格

包装、参考价格

B833583

MACKLIN

苯甲基(2R,3S)-(-)-6-氧-4-苄氧羧酸-2,3-二苯基吗啉

98%

63元/200mg; 224元/1g; 856元/5g;

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储存：2~8℃
状态：白色固体

H60821

Alfa Aesar

(5R,6S)-(-)-4-Benzyloxycarbonyl-5,6-diphenyl-2-morpholinone

98%

2512元/1g;

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基本信息

MDL
MFCD00074958

分子式
C₂₄H₂₁NO₄

分子量
387.43

熔点
205-207°

形态
Solid

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA
否

331872

Sigma-Aldrich

(2R,3S)-(-)-N-Z-6-oxo-2,3-diphenylmorpholine

98%

781.02元/1 G;

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产品说明

应用

(2R,3S)-(−)-N-Z-6-oxo-2,3-diphenylmorpholine is a Williams chiral auxiliary, which can be used:

As a template in the preparation of Fmoc-L-cyclopentylglycine, which acts as an angiotensin II antagonist.
In the synthesis of (L)-Fmoc-α-Me-Lys(Boc)-OH, a building block for the synthesis of peptidomimetics.
To introduce chirality in the modified amino acid named N-Fmoc 4-(2′-(di-tert-butylmalonyl))-l-phenylalanine.

包装

1 g in glass bottle
250 mg in glass bottle

基本信息

经验(实验)分子式	C₂₄H₂₁NO₄
分子量	387.43
MDL编号	MFCD00074958
PubChem化学物质编号	24860004
NACRES	NA.22

产品性质

测定	98%
旋光性	[α]25/D −66°, c = 5.5 in methylene chloride
mp	205-207 ℃ (lit.)
储存温度	2-8℃
SMILES string	O=C1CN([C@H]([C@H](O1)c2ccccc2)c3ccccc3)C(=O)OCc4ccccc4
InChI	1S/C24H21NO4/c26-21-16-25(24(27)28-17-18-10-4-1-5-11-18)22(19-12-6-2-7-13-19)23(29-21)20-14-8-3-9-15-20/h1-15,22-23H,16-17H2/t22-,23+/m0/s1
InChI key	HECRUWTZAMPQOS-XZOQPEGZSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

219334

Fluorochem

(2R,3S)-Benzyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate

98%

1980元/1g; 7172元/5g; 24156元/25g;

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基本信息

CAS Number	100516-54-9
MDL Number	MFCD00074958
Melting Point	205-207℃

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .