CAS 1005-56-7; 硫代氯甲酸-O-苯酯; Carbonochloridothioic acid,O-phenyl ester

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货号

品牌

产品名称

规格

包装、参考价格

O816870

MACKLIN

硫代氯甲酸苯酯

98%

30元/1g; 76元/5g; 320元/25g; 1158元/100g; 3575元/500g;

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储存：2~8°C,干燥,密封
状态：澄清黄色到黄色绿色液体
折射率：n20/D 1.581(lit.)

P1236

TCI

Phenyl Chlorothionoformate

>98.0%(GC)(T)

870元/5G; 2915元/25G;

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基本信息

纯度/分析方法	>98.0%(GC)(T)
分子式/分子量	C₇H₅ClOS = 172.63
外观与形状(20℃)	液体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	湿气 (分解)
Reaxys-RN	774830
PubChem物质ID	87575332
SDBS (AIST Spectral DB)	21478
MDL编号	MFCD00004920

技术规格

Appearance	Light yellow to Amber to Dark green clear liquid
Purity(GC)	min. 98.0 %
Purity(Argentometric Titration)	min. 98.0 %

物性(参考值)

沸点	93 ℃/10 mmHg
闪点	81 ℃
比重	1.28
折射率	1.58

安全信息

图形或危害标志
信号词	危险
危险性说明	H314 : 造成严重皮肤灼伤和眼损伤。 H227 : 可燃液体。 H290 : 可能腐蚀金属。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P210 : 远离热源/火花/明火/热表面。禁止吸烟。 P234 : 只能在原容器中存放。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P390 : 吸收溢出物，防止材料损坏。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。 P363 : 沾染的衣服清洗后方可重新使用。 P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。 P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。 P403 + P235 : 存放在通风良好的地方。保持低温。 P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。 P405 : 存放处须加锁。

运输信息

UN编号	UN3265
类别	8
包装类别	II
监管条件代码(*)

596103

J&K

Phenyl Chlorothionoformate

98%

140元/1G; 523元/5G; 1777元/25G;

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基本信息

分子式	C₇H₅ClOS
分子量	172.63
沸点	81-83
闪点	81
密度	1.248
折光率(n20D)	1.581
MDL编码	MFCD00004920
Beilstein	774830
EINECS 编号	213-736-4
存储条件	Store at 0℃

安全信息

图形或危害标志
提示语	Danger
危险说明	H314
防范说明	P280 P301+P330+P331 P305+P351+P338 P310
UN号码	3265
危险分类	8
包装等级	II
WGK	3
TSCA	否

L00838

Alfa Aesar

Phenyl Chlorothionoformate

98+%

410元/1g; 1179元/5g; 5404元/25g;

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应用
Phenyl chlorothionoformate has been used in stereo directed synthesis of optically active, (-)-mintlactone, synthesis of peptide α-thioesters having a variety of C-terminal amino acids, synthesis of scyllo-inositol derivatives, thionocarbonylation of unprotected thymine nucleosides, preparation of phenoxythiocarbonyl esters of protected ribonucleosides. It is also used as a reagent in the thionocarbonylation of unprotected thymine nucleosides. It forms phenoxythiocarbonyl esters of protected ribonucleosides which can be reduced by tributyltin hydride to deoxyribonucleosides.

备注
Moisture, Heat Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents. Stable under recommended storage conditions.

基本信息

MDL
MFCD00004920

EINECS
213-736-4

分子式
C₇H₅ClOS

分子量
172.63

沸点
81-83°/6mm

闪点
81°(177°F)

密度
1.248

折射率
1.5804

灵敏度
Keep Cold. Moisture Sensitive. Store under Nitrogen.

形态
Liquid

溶解性
Soluble in water.

Beilstein
774830

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H314-H318
Combustible liquid.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P280-P305+P351+P338-P309-P310
Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
20-23-26-36/37/39-45-60
When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
否

C21549

Alfa Aesar

Phenyl chlorothionocarbonate

99%

474元/1g; 1528元/5g; 5313元/25g;

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基本信息

Ref#
21549

MDL
4920

分子式
C7 H5 Cl O S

分子量
172.63

闪点
81

密度
1248

安全信息

危险等级
8

包装组
II

234524

Sigma-Aldrich

O-Phenyl chlorothionoformate

99%

848.94元/5 G;

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产品说明

应用

O -百菌清甲酸苯酯已用于：

立体定向合成光学活性，(-)-薄荷内酯
肽 α 的合成-具有多种 C -末端氨基酸的硫酯
司可洛 -肌醇衍生物的合成
无保护胸腺嘧啶核苷的硫代羰基化
受保护核苷的苯氧基硫代羰基酯的制备

包装

1, 5 g in glass bottle

基本信息

线性分子式	ClC(S)OC₆H₅
分子量	172.63
Beilstein	774830
EC 号	213-736-4
MDL编号	MFCD00004920
PubChem化学物质编号	24854046
NACRES	NA.22

产品性质

质量水平	200
测定	99%
形式	liquid
折射率	n20/D 1.581 (lit.)
bp	81-83 ℃/6 mmHg (lit.)
密度	1.248 g/mL at 25 ℃ (lit.)
SMILES string	ClC(=S)Oc1ccccc1
InChI	1S/C7H5ClOS/c8-7(10)9-6-4-2-1-3-5-6/h1-5H
InChI key	KOSYAAIZOGNATQ-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H314
预防措施声明	P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405
危险分类	Skin Corr. 1B
储存分类代码	8A - Combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	177.8 °F - closed cup
闪点(C)	81 ℃ - closed cup
个人防护装备	Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

046963

Fluorochem

2-Phenyl chlorothionoformate

95%

550元/5g; 1870元/25g;

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基本信息

CAS Number	1005-56-7
MDL Number	MFCD00004920
Boiling Point	81-83℃/6mmHg
Density	1.276

安全信息

图形或危害标志
危险性说明	H314: Causes severe skin burns and eye damage.
防范说明	P260: Do not breathe . P264: Wash hands thoroughly after handling. P280: Wear . P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor/physician. P321: Specific treatment (see . on this label). P363: Wash contaminated clothing before reuse. P405: Store locked up. P501: Dispose of contents/container to local regulations.