Technical Notes:

1.Catalyst in conjunction with "pybox" for the asymmetric hydrosilylation of ketones.

2. C-C bond forming reactions.

References:

1.Catalytic Asymmetric Synthesis, 1993, Ch 6, 303.

2.Encyclopedia of Reagents for Organic Synthesis, 1995, Vol. 6, 4409.

3.Chem. Commun., 2003, 2438.

4.Org. L ett., 2003, 5, 893.

5.Chem. Commun., 2004, 1192.

应用
It is used as primary and secondary intermediate, in the preparation of compounds used in homogeneous catalysis.

备注
Hygroscopic. Incompatible with strong bases.

基本信息

MDL
MFCD00011204

EINECS
233-165-4

分子式
Cl₃Rh

分子量
209.26

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Immiscible in water.

Merck
14,8188

GHS危害和防范说明

GHS符号

Hazard Statements
H290-H302-H318-H341
May be corrosive to metals.Harmful if swallowed.Causes serious eye damage.Suspected of causing genetic defects.

Precautionary Statements
P201-P280-P305+P351+P338-P310a-P405-P501a
Obtain special instructions before use.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
41-68
Risk of serious damage to eyes.Possible risk of irreversible effects.

安全等级
23-26-36/37/39-45-60-61
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

RTECS
VI9275000

TSCA
是

应用
It is used in homogeneous catalysis, for example in the industrial prodcution of acetic acid. It is used to coat optic fibres and optical mirrors, and for crucibles, thermocouple elements and headlight reflectors.

备注
Incompatible with strong oxidizing agents. Deliquescent compound. Store in an airtight container.

基本信息

MDL
MFCD00011204

EINECS
233-165-4

分子式
Cl₃Rh

分子量
209.26

灵敏度
Hygroscopic. Ambient temperatures.

形态
Powder

溶解性
Insoluble in water. Soluble in hydroxide and cyanide solutions.

Merck
14,8188

GHS危害和防范说明

GHS符号

Hazard Statements
H290-H302-H318-H341-H413
May be corrosive to metals.Harmful if swallowed.Causes serious eye damage.Suspected of causing genetic defects.May cause long lasting harmful effects to aquatic life.

Precautionary Statements
P201-P280-P305+P351+P338-P310a-P405-P501a
Obtain special instructions before use.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
22-41-68-53
Harmful if swallowed.Risk of serious damage to eyes.Possible risk of irreversible effects.May cause long-term adverse effects in the aquatic environment.

安全等级
26-36/37/39-60-61
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
VI9275000

TSCA
是

基本信息

Ref#
41910

MDL
11204

分子式
Cl3 Rh

分子量
209.26

密度
5.38

形态
Powder

安全信息

危险等级
8

包装组
III

产品说明

应用

氯化铑(III)前体可用于掺杂石墨烯与 Rh 纳米粒子，制备用于电催化的杂合物，应用于能源、传感和生物医学领域。

包装

500 mg in glass insert
2.5 g in glass bottle

外形

疏水型

基本信息

产品性质

安全信息

象形图
警示用语：	Warning
危险声明	H302
预防措施声明	P301 + P312 + P330
危险分类	Acute Tox. 4 Oral
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

基本信息

安全信息

图形或危害标志
危险性说明	H302: Harmful if swallowed. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to local regulations.