[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 100-65-2
关键词:       仅模糊查询
CAS: 100-65-2
分子式: C6H7NO
分子量: 109.13
中文名称: 
苯胲
苯基羟胺
英文名称: 
n-phenyl-hydroxylamin
n-hydroxy-anilin
n-hydroxy-benzenamin
hydroxylamino-benzen
beta-phenylhydroxylamine
n-hydroxyaniline
n-hydroxybenzenamine
n-phenylhydroxylamine
nci-c60093
phenylhydroxyamine
phenylhydroxylamine
Hydroxylaminobenzene
展开更多英文名
性质描述: 黄色针状晶体。溶点81-82℃。能自发爆炸。
生产方法: 将250g(4.7mol)硝基苯和8L水一起猛烈搅拌,于15-20min内分批加入620g(8.1mol)85%锌粉,还原反应中温度升至60-65℃,反应毕,趁热滤除氧化锌,滤液用食盐饱和(约需3kg食盐),冷至0℃,结晶出苯胲。得纯品275-300g,收率62-68%。
用途: 用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
N833478MACKLIN苯基羟胺97 %44元/200mg;   197元/1g;   898元/5g;   2669元/25g;   展开
储存:-20°C, 避光, 惰性气体保存
状态:白色到微米黄色纤维
Y10008Alfa AesarN-Phenylhydroxylamine203元/100mg;   329元/250mg;   534元/1g;   1873元/5g;   展开

基本信息

分子量
109.13

671576Sigma-AldrichN-Phenylhydroxylamine≥95.0%885.92元/1 G;   2697.14元/5 G;   展开

产品说明

应用

N-苯基羟胺作为起始材料,可用于下列合成反应:

  • 通过连续3,3-重排和环脱水反应,用金催化剂与脂肪族末端炔烃进行处理,合成2-烷基吲哚。
  • 通过三组分一锅催化法,与醛和 α, β不饱和醛合成异恶唑烷。
  • 通过homo3+2偶极环加成反应,处理醛和环丙烷,合成四氢1,2-恶嗪。

包装

1, 5 g in poly bottle

基本信息

经验(实验)分子式C6H7NO
分子量109.13
EC 号202-875-6
MDL编号MFCD00045718
PubChem化学物质编号329760431
NACRESNA.22

产品性质

质量水平100
测定≥95.0%
mp80-84 ℃
储存温度−20℃
SMILES stringONc1ccccc1
InChI1S/C6H7NO/c8-7-6-4-2-1-3-5-6/h1-5,7-8H
InChI keyCKRZKMFTZCFYGB-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语:Danger
危险声明H301
预防措施声明P301 + P310
危险分类Acute Tox. 3 Oral
储存分类代码6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
336638FluorochemN-Phenylhydroxylamine90%1452元/1g;   4598元/5g;   7348元/10g;   11814元/25g;   展开

基本信息

CAS Number100-65-2
MDL NumberMFCD00045718
Boiling Point204.59℃
Melting Point80 - 84℃
Density1.1143

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9