基本信息

技术规格

物性(参考值)

安全信息

图形或危害标志
信号词	警告
危险性说明	H303 : 吞咽可能有害。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P312 : 如感觉不适，呼叫急救中心/医生。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

相关法规

基本信息

安全信息

图形或危害标志
提示语	Warning
危险说明	H303 H315 H319
防范说明	P305+P351+P338
WGK	2
RTECS	EB2690000

应用
Bismuth(III) chloride is used as a catalyst in organic synthesis and to prepare other bismuth salts. It is used as a starting material for the preparation of bismuthoxychloride upon hydrolysis. It is an oxidizing agent to prepare metallic bismuth by reducing agent. Further, it catalyzes the Michael reaction and the Mukaiyama-aldol reaction. In addition to this, it is a Lewis acid.

备注
Hygroscopic. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00003461

EINECS
232-123-2

分子式
BiCl₃

分子量
315.34

熔点
230-232°

沸点
ca 430° subl.

密度
4.75

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in hydrochloric acid, nitric acid, diethyl ether, ethyl acetate and acetone. Insoluble in alcohol.

Merck
14,1262

GHS危害和防范说明

GHS符号

Hazard Statements
H303-H314-H318
May be harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
34
Causes burns.

安全等级
3-20-26-36/37/39-45-60
Keep in a cool place.When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
EB2690000

TSCA
是

应用
Catalysts for organic reactions, preparation of Bi salts.Bismuth(III) chloride is used as a catalyst in organic synthesis and to prepare other bismuth salts. It is used as a starting material for the preparation of bismuthoxychloride upon hydrolysis. It is an oxidizing agent to prepare metallic bismuth by reducing agent. Further, it catalyzes the Michael reaction and the Mukaiyama-aldol reaction. In addition to this, it is a Lewis acid.

备注
Hygroscopic. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00003461

EINECS
232-123-2

分子式
BiCl₃

分子量
315.34

熔点
230-232°

沸点
ca 430° subl.

密度
4.75

灵敏度
Hygroscopic. Store under Nitrogen. Ambient temperatures.

形态
Powder

溶解性
Soluble in HCl, HNO{3}, acetone, ethyl acetate. Insoluble in alcohol. Decomposed by water to BiOCl.Soluble in hydrochloric acid, nitric acid, diethyl ether, ethyl acetate and acetone. Insoluble in alcohol.

Merck
14,1262

GHS危害和防范说明

GHS符号

Hazard Statements
H303-H314-H318
May be harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
34
Causes burns.

安全等级
3-20-26-36/37/39-45-60
Keep in a cool place.When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
EB2690000

TSCA
是

应用
It is used as a catalyst in organic chemistry. It is a good source of bismuth and is used to make other bismuth compounds. Also used as a catalyst and to make other bismuth salts.

备注
Hygroscopic, store away form water/moisture. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store under inert gas.

基本信息

MDL
MFCD00003461

EINECS
232-123-2

分子式
BiCl₃

分子量
315.34

熔点
230-232°

沸点
ca 430° subl.

密度
4.75

灵敏度
Hygroscopic. Store under Nitrogen. Ambient temperatures.

形态
Crystalline

溶解性
Soluble in water.

Merck
14,1262

GHS危害和防范说明

GHS符号

Hazard Statements
H303-H314-H318
May be harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
34
Causes burns.

安全等级
3-20-26-36/37/39-45-60
Keep in a cool place.When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
EB2690000

TSCA
是

应用
Bismuth chloride is used as a catalyst in organic synthesis. In particular, it catalyzes the Michael reaction and the Mukaiyama-aldol reaction. The addition of other metal iodides increases its catalytic activity.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away from strong oxidizing agents.

基本信息

MDL
MFCD00003461

EINECS
232-123-2

分子式
BiCl₃

分子量
315.34

熔点
230-232°

沸点
ca 430° subl.

密度
4.75

灵敏度
Hygroscopic. Store under Nitrogen. Ambient temperatures.

形态
Powder, Ampouled under argon

溶解性
It is soluble in methanol, diethyl ether, acetone.

Merck
14,1262

GHS危害和防范说明

GHS符号

Hazard Statements
H303-H314-H318
May be harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
34
Causes burns.

安全等级
3-20-26-36/37/39-45-60
Keep in a cool place.When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
EB2690000

TSCA
是

基本信息

Ref#
20883

MDL
3461

分子式
Bi Cl3

分子量
315.33

密度
4.75

形态
Powder

基本信息

Ref#
31835

MDL
3461

分子式
Bi Cl3

分子量
315.33

密度
4.75

基本信息

产品性质

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319
预防措施声明	P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
危险分类	Eye Irrit. 2 - Skin Irrit. 2
储存分类代码	11 - Combustible Solids
WGK	WGK 2
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

基本信息

产品性质

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319
预防措施声明	P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
危险分类	Eye Irrit. 2 - Skin Irrit. 2
储存分类代码	11 - Combustible Solids
WGK	WGK 2
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

产品说明

包装

5 g in ampule

法律信息

AnhydroBeads is a trademark of sigma-aldrich Co. LLC

基本信息

产品性质

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2
储存分类代码	11 - Combustible Solids
WGK	WGK 2
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

产品说明

一般描述

氯化铋 (III) 是一种无机盐，可由铋与氯反应制得。

应用

氯化铋 (III) 可作为催化剂用于以下过程：

• 醇解、乙酰化和环氧化物水解生成相应的的 β-烷氧基和 β-乙酰氧基醇和二醇。
• 用硫氰酸铵从环氧乙烷制备噻吩。
• 羰基化合物、胺和亚磷酸二烷基酯三组分偶联生成 α-氨基膦酸盐。
• 烯丙基三甲基硅烷与仲苯甲醇的烯丙基化反应。
• [4 + 2] 二烯烃与α-羰基烯二烯烃之间的环加成反应。

包装

25, 100, 500 g in poly bottle

基本信息

产品性质

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2
储存分类代码	11 - Combustible Solids
WGK	WGK 2
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

产品说明

分析说明

Assay (complexometric): ≥ 98.0 %
Identity (ICP-OES): passes test

基本信息

产品性质

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319
预防措施声明	P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
危险分类	Eye Irrit. 2 - Skin Irrit. 2
储存分类代码	13 - Non Combustible Solids
WGK	WGK 2
闪点(F)	Not applicable
闪点(C)	Not applicable

基本信息

安全信息

图形或危害标志
提示语	Warning
危险说明	H303 H315 H319
防范说明	P305+P351+P338
WGK	2
RTECS	EB2690000

基本信息

安全信息

图形或危害标志
提示语	Warning
危险说明	H303 H315 H319
防范说明	P305+P351+P338
WGK	2
RTECS	EB2690000

基本信息

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .

基本信息

安全信息

图形或危害标志
危险性说明	H302: Harmful if swallowed. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to local regulations.