基本信息

技术规格

物性(参考值)

安全信息

图形或危害标志
信号词	危险
危险性说明	H302 + H332 : 吞咽或吸入有害。 H314 : 造成严重皮肤灼伤和眼损伤。 H372 : 长期或反复接触会对器官造成损害。 H373 : 长期或反复接触可能损害器官。 H317 : 可能造成皮肤过敏反应。 H335 : 可能造成呼吸道刺激。 H410 : 对水生生物毒性极大并具有长期持续影响。 H290 : 可能腐蚀金属。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P273 : 避免释放到环境中。 P272 : 受沾染的工作服不得带出工作场地。 P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P234 : 只能在原容器中存放。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P390 : 吸收溢出物，防止材料损坏。 P391 : 收集溢出物。 P314 : 如感觉不适，须求医/就诊。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P333 + P313 : 如发生皮肤刺激或皮疹：求医/就诊。 P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。 P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。 P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。 P403 + P233 : 存放在通风良好的地方。保持容器密闭。 P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。 P405 : 存放处须加锁。

相关法规

运输信息

基本信息

安全信息

图形或危害标志
提示语	Danger
危险说明	H302 H314
防范说明	P280 P305+P351+P338 P310
UN号码	3260
危险分类	8
包装等级	III
WGK	1
RTECS	XP8700000
TSCA	是

基本信息

安全信息

图形或危害标志
提示语	Danger
危险说明	H302 H314
防范说明	P280 P305+P351+P338 P310
UN号码	3260
危险分类	8
包装等级	III
WGK	1
RTECS	XP8700000
TSCA	是

应用
Tin(II) chloride is widely used as a reducing agent in organic synthesis, for example conversion of quinones into hydroquinones, nitroaromatics into aromatic amines, and in Stephen reduction. It can be used to reduce certain metal salts into metals, tin plating, analytical testing of mercury ions, formation of silver mirrors and metal-metal bonds. It is also used for tin-plating, as a mordant in textile dyeing and as a catalyst in the production of polylactic acid. Further it is used as a food additive, wherein it serves as an anti-oxidant and a color retention agent. It can be used in the condensation of aryl aldehydes with cyclohexan-1,3-diones to synthesize xanthenes. It catalyzes direct conversion of aldehydes into beta-keto esters.

备注
Tin(II) chloride is very freely soluble in cold water. If the volume of water increases or at hot condition it hydrolyses to form an insoluble hydroxide derivative.

基本信息

MDL
MFCD00011241

EINECS
231-868-0

分子式
SnCl₂

分子量
189.62

熔点
247°

沸点
652°

密度
3.95

灵敏度
Hygroscopic. Air Sensitive. Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in ethanol, acetone, ether and tetrahydrofuran. Insoluble in xylene.

Merck
14,8783

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H314-H318-H317
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.May cause an allergic skin reaction.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
22-34-43
Harmful if swallowed.Causes burns.May cause sensitization by skin contact.

安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
XP8700000

TSCA
是

应用
Tin(II) chloride is widely used as a reducing agent in organic synthesis, for example conversion of quinones into hydroquinones, nitroaromatics into aromatic amines, and in Stephen reduction. It acts as an antisludging agent and a stabilizer. It can be used to reduce certain metal salts into metals, tin plating and in analytical chemistry to test mercury ions. It is also used as a mordant in textile dyeing and as a catalyst in the production of polylactic acid. It is used as a food additive, wherein it serves as an anti-oxidant and a color retention agent. It can be used in the condensation of aryl aldehydes with cyclohexan-1,3-diones to synthesize xanthenes. It catalyzes direct conversion of aldehydes into beta-keto esters.

备注
Air sensitive and hygroscopic. Keep the container tightly closed. Incompatible with strong bases, strong oxidizing agents, reactive metals and hydrogen peroxide.

基本信息

MDL
MFCD00011241

EINECS
231-868-0

分子式
SnCl₂

分子量
189.62

熔点
247°

沸点
652°

密度
3.95

灵敏度
Hygroscopic. Air Sensitive. Ambient temperatures.

形态
Crystalline

溶解性
Soluble in water, alkalies, alcohol, methy lethyl ketone, methyl acetate, and acetone.

Merck
14,8783

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H314-H318-H317
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.May cause an allergic skin reaction.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

UN#
UN3260

危险等级
8

包装组
III

危险类别
22-34-43
Harmful if swallowed.Causes burns.May cause sensitization by skin contact.

安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
XP8700000

TSCA
是

应用
Tin(II) chloride is widely used as a reducing agent in organic synthesis, for example conversion of quinones into hydroquinones, nitroaromatics into aromatic amines, and in Stephen reduction. It acts as an antisludging agent and a stabilizer. It can be used to reduce certain metal salts into metals, tin plating and in analytical chemistry to test mercury ions. It is also used as a mordant in textile dyeing and as a catalyst in the production of polylactic acid. It is used as a food additive, wherein it serves as an anti-oxidant and a color retention agent. It can be used in the condensation of aryl aldehydes with cyclohexan-1,3-diones to synthesize xanthenes. It catalyzes direct conversion of aldehydes into beta-keto esters.

备注
Air sensitive and hygroscopic. Keep the container tightly closed. Incompatible with strong bases, strong oxidizing agents, reactive metals and hydrogen peroxide.

基本信息

MDL
MFCD00011241

EINECS
231-868-0

分子式
SnCl₂

分子量
189.62

熔点
247°

沸点
652°

密度
3.95

灵敏度
Hygroscopic. Air Sensitive. Ambient temperatures.

形态
Powder, Ampouled under argon

溶解性
Soluble in water, alkalies, alcohol, methyl ethyl ketone, methyl acetate and acetone.

Merck
14,8783

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H314-H318-H317
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.May cause an allergic skin reaction.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
22-34-43
Harmful if swallowed.Causes burns.May cause sensitization by skin contact.

安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
XP8700000

TSCA
是

基本信息

Ref#
19698

MDL
11241

分子式
Cl2 Sn

分子量
189.6

密度
3.95

形态
Crystalline Powder

安全信息

危险等级
9

包装组
III

基本信息

Ref#
F50866

MDL
MFCD00011241

分子式
Cl{2}Sn^.xH{2}O

形态
Solid

安全信息

危险等级
8

基本信息

Ref#
F52363

安全信息

危险等级
8

包装组
III

基本信息

Ref#
F52364

安全信息

危险等级
8

包装组
III

产品说明

一般描述

氯化锡(II)(SnCl₂)99m，也称氯化亚锡，通常用作还原剂。

应用

用该试剂可实现八乙基咔咯锡配合物的合成。这些新化合物仅在共轭环体系处而不是金属中心表现出可逆性氧化。
氯化锡(II)(SnCl₂)用于通过^99m锝(^99mTc)标记化合物。

包装

1, 5 g in ampule

基本信息

产品性质

安全信息

象形图
警示用语：	Danger
危险声明	H290 - H302 + H332 - H314 - H317 - H335 - H373 - H412
预防措施声明	P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338 + P310
危险分类	Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3
靶器官	Cardio-vascular system, Respiratory system
储存分类代码	8B - Non-combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

产品说明

一般描述

氯化亚锡(SnCl₂)被广泛用作还原剂。它在不同的科学领域发挥着重要作用。由于它在熔融状态下具有出色的催化作用，因此它被用于煤的加氢液化。它是用于半导体层化学气相沉积(CVD)的理想原材料。它可以通过使用其二水合物与乙酸酐反应来制备。它在酸性介质中表现出还原性。它参与还原下列化合物：

• 芳香族硝基化合物
• 腈
• 氰基甲硅烷基醚
• 有机叠氮化物

应用

氯化亚锡可用于：

• 催化重氮砜、重氮氧化膦和重氮膦酸盐与醛加成，分别形成β-酮砜、β-酮膦氧化物和β-酮膦酸盐。
• 与三苯甲基氯一起用于催化甲硅烷基烯醇醚与缩醛或醛的羟醛反应以及甲硅烷基烯醇醚与 α,β-不饱和酮的迈克尔反应。
• 在钯催化剂存在下，作为烯丙醇与胺的烯丙基胺化反应的促进剂。

包装

10, 50 g in glass bottle

基本信息

产品性质

安全信息

象形图
警示用语：	Danger
危险声明	H290 - H302 + H332 - H314 - H317 - H335 - H373 - H410
预防措施声明	P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类	Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3
靶器官	Cardio-vascular system, Respiratory system
储存分类代码	8B - Non-combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

产品说明

一般描述

SnCl₂ 二水合物与乙酸酐反应，生成无水SnCl₂。SnCl₂ 在酸性介质中表现出还原性。SnCl₂ 在熔融状态下具有出色的催化作用。它是用于半导体层化学气相沉积(CVD)的理想原材料。SnCl₂ 参与还原芳香族硝基化合物、腈、氰基甲硅烷基醚和有机叠氮化物。

应用

氯化亚锡可用于：

• 催化重氮砜、重氮氧化膦和重氮膦酸盐与醛加成，分别形成β-酮砜、β-酮膦氧化物和β-酮膦酸盐。
• 与三苯甲基氯一起用于催化甲硅烷基烯醇醚与缩醛或醛的羟醛反应以及甲硅烷基烯醇醚与 α,β-不饱和酮的迈克尔反应。
• 在钯催化剂存在下，作为烯丙醇与胺的烯丙基胺化反应的促进剂。

包装

2 kg in poly bottle
100, 500 g in poly bottle

基本信息

产品性质

安全信息

象形图
警示用语：	Danger
危险声明	H290 - H302 + H332 - H314 - H317 - H335 - H373 - H410
预防措施声明	P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类	Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3
靶器官	Cardio-vascular system, Respiratory system
储存分类代码	8B - Non-combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

产品说明

分析说明

Assay (iodometric): ≥ 97.0 %
Identity (ICP-OES): passes test

基本信息

产品性质

安全信息

象形图
警示用语：	Danger
危险声明	H290 - H302 + H332 - H314 - H317 - H335 - H373 - H410
预防措施声明	P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类	Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3
靶器官	Cardio-vascular system, Respiratory system
储存分类代码	8B - Non-combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

产品说明

一般描述

SnCl₂ dihydrate reacts with acetic anhydride to yield anhydrous SnCl₂. SnCl₂ exhibits reducing properties in acidic media. SnCl₂ shows superior catalytic action in its molten state. It is a promising raw material for the chemical vapour deposition (CVD) of semiconducting layers. SnCl₂ participates in the reduction of aromatic nitro compounds, nitriles, cyanosilyl ethers and organic azides.

应用

Redi-Dri^™ is an innovative packaging product line that helps eliminate clumping material by adding extra packaging process steps without any chemical additives, anti-clumping agents, or hydrophobic compounds. Redi-Dri^™offers a more convenient and safer way to handle the products.
Tin(II) chloride (SnCl₂) has been used as a starting material to evaluate the thermal behavior of SnCl₂ on heating at the rate of 5℃min^-1 in air. The product undergoes phase transformation on heating at rate of 5℃ min^-1 in air, it involves an incomplete evaporation followed by oxidation forming SnO₂ nanoparticles. SnCl₂ has also been used for the fabrication of Sn-containing carbon nano-structures.
Tin(II) chloride may be used:

• To catalyze the addition of diazo sulfones, diazo phosphine oxides and diazo phosphonates to aldehydes to form β-keto sulfones, β-keto phosphine oxides and β-keto phosphonates, respectively.
• Along with trityl chloride, to catalyze the aldol reaction of silyl enol ethers with acetals or aldehydes and the Michael reaction of silyl enol ethers with α,β-unsaturated ketones.
• As a promoter in the allylic amination of allylic alcohols with amines in the presence of palladium catalyst.

其他说明

Go to Redi-Dri^™ Product Listing 208256

法律信息

Redi-Dri is a trademark of sigma-aldrich Co. LLC

基本信息

产品性质

安全信息

象形图
警示用语：	Danger
危险声明	H290 - H302 + H332 - H314 - H317 - H335 - H373 - H412
预防措施声明	P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338 + P310
危险分类	Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3
靶器官	Cardio-vascular system, Respiratory system
储存分类代码	8B - Non-combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

基本信息

安全信息

图形或危害标志
危险性说明	H290: May be corrosive to metals. H302: Harmful if swallowed. H314: Causes severe skin burns and eye damage. H317: May cause an allergic skin reaction. H318: Causes serious eye damage. H332: Harmful if inhaled. H335: May cause respiratory irritation. H373: May cause damage to organs .. H412: Harmful to aquatic life with long lasting effects.
防范说明	P233: Keep container tightly closed. P234: Keep only in original container. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor/physician. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P314: Get medical advice/attention if you feel unwell. P321: Specific treatment (see . on this label). P330: Rinse mouth. P333 + P313: If skin irritation or rash occurs: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P363: Wash contaminated clothing before reuse. P390: Absorb spillage to prevent material damage. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P406: Store in corrosive resistant/. container with a resistant inner liner. P501: Dispose of contents/container to local regulations.