| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | 详情 |
| E742745 | MACKLIN | 4-氟苯乙炔 | Standard for GC, ≥99.8%(GC) | 350元/1g; | 展开 |
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| E809168 | MACKLIN | 4-氟苯乙炔 | 98% | 35元/1g; 85元/5g; 355元/25g; 1198元/100g; | 展开 |
储存：2~8°C 折射率：n20/D 1.516(lit.) |
| F0470 | TCI | 1-Ethynyl-4-fluorobenzene | >98.0%(GC) | 290元/1G; 1360元/5G; | 展开 |
基本信息 | 纯度/分析方法 | >98.0%(GC) | | 分子式/分子量 | C8H5F = 120.13 | | 外观与形状(20℃) | 固体 | | 储存温度 | 0-10℃ | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 空气,加热 | | Reaxys-RN | 1099285 | | PubChem物质ID | 87570227 | | MDL编号 | MFCD00168823 |
技术规格 | Appearance | White to Orange to Green powder to lump | | Purity(GC) | min. 98.0 % |
物性(参考值) | 熔点 | 24 ℃ | | 沸点 | 56 ℃/40 mmHg | | 闪点 | 29 ℃ | | 折射率 | 1.52 |
安全信息 | 图形或危害标志 |   | | 信号词 | 警告 | | 危险性说明 | H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H228 : 易燃固体。
| | 防范说明 | P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P241 : 使用防爆的电气/通风/照明设备。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染：用水充分清洗。
P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。
P337 + P313 : 如仍觉眼刺激：求医/就诊。
P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激：求医/就诊。
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运输信息 | UN编号 | UN1325 | | 类别 | 4.1 | | 包装类别 | III | | 监管条件代码(*) | |
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| 350781 | J&K | 1-Ethynyl-4-fluorobenzene | 99% | 262元/1G; 1109元/5G; | 展开 |
基本信息 | 分子式 | C8H5F | | 分子量 | 120.12 | | 熔点 | 27-28 | | 沸点 | 55-56 | | 闪点 | 29 | | 密度 | 1.048 | | 折光率(n20D) | 1.5160 | | MDL编码 | MFCD00168823 |
安全信息 | 图形或危害标志 | | | 提示语 | Danger | | 危险说明 | H228
H315
H319
H335 | | 防范说明 | P210
P261
P305+P351+P338 | | UN号码 | 1325 | | 危险分类 | 4.1 | | 包装等级 | II | | WGK | 3 | | TSCA | 否 |
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| H26269 | Alfa Aesar | 4-Fluorophenylacetylene | 99% | 883元/1g; 3554元/5g; 11758元/25g; | 展开 |
应用
Intermediates of liquid Crystals. As pharmaceutical intermediates. As organic synthesis intermediates. For vacuum deposition. 备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, heavy metal powders. 基本信息 MDL
MFCD00168823 分子式
C8H5F 分子量
120.12 熔点
27-28° 沸点
55-56°/40mm 闪点
29°(85°F) 密度
1.048 折射率
1.5170 灵敏度
Ambient temperatures. 形态
Low melting solid 溶解性
Soluble in chloroform, diethyl ether, acetone, dichloromethane, hexane and ethanol. Highly soluble in toluene. Insoluble in water. Beilstein
1099285 GHS危害和防范说明 GHS符号
Hazard Statements
H228-H319-H335
Flammable solid.Causes serious eye irritation.May cause respiratory irritation. Precautionary Statements
P210-P305+P351+P338
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 安全信息 危险等级
4.1 包装组
III 危险类别
11-36/37
Highly flammable.Irritating to eyes and respiratory system. 安全等级
16-26
Keep away from sources of ignition - No smoking.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 欧盟危险品标志
 TSCA
否 |
| C37137 | Alfa Aesar | 1-Ethynyl-4-fluorobenzene | 98% | 1069元/1g; 3506元/5g; | 展开 |
基本信息 Ref#
37137 MDL
168823 分子式
C8 H5 F 分子量
120.13 闪点
29 密度
1048 形态
Colorless to pale yellow liquid as melt 安全信息 危险等级
4.1 包装组
II |
| 404330 | Sigma-Aldrich | 1-Ethynyl-4-fluorobenzene | 99% | 481.43元/1 G; 824.49元/5 G; | 展开 |
产品说明 一般描述 1-乙炔基-4-氟苯 (pFAB) 是一种氟苯衍生物。本文报道了三阴离子钳型烷基苯复合物催化的 1-乙炔基-4-氟苯聚合。碘苯基端有机单层的表面通过 pFAB 与表面上发现的碘苯基的薗头偶合反进行修饰。由 Y [N (TMS) 2 3 和 4-氯苯胺催化的二聚化反应以极好的产率得到三种可能的烯二炔中的一种。 应用 1-乙炔基-4-氟苯是一种取代的苯乙炔，它可与多种卤代芳烃通过薗头偶合反应，在双 (μ~ +)、双 (μ~ +)、单 (μ~ +)、双 (μ~ +)、单 (μ~ +)、双 (μ~ +)、单 (μ~ +)、双 (μ~ +)、双 (μ~ +)-碘)双((-)-司巴丁)双 (I) 催化剂。
1-乙炔基-4-氟苯可用于以下合成： - 在铜催化剂存在下，3-(4-氟苯基)-1 H -异色-1-酮与 2-碘苯甲酸反应。
- 4-溴-3,5-二氟-2,6-双-(4-氟-苯乙炔基)-吡啶通过钯催化的薗头偶合反应与 2,4,6-三溴-3,5-二氟吡啶反应。
- 1-(4-氟苯基)-3-甲氧基-3-(4-甲氧基苯基)丙-1-酮与 p -茴香醛反应。
- 在叠氮化钠存在下，5-(4-氟苯基)-1-(2-硝基苄基)-1 H -1,2,3-三唑与 1-(溴甲基)-2-硝基苯反应。
包装 1, 5 g in glass bottle 基本信息 | 线性分子式 | FC6H4C≡CH | | 分子量 | 120.12 | | Beilstein | 1099285 | | MDL编号 | MFCD00168823 | | PubChem化学物质编号 | 24865238 | | NACRES | NA.22 |
产品性质 | 质量水平 | 200 | | 测定 | 99% | | 折射率 | n20/D 1.516 (lit.) | | bp | 55-56 ℃/40 mmHg (lit.) | | mp | 26-27 ℃ (lit.) | | 密度 | 1.048 g/mL at 25 ℃ (lit.) | | 储存温度 | 2-8℃ | | SMILES string | Fc1ccc(cc1)C#C | | InChI | 1S/C8H5F/c1-2-7-3-5-8(9)6-4-7/h1,3-6H | | InChI key | QXSWHQGIEKUBAS-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Danger | | 危险声明 | H228 - H315 - H319 - H335 | | 预防措施声明 | P210 - P240 - P241 - P261 - P302 + P352 - P305 + P351 + P338 | | 危险分类 | Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 4.1B - Flammable solid hazardous materials | | WGK | WGK 3 | | 闪点(F) | 84.2 °F - closed cup | | 闪点(C) | 29 ℃ - closed cup | | 个人防护装备 | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
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| 916051 | Amethyst | 1-Ethynyl-4-fluorobenzene | 98%, 用于合成 | 140元/1G; 510元/5G; 709元/25G; 2709元/100G; | 展开 |
基本信息 | 分子式 | C8H5F | | 分子量 | 120.12 | | 熔点 | 27-28 | | 沸点 | 55-56 | | 闪点 | 29 | | 密度 | 1.048 | | 折光率(n20D) | 1.5160 | | MDL编码 | MFCD00168823 |
安全信息 | 图形或危害标志 | | | 提示语 | Danger | | 危险说明 | H228
H315
H319
H335 | | 防范说明 | P210
P261
P305+P351+P338 | | UN号码 | 1325 | | 危险分类 | 4.1 | | 包装等级 | II | | WGK | 3 | | TSCA | 否 |
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| 008808 | Fluorochem | 4-Fluorophenylacetylene | 99% | 440元/1g; 1232元/5g; | 展开 |
基本信息 | CAS Number | 766-98-3 | | MDL Number | MFCD00168823 | | Boiling Point | 42-44℃/20mm | | Melting Point | 26-28℃ | | Density | 1.048 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H228: Flammable solid.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
| | 防范说明 | P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof / equipment.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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