CAS 72287-26-4; 1,1'-双(二苯基膦)二茂铁氯化钯; [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(ii)pdcl2(dppf)

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B807104

MACKLIN

[1,1'-双(二苯基膦基)二茂铁]二氯化钯

Pd 14.5%

367元/1g; 1342元/5g; 5142元/25g;

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储存：室温
状态：红色到暗棕色粉末

B798965

MACKLIN

[1,1'-双(二苯基膦基)二茂铁]二氯化钯

99.9% metals basis

836元/1g; 3337元/5g;

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储存：室温, 惰性气体
状态：红色到非常暗红色粉末

130100

J&K

1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride

98%

363元/1G; 1404元/5G; 4598元/25G; 16700元/100G;

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基本信息

分子式	C₃₄H₂₈FeP₂·PdCl₂
分子量	731.71
熔点	266-283
MDL编码	MFCD00015757
EINECS 编号	460-040-3

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3

919780

Sigma-Aldrich

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) ChemBeads

1425.17元/250 MG; 3562.94元/1 G;

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产品说明

应用

Catalyst for C-C and C-N coupling reaction.
Pd(dppf)Cl₂ may be used as an effective palladium catalyst in the following reactions:

Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
Suzuki coupling of aryl boronic esters with [¹¹C]methyl iodide to form functionalized [¹¹C]toluene derivatives.
Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

其他说明

High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads

Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

基本信息

线性分子式

(C₁₇H₁₄P)₂Fe . PdCl₂

产品性质

测定	~4 wt.% loading of catalyst
质量水平	100
形式	solid

安全信息

象形图
警示用语：	Danger
危险声明	H350i
预防措施声明	P201 - P202 - P280 - P308 + P313 - P405 - P501
危险分类	Carc. 1B Inhalation
储存分类代码	6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

697230

Sigma-Aldrich

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

1158.79元/1 G; 2797.61元/5 G; 88518.1元/250 G;

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产品说明

应用

用于C-C和C-N偶联反应的催化剂。
钯催化交叉偶联反应应用指南
Pd(dppf)Cl₂可作为一种有效的钯催化剂用于以下反应：

具有高产率和选择性的仲烷基和正烷基格氏试剂的交叉偶联。
芳基硼酸酯与[¹¹C]甲基碘形成官能化的[¹¹C]甲苯衍生物的铃木偶联反应。
1,3,5-三溴苯与格氏试剂形成星形低聚噻吩的Kumada交叉偶联反应。

包装

1, 5, 250 g in glass bottle

基本信息

线性分子式	(C₁₇H₁₄P)₂Fe · PdCl₂
分子量	731.70
EC 号	460-040-3
MDL编号	MFCD00015757
PubChem化学物质编号	329761901
NACRES	NA.22

产品性质

质量水平	200
形式	powder
reaction suitability	core: palladium reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst reaction type: Buchwald-Hartwig Cross Coupling Reaction
mp	266-283 ℃ (lit.)
SMILES string	[Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
InChI	1S/2C17H14P.2ClH.Fe.Pd/c21-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h21-14H;2*1H;;/q;;;;;+2/p-2
InChI key	JCWIWBWXCVGEAN-UHFFFAOYSA-L

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

035791

Fluorochem

1,1'-Bis(diphenylphosphino)ferrocenepalladium (II) dichloride

98%

506元/1g; 2156元/5g; 10340元/25g;

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基本信息

CAS Number	72287-26-4
MDL Number	MFCD00015757

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .