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CAS: 703-55-9
分子式: C10H7BrMg
分子量: 231.37
沸点: 65 °C
英文名称: 
1-Naphthylmagnesium bromide solution
bromo-1-naphthalenyl-magnesiu
推荐供应商
货号品牌产品名称规格包装、参考价格详情
N821468MACKLIN1-萘基溴化镁0.25 M solution slurry in THF, MkSeal150元/5ml;   1412元/50ml;   展开
储存:2~8 ℃
状态:液体
341175J&K1-Naphthylmagnesium bromide, 0.25 M slurry solution in THF, J&KSeal0.25 M 四氢呋喃浆态溶液, J&KSeal瓶2577元/100ML;   展开

基本信息

分子式C10H7BrMg
分子量231.37
沸点65
闪点-17
密度0.908
MDL编码MFCD00015768

安全信息

图形或危害标志
提示语Danger
危险说明EUH014
EUH019
H225
H260
H314
H335
防范说明P210
P243
P261
P301+P330+P331
P305+P351+P338
UN号码2924
危险分类3
次要危险性8
包装等级II
WGK1
561673Sigma-Aldrich1-Naphthylmagnesium bromide solution0.25 M slurry in THF2460.64元/50 ML;   展开

产品说明

应用

1-Naphthylmagnesium bromide can be used:

  • To prepare unsymmetrical chiral diene ligands, which are applicable in asymmetric transformation reactions.
  • As a starting material in the synthesis of methyl (2Z,4E)-2-methylsulfanyl-5-(1-naphthyl)-4-nitro-2,4-pentadienoate, a naphthylnitrobutadiene based anti-proliferative compound.

包装

50 mL in Sure/Seal™

法律信息

Rieke® Metals, Inc. 产品 ®Rieke Metals, Inc. 的注册商标

基本信息

经验(实验)分子式C10H7BrMg
分子量231.37
MDL编号MFCD00015768
PubChem化学物质编号24879961

产品性质

质量水平100
reaction suitabilityreaction type: Grignard Reaction
浓度0.25 M slurry in THF
bp65 ℃
密度0.908 g/mL at 25 ℃
SMILES stringBr[Mg]c1cccc2ccccc12
InChI1S/C10H7.BrH.Mg/c1-2-6-10-8-4-3-7-9(10)5-1;;/h1-7H;1H;/q;;+1/p-1
InChI keyPZIIGUMPOSVMSD-UHFFFAOYSA-M

安全信息

象形图GHS02GHS05GHS07GHS08
警示用语:Danger
危险声明H225 - H302 - H314 - H335 - H351
预防措施声明P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
危险分类Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
靶器官Respiratory system
补充剂危害EUH014 - EUH019
储存分类代码3 - Flammable liquids
WGKWGK 3
闪点(F)1.4 °F - closed cup
闪点(C)-17 ℃ - closed cup
214111Fluorochem1-Naphthylmagnesium bromide, 0.25M 2-MeTHF97%4136元/50ml;   6402元/100ml;   10824元/250ml;   展开

基本信息

CAS Number703-55-9
MDL NumberMFCD00015768
Boiling Point78℃
Density0.855

安全信息

图形或危害标志
危险性说明 EUH014: Reacts violently with water.
EUH019: May form explosive peroxides.
H225: Highly flammable liquid and vapour.
H301: Toxic if swallowed.
H314: Causes severe skin burns and eye damage.
H315: Causes skin irritation.
H318: Causes serious eye damage.
防范说明 P210: Keep away from – No smoking.
P235: Keep cool.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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